Yüksekova kompleksinde (Özalp - Van, Türkiye) peridotitleri kesen diyabaz daykların jeokimyasal özellikleri ve rodenjitleşme

Bu incelemede, Yüksekova kompleksinden (Özalp - Van) peridotitleri kesen diyabaz daykların jeolojisi ve başkalaşımlarına neden olan Ca metazomatizmasının etkileri irdelenmiştir. Mineralojik-petrografik çalışmalar ve jeokimyasal veriler ışığında, Yüksekova karmaşığında peridotitleri kesen diyabaz daykların, Ca metazomatizmasına bağlı olarak çeşitli derecelerde rodenjitleşme gösterdikleri tespit edilmiştir. Bu metazomatizmaya bağlı olarak Ca-Al-Mglu silikatlar oluşmuştur. Ofitik dokuya sahip rodenjitleşmiş diyabaz daykların mineralojik bileşimini diyopsit, plajiyoklaz, hidrogrossular, klorit, epidot ve daha az oranda flogopit, prehnit, apatit, kalsit ve opak mineraller oluşturmaktadır. Metazomatizma toleyitik karakterdeki daykların tüm kayaç ana oksitlerinde Ca zenginleşmesi ve SiO2 tüketilmesine sebep olmuştur. Buna göre dayklar üç farklı alt guruba ayrılmıştır. Birinci gurup ileri derecede rodenjitleşmiş diyabaz dayklarından oluşur (~% ağ 42.0–38.0 SiO2 ;~% ağ 19.0–26.0 CaO). İkinci gurubu oluşturan diyabaz dayklarında rodenjitleşme derecesi daha düşüktür (~% ağ 42.5–43.0 SiO2; % ağ 14.5–15.0 CaO). Üçüncü gurubu oluşturan diyabaz dayklarında ise hem petrografik hem de jeokimyasal analiz sonuçlarına göre rodenjitleşme etkilerine rastlanılmamıştır (~% ağ 47.0–50.0 SiO2 ; % ağ 10.0 –12.0 CaO). İz ve NTE içeriklerinin zenginleştiği rodenjitleşmiş dayklarda, metazomatik kaynağa etki eden akışkanların bu elementlerce daha zengin kayaçlarla olan etkileşmeleri sonucunda geliştiği düşünülmektedir. Bu etkileşimde yerel jeoloji, ortamın tektonik yapısı ve buna bağlı gelişecek olan akışkanlarda sıcaklık, oksijen kısmi basıncı ve kimyasal bileşimi gibi faktörlerin önemli olduğu düşünülmektedir.

In this study, the geology of diabase dykes which cut peridotites of Yüksekova complex (Özalp, Van, Turkey) and the effects of Ca metasomatism that caused the metamorphism of these peridotites were investigated. Within the light of mineralogical and petrographical studies and geochemical data; it was determined that diabase dykes that cut peridotites in Yüksekova complex had shown rodingitization in various degrees due to Ca metasomatism. Depending on this metasomatism, Ca-Al-Mg rich silicates were formed. The mineralogy of rodingitized dykes with ophitic texture is composed of diopside, plagioclase, hydrogrossularite, chlorite, epidote and in minor amounts phlogopite, prehnite, apatite, calcite, opaque minerals. Metasomatism caused enrichment of Ca and depletion of SiO2 in whole rock major oxides of dykes in tholeiitic character. So, dykes were divided into three different subgroups. The first group is formed from high grade rodingitized diabase dykes (~38.0–42.0 wt. % in SiO2; 19.0–26.0 wt. % in CaO). The grade of rodingitization in diabase dykes forming the second group is relatively low (~42.5–43.0 wt. % in SiO2; 14.5–15.0 wt. % in CaO). However, the effect of rodingitization has not been encountered due to results of both petrographical and geochemical analyses in diabase dykes which form the third group (~47.0–50.0 wt. % in SiO2; 10.0–12.0 wt. % in CaO). It is considered that in rodingitized dykes of which are enriched by trace and REE (Rare Earth Element) contents, the fluids affecting the metasomatic source have developed as a result of interactions with other rocks which were enriched more in these elements. It is also contemplated that the local geology, tectonical structure of the environment and the heat, oxygen fugacity and chemical composition in fluids which would develop due to those factors are significant in this interaction.

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  • Albayrak, M., 1995. Akseki–Aydınkent (Antalya) arasının Jeolojisi ve Petrol Olanakları, Yüksek Lisans Tezi, Ankara Üniversitesi, Fen Bilimleri Enstitüsü.
  • Algeo, T.J., Berner, R.A., Maynard, J.B. ve Scheckler, S.E., 1995. Late Devonian oceanic anoxic events and biotic crises: “rooted” in the evolution of vascular land plants? GSA Today, 5, 64–66.
  • ——— ve Scheckler, S.E., 1998. Terrestrial– marine teleconnections in the Devonian: links between the evolution of land plants, weathering processes, and marine anoxic events. Philosophical Transactions of Royal Society B: Biology Science, 353, 113–130.
  • ——— ve Maynard, J.B., 2004. Trace–Element Behavior and Redox Facies in Core Shales Of Upper Pennsylvanian Kansas-Type Cyclothems. Chemical Geology, 206, 289 – 318.
  • Amajor, L.C., 1987. Major and trace elements geochemistry of Albin and Turonian shales from the Southern Benue trough, Nigeria. Journal of African Earth Science, 6, 633 – 461.
  • Andersson, A., Dahlman, B., Gee, D.G., ve Snäll, S., 1985. The Scandinavian Alum Shales. Sveriges Geologiska Undersoekning, Serie Ca: Avhandlingar och Uppsatser I A4, NR 56, 50 p.
  • Arnaboldi, M. ve Meyers, P.A., 2003. Geochemi cal evidence for paleoclimatic variations during deposition of two Pliocene sapro pels from the Vrica section, Calabria. Palaeogeography, Palaeoclimatology, Palaeoecology, 190, 257–271.
  • Bhatia, M.R., 1983. Plate tectonics and geochemical composition of sandstones. Journal of Geology 91, 611–627.
  • Blumenthal, M.M., 1951, Batı Toroslarda Alanya ard ülkesinde jeolojik araştırmalar. Maden Tetkik ve Arama Genel Müdürlüğü dergisi, 5, 194.
  • Boggs, Jr.S., 2009. Petrology of sedimentary rocks. Cambridge University Press, UK, 2nd edition, 600 p.
  • Breit, G.N. ve Wanty, R.B., 1991. Vanadium accumulation in carbonaceous rocks: a review of geochemical controls during deposition and diagenesis. Chemical Geology, 91, 83-97.
  • Brüchert, V., R., Jorgensen, B.B., Neumann, K., Richmann, D., Schlösser, M. ve Schulz, H., 2003. Regulation of bacterial sulfate reduction and hydrogen sulfide fiuxes in the central Namibian coastal upwelling zone. Geochimica et Cosmochimica Acta, 67, 4505–4518.
  • Brumsack, H.ve J., 2006. The trace metal content of recent organic carbon-rich sediments: implications for Cretaceous black shale formation. Palaeogeography, Palaeocli matology, Palaeoecology, 232, 344–361.
  • Caplan, M.L. ve Bustin, R.M., 1998. Paleoceanographic controls on geochemical characteristics of organic-rich Exshaw mudrocks: role of enhanced primary productivity. Organic Geochemistry, 30, 161–188.
  • Demaison, G.J. ve Moore, G.T., 1980. Anoxic environments and oil source bed genesis. American Association of Petroleum Geologists Bulletin 64, 1179–1209.
  • Dill, H., 1986. Metallogenesis of Early Paleozoic Graptolite Shales from the Graefenthal Horst (Northern Bavaria-Federal Republic of Germany). Economic Geology, 81, 889–903.
  • ———, Teschner, M. ve Wehner, H., 1988. Petrography, inorganic and organic geochemistry of Lower Permian Carbonaceous Fan sequences (‘‘Brandschiefer Series’’) Federal Republic of Germany: Contrints to their paleogeography and assessment of their source rock potential. Chemical Geology, 67, 307–325.
  • Erbacher, J., Huber, B.T., Norris, R.D. ve Markey, M., 2001. Increased thermohaline stratification as a possible cause for an open ocean anoxic event in the Cretaceous period. Nature, 409, 325-326.
  • Fedo, C.M., Nesbitt, H.W. ve Young, G.M., 1995. Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for paleoweathering conditions and provenance. Geology, 23, 921– 924.
  • Filipelli, G.M., Delaney, M.L., Garrison, R.E., Omarzai, S.K. ve Behl, R.J., 1994. Phosphorus accumulation rates in a Miocene low oxygen basins: the Monterey Formation (Pismo Basin), California. Marine Geology, 116, 419-430.
  • Fleischer, V.D., Garlick, W.G., ve Haldane, R., 1976. Geology of the Zambian Copperbelt; In: K.H. Wolf (ed). Handbook of Stata-Bound and Stratiform Ore Deposits, vol. 6. Elsevier, Amsterdam, 223–352.
  • Floyd, P.A. ve Leveridge, B.E., 1987. Tectonic environment of the Devonian Gramscatho basin, south Cornwell: framework mode and geochemical evidence from turbidite sandstones. Journal of the Geological Society London, 144, 531–542.
  • Gabo, J.A.S., Dimalanta, C.B., Asio, M.G., Queaño, K.L., Yumul Jr., G.P. ve Imai, A., 2009. Geology and geochemistry of the clastic sequences from Northwestern Panay (Philippines): Implications for provenance and geotectonic setting. Tectonophysics, 479, 111-119.
  • Garver, J.I., Royce, P.R. and Scott, T.J., 1994. The presence of ophiolites in tectonic highlands as determined by chromium and nickel anomalies in synorogenic shales: two examples from North America. Russian Geology and Geophysics, 35, 1-8.
  • Garver, J.I.,Royce, P.R. ve Smick, T.A., 1996. Chromium and nickel in shale of the Taconic Foreland: A case study for the provenence of fine-grained sediments with an ultramafic source. Journal of Sedimentary Research, 66, 100-106.
  • Goldberg, K. ve Munir Humayun, M., 2010. The applicability of the Chemical Index of Alteration as a paleoclimatic indicator: An example from the Permian of the Paraná Basin, Brazil. Palaeogeography, Palaeoclimatology, Palaeoecology, 293, 175-183.
  • Gustavson, L.B., ve Williams, N., 1981. Sediment-hosted stratiform deposits of copper, lead, and zinc; In: B.J. Skinner (ed). Seventy-Fifth Anniversary Volume, The Economic Geology Publishing Co., Yale, 139–178.
  • Harnois, L., 1988. The CIW index: a new Chemical Index of Weathering. Sedimentary Geology, 55, 319– 322.
  • Hatch, J.R. ve Leventhal, J.S., 1992. Relationship between inferred redox potential of the depositional environment and geochemistry of the Upper Pennsylvanian (Missourian) Stark Shale Member of the Dennis Limestone, Wabaunsee County, Kansas, U.S.A. Chemical Geology, 99, 65–82.
  • Hedges, J.I. ve Keil, R.G., 1995. Sedimentary organic matter preservation: an assessment and speculative synthesis. Marine Chemistry, 49, 81-115.
  • Hiscott, R.N., 1984. Ophiolitic source rocks for Taconic-age flysch: Trace element evidence. Geological Society of America Bulletin, 95, 1261-1267.
  • Holland, H., 1978. The Chemistry of the Atmosphere and the Oceans. Wiley Interscience, New York. 351 p.
  • Ibach, L.E.J., 1982. Relationship between sedimentation rate and total organic carbon content in ancient marine sediments. American Association Petroleum Geologist Bulletin, 66, 170-188.
  • Ingall, E.D. ve Jahnke, R.A., 1997. Influence of water-column anoxia on the elemental fractionation of carbon and phosphorus during sediment diagenesis. Marine Geology, 139, 219–229.
  • Jones, B. ve Manning, D.A.C., 1994. Comparison of geological indices used for the interpretation of palaeoredox conditions in ancient mudstones. Chemical Geology 111, 111-129.
  • Kirschbaum, A., Martinez, E., Pettinari, G. ve Herrero, S., 2005. Weathering profiles in granites, Sierra Notre (Cordoba, Argentina). Journal of South American Earth Sciences, 19, 479–493.
  • Koca, D., Sarı, A., Koç, Ş., Yavuz, B. ve Koralay, D.B., 2010. Denizel kaynak kayalarda ana ve iz element zenginleşmelerinde Türkiye’den bir örnek: Akkuyu formasyonu (Orta Toroslar). Gazi Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 25, 243-256.
  • Kronberg, B. I. ve Nesbitt, H. W., 1981. Quantification of weathering, soil geochemistry and soil fertility. Journal of Soil Science, 32, 453-459.
  • Lewan, M.D., 1984. Factors controlling the proportionality of vanadium and nickel in. crude oils. Geochimica et Cosmochimica Acta, 48, 2231–2238.
  • ———, ve Maynard, J.B., 1982. Factors controlling enrichment of vanadium and nickel in the bitumen of organic sedimentary rocks. Geochimica et Cosmochimica Acta, 46, 2547–2560.
  • Mader, D. ve Neubauer, F., 2004. Provenance of Palaeozoic sandstones from the Carnic Alps (Austria): petrographic and geochemical indicators. International Journal of Earth Sciences, 93, 262–281.
  • Martin, C., 1969. Akseki kuzeyindeki bir kısım Torosların stratigrafik ve tektonik incelemesi. Maden Tetkik ve Arama Dergisi, 72, 157–175.
  • Middleburg, J.J. ve Comans, R.N.J., 1991. Sorption of cadmium on hydroxyapatite. Chemical Geology, 90, 45-53.
  • Monod, O., 1977. Recherches géologiques dans les Taurus occidental au sud de Beyşehir (Turquie). Thèse de Doctorat, Université Paris – Sud (Orsay), 442 (yayınlanmamış).
  • Morford, J.L., Russell, A.D. ve Emerson, S. 2001. Trace metal evidence for changes in redox environment associated with the transition from terrigenous clay to diatomaceous sediment, Saanich Inlet, BC. Marine Geology, 174, 355–369.
  • Murphy, A.E., Sageman, B.B., Hollander, D.J., Lyons, T.L. ve Brett, C.E., 2000. Black shale deposition and faunal overturn in the Devonian Appalachian Basin: clastic starvation, seasonal watercolumn mixing, and efficient biolimiting nutrient recycling. Paleoceanography, 15, 280– 291.
  • Nesbitt, H.W. ve Young, G.M., 1984. Prediction of some weathering trends of plutonic and volcanic rocks based on thermodynamic and kinetic considerations. Geochimica et Cosmochimica Acta, 48, 1523–1534.
  • ——— ve ———, 1989. Formation and diagenesis of weathering profiles. Journal of Geology, 97, 129–147.
  • Nijenhuis, I.A., Bosch, H.-J., Sinninghe Damsté, J.S., Brumsack, H.-J.ve De Lange, G.J., 1999. Organic matter and trace element rich sapropels and black shales: a geochemical comparison. Earth and Planetary Science Letters, 169, 277–290.
  • Pedersen, T.F. ve Calvert, S.E., 1990. Anoxia vs. productivity: what controls the formation of organic-carbon-rich sediments and sedimentary rocks? American Association of Petroleum Geologists Bulletin, 74, 454– 466.
  • Pettijohn, F.J., Potter, P.R. ve Siever, R., 1987. Sand and sandstones. Springer, New York, 2nd edition. 553p.
  • Potter, P.E., 1978. Petrology and chemistry of modern big river sands. Journal of Geology, 86, 423–449.
  • Rimmer, S.M., Thompson, J.A., Goodnight, S.A. ve Robl, T.L., 2004. Multiple controls on the preservation of organic matter in Devonian–Mississippian marine black shales: geochemical and petrographic evidence. Palaeogeography, Palaeoclimatology, Palaeoecology, 215, 125–154
  • Roaldset, E., 1972. Mineralogy and geochemistry of Quaternary clays in the Numedal Area, southern Norway. Norsk Geolisk Tidsskrift, 52, 335– 369.
  • Roser, B.P. ve Korsch, R.J., 1986. Determination of tectonic setting of sandstone mudstone suites using SiO2 content and K2O/Na2O ratio. Journal of Geology, 94, 635–650.
  • Ross, D.J.K. ve Bustin, R.M., 2006. Sediment geochemistry of the Lower Jurassic Gordondale Member, northeastern British Columbia. Bulletin of Canadian Petroleum Geology, 54, 337–365.
  • Ruttenberg, K.C. ve Goñi, M.N., 1997. Phosphorus distribution, C:N:P ratios, and 13C in arctic, temperate, and tropical coastal sediments: tools for characterizing bulk sedimentary organic matter. Marine Geology, 139, 123– 145.
  • Sarı, A., Sonel, N. ve Doğan A.O, 1997. ÜzümlüÇamlık arasında kalan bölgenin Stratigrafisi (Beyşehir Güneyi, Konya). Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 2, 17–38.
  • ———-, Koca, D., Koc, S., Yavuz, B. ve Koralay, D.B., 2008. Üst Jura denizel fasiyeslerinde iz element birikimlerinde organik madde içeriğinin rolü (Orta Toroslar, Türkiye). Selçuk Üniversitesi Mühendislik- Mimarlık Fakültesi Dergisi, 23, 43-56.
  • Selby, M.J., 1993. Hillslope Materials and Processes. 2nd Edition Oxford University Press, Oxford, 480 p.
  • Sethie, P. S., Hannigan, R.E. ve Leithold, E.L., 1998. Rare-earth element chemistry of Cenomanian–Turonian shales of the North American Greenhorn Sea, Utah. In: Schieber, J., W. Zimmerle, and P. Sethi (ed). Shales and Mudstones II:E. Schweizerbart’sche Verlagsbuchhandlung, Stuttgart, 296p.
  • Sonel, N., Sarı, A., Doğan, A.O. ve Bozüyük, İ., 1995. Üzümlü (Beyşehir) civarının kaynak kaya fasiyesleri ve petrol oluşumunun organik jeokimyasal yöntemlerle incelenmesi. Türkiye Jeoloji Kurultayı Bülteni, 10, 34–40.
  • Suees, E., Kulm, L.D. ve Killingley, J.S., 1987. Coastal upwelling and a history of organic-rich mudstone deposition off Peru. : In: J.Brooks and A.J. Fleet (ed). Marine Petroleum Source Rocks. Geological Society Special publication, 26, 181-197.
  • Toker, V., Sonel, N., Ayyıldız, T. ve Albayrak, M., 1993. Akseki Kuzeyi–Üzümdere (Antalya) civarının stratigrafisi. Türkiye Jeoloji Kurultayı Bülteni, 36, 57–71.
  • Tribovillard, N., Algeo, T.J., Lyons, T. ve Riboulleau, A., 2006. Trace metals as paleoredox and paleoproductivity proxies: An update. Chemical Geology, 232, 12-32.
  • van Cappellen, P. ve Ingall, E.D., 1994. Benthic phosphorus regeneration, net primary production and ocean anoxia: a model of the coupled marine biogeochemical cycles of carbon and phosphorus. Paleoceanography, 9, 677-692.
  • Vogt, T., 1927. Sulitjelmafeltets geologi og petrografi. Norges Geologiske Undersokelse, 121, 1– 560 (in Norwegian, with English abstract).
  • Warning, B. ve Brumsack, H.J. 2000. Trace metal signatures of Mediterranean sapropels. Palaeogeography, Palaeoclimatology, Palaeoecology, 158, 293–309.
Maden Tetkik ve Arama Dergisi-Cover
  • ISSN: 0026-4563
  • Yayın Aralığı: Yılda 3 Sayı
  • Başlangıç: 1950
  • Yayıncı: Cahit DÖNMEZ