REAKTİF SİYAH 5 BOYASININ PAMUKLU KUMAŞI BOYAMA DAVRANIŞI: K/S RENK VERİMİ, FİKSAJ VE HASLIKLAR

Bu çalışmada, pamuklu kumaş CI Reaktif Siyah 5 boyarmaddesi ile çektirme yöntemine göre farklı boyama şartlarında boyanmıştır. Boyama banyosu artık renkli çözeltileri UV-Vis ölçümlerine göre boyarmaddelerin maksimum çekim yüzdeleri belirlenmiştir. Boyalı kumaşlar yıkama işlemi öncesi ve sonrası olmak üzere spektrofotometrik renk ölçümleri yapılarak K/S renk verimi değerlerine göre relatif fiksaj yüzdesi hesaplanmıştır. En son olarak yıkama ve sürtme haslıkları belirlenerek seçilen boyama sonuçları içinde, çekim, fiksaj ve haslık sonuçları karşılaştırılmıştır.

DYEING BEHAVIOR OF REACTIVE BLACK 5 DYE ON COTTON FABRIC: K/S COLOR STRENGTH, FIXATION AND FASTNESSES

In this study, cotton fabrics were dyed with CI Reactive Black 5 dye on different dyeing conditions with exhaustion technique. Maximum exhaustion percent of dyeing was determined by UV-Vis measurement of colored waste dye bath solutions. Dyed fabrics color were measured by spectrophotometrically before and after washing relative fixation percent calculated by using K/S color strength values. Finally, Exhaustion, fixation and fastness results are compared in the selected dyeing results by determining the washing and rubbing fastness.

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[1] BROADBENT A.D., Basic Principles of Textile Coloration, Society of Dyers and Colourists, West Yorkshire, England, 2001.
[2] SHORE J., Cellulosics Dyeing, Society of Dyers and Colourists, West Yorkshire, England, 1995.
[3] FERUS-COMELO, M., An Analysis of the Substantivity of Hydrolysed Reactive Dyes and Its Implication For Rinsing Processes, Coloration Technology, 129, 24-31, 2013.
[4] ERSOZ, G., NAPOLEONI, A., ATALAY, S., Comparative Study Using Chemical Wet Oxidation for Removal of Reactive Black 5 in the Presence of Activated Carbon, Journal of Environmental Engineering, 139, 1462-1469, 2013.
[5] BANSAL, S., KUSHWAHA, J.P., SANGAL, V.K., "Electrochemical Treatment of Reactive Black 5 Textile Wastewater: Optimization, Kinetics, and Disposal Study", Water Environment Research, 85, 2294-2306, 2013.
[6] GUO, X.Y.,CAI, Y.P., WEI, Z.B., "Treatment of Diazodye C.I. Reactive Black 5 in Aqueous Solution by Combined Process of Interior Microelectrolysis and Ozonation", Water Science and Technology, 67, 1880-1885, 2013. ,
[7] BHATTI, I.A., ADEEL, S., NADEEM, R., ASGHAR, T., "Improvement of Colour Strength and Colour Fastness Properties of Gamma Irradiated Cotton Using Reactive Black-5", Radiation Physics and Chemistry, 81, 264-266, 2012.
[8] KHATRI, Z., MEMON, M.H., KHATRI, A., TANWARI, A., Cold Pad-Batch Dyeing Method for Cotton Fabric Dyeing with Reactive Dyes Using Ultrasonic Energy, Ultrasonics Sonochemistry, 18, 1301-1307, 2011.
[9] SUWANRUJI, P.,FREEMAN, H.S., "Design, Synthesis and Application of Easy Wash-Off Reactive Dyes", Coloration Technology, 122, 27-36, 2006.
[10] BLACKBURN, R.S., BURKINSHAW, S.M., A Greener Approach to Cotton Dyeing Swith Excellent Wash Fastness, Green Chemistry, 4, 47-52, 2002.
[11] BURKINSHAW, S.M., KATSARELIAS, D., "The Wash-Off of Reactive Dyes on Cellulosic Fibres. 4. The Use of Different Alkalis with Monochlorotriazinyl Dyes on Cotton", Dyes and Pigments, 35, 249-259, 1997.
[12] THIAGARAJAN, P., NALANKILLI, G., "Improving Light Fastness of Reactive Dyed Cotton Fabric with Antioxidant and UV Absorbers", Indian Journal of Fibre & Textile Research, 38, 161-164, 2013.
[13] FANG, L., ZHANG, X.D., SUN, D.S., "Chemical Modification of Cotton Fabrics for Improving Utilization of Reactive Dyes", Carbohydrate Polymers, 91, 363-369, 2013.
[14] ZHENG, C.L., YUAN, A.L., WANG, H.B., SUN, J., "Dyeing Properties of Novel Electrolyte-Free Reactive Dyes on Cotton Fibre", Coloration Technology, 128, 204-207, 2012.
[15] TUTAK, M., ÖZDEMIR, A.O., "Reactive Dyeing of Cationized Cotton: Effects on the Dyeing Yield and the Fastness Properties", Journal of Applied Polymer Science, 119, 500-504, 2011.
[16] AHMED, N., OULTON, D.P., TAYLOR, J.A., "The Use of Reflectance Measurements in the Determination of Fixation of Reactive Dyes to Cotton", Color Research and Application, 31, 117-121, 2006.
[17] TÜRK STANDARTLARI ENSTİTÜSÜ, Tekstil-Renk Haslığı Deneyleri-Bölüm C06: Evsel ve Ticari Yıkamaya Karşı Renk Haslığı, TS EN ISO 105-C06, .2012.
[18] TÜRK STANDARTLARI ENSTİTÜSÜ, Tekstil-Renk Haslığı Deneyleri-Bölüm X12: Sürtünmeye Karşı Renk Haslığı Tayini, TS EN ISO 105-X12, .2006.
[19] ÖZDEMİR A., Selülozik Tekstil Materyallerinde Renklendirme Veriminin Artırılması İçin Katyonikleştirme Şartlarının Araştırılması, Yüksek Lisans Tezi, Erciyes Üniversitesi, Fen Bilimleri Enstitüsü, Kayseri, 2009.