AYNUR MANZAK, Cem KURŞUN, YASEMİN YILDIZ

Humik asidin sulu çözeltilerden polimer içerikli membranlar ile ekstraksiyonu

Bu çalışmada, humik asit sodyum humat çözeltisinden polimer içerikli membranlar (PIMs) kullanılarak ekstrakte edilmektedir. Sodyum humat, Kahramanmaraş Afşin Elbistan Bölgesindeki linyitlerden elde edilmiştir. PIMs; polimer selüloz triasetat, taşıyıcı trikaprilmetilamonyum klorür, modifiyer tributil fosfat ve plastikleştirici 2- nitrofenil pentil eter kullanılarak hazırlanmıştır. Polimerik film 2 cam hücre arasına yerleştirilmiştir. Sıyırma çözeltisi tipi, sıyırma çözeltisi konsantrasyonu, besleme ve sıyırma çözeltisi karıştırma hızı parametrelerinin ekstraksiyona etkisi deneysel olarak incelenmiştir. Sıyırma fazına yaklaşık %25 humik asit geçirilmiş ve UV-Vis spektrofotometresiyle ölçülmüştür.

Extraction of humic acid from an aqueous solution with polymer inclusion membranes

In this study, humic acid was extracted from the solution of sodium humate by using polymer inclusion membranes (PIMs). Sodium humate was obtained by treating lignite from Kahramanmaraş Afşin-Elbistan Region. PIMs were prepared by using cellulose triacetate as polymer, a carrier, tricaprylmethylammonium chloride, modifier tri-butyl phosphate and plasticizer 2- nitro phenyl pentyl ether. The polymeric film was placed between two glass cells. The effect of the stripping solution type, stripping solution concentration and feed and stripping solution mixing rate parameters were experimentally investigated. About 25% humic acid was passed to the stripping phase and measured by UV-Vis spectrophotometer.

PDF

___

F. J. Stevenson, “Humus Chemistry: Genesis, Compositions, Reactions,” 2nd edition, John Wiley and Sons, 1994, pp. 1-512.
J. Beck, K. C. Jones, M. H. B. Hayes, U. Mingelgrin, “Organic Substances in Soil and Water: Natural Constituents and Their Influences on Contaminant Behavior,” The Royal Society of Chemistry, pp. 1-200, 1993.
P. MacCarthy, I. H. Suffet, “In Aquatic Humic Substances: Influence in Fate and Treatment of Pollutants: Advances in Chemistry Series 219,” American Chemical Society, pp.1-898, 1989.
F. J. Stevenson, “Humus Chemistry: Genesis, Composition, Reactions,” John Wiley and Sons, 1982, pp. 1-592.
N. N. Rupiasih, P. Vidyasagar, “A Review: Compositions, Structures, Properties and Applications of Humic Substances,” Journal of Advances in Science and Technology, vol. 8 (I&II), pp. 16-25, 2005.
K. L. Jarvis, P. Majewski, “Influence of Film Stability and Aging of Plasma Polymerized Allylamine Coated Quartz Particles on Humic Acid Removal,” Appl. Mater. Interfaces, vol. 5 (15), pp. 7315–7322, 2013.
N. Taoualit, F.-Z. Azzazi, N.E. Benkadi and D.E. Hadj-Boussaad, ‘‘Extraction and Transport of Humic Acid using Supported Liquid-Membrane Containing Trioctyl Phosphine Oxide (TOPO) as the Carrier,’’ Acta Physica Polonica Acta, vol. 30, 2016.
H. X. Yu, B. K. W. Man, L. L. N Chan, M. H. W. Lam, P. K. S., Lam, L. Wang, H. Jin, R. S. S. Wu, “Cloud-point extraction of nodularin-R from natural waters,” Analytica Chimica Acta , vol. 509, pp. 63–70, 2004.
E. M. Pena-Mendez, J. Havel, J. Patocka, “Humic substance-compounds of still unknown structure: applications in agriculture, industry, enviroment and biomedicine,” Applied Biomedicine, vol. 3(1), pp. 13-24, 2005.
S. Sodaye, G. Suresh, A. K. Pandey, A. Goswami, “Determination and theoretical evaluation of selectivity coefficients of monovalent anions in anion‐exchange polymer inclusion membranes,” J. Membr. Sci., vol. 295, pp. 108–113, 2007.
S. D. Kolev, “Liquid membranes,’’ In Encyclopedia of Analytical Science, 2nd ed. Worsfold, P., Townshend, A., Poole, C., Eds.; Elsevier: Amsterdam, The Netherlands, 2005; pp. 531–538.
L. D. Nghiem, P. Mornane, I. D. Poer, J. M. Perera, R. W. Carall, S. D. Kolev, “Extraction and transport of metal ions and small organic compounds using polymer inclusion membranes (PIMs),” J. Membr. Sci., vol. 281, pp. 7–41, 2006.
C. Combe, E. Molis, P. Lucas, R. Riley, M. M. Clark, “The effect of CA membrane properties on adsorptive fouling by humic acid,” Journal of Membrane Science, vol. 154, pp. 73-87, 1999.
K. L. Jarvis, P. Majewski, “Plasma polymerized allylamine coated quartz particles for humic acid removal,” Journal of Colloid and Interface Sci., vol. 380, pp. 150-15, 2012.