Nano–Boyutta Alüminyum Partikülü ile Basic Blue 11’in Sonokatalitik Oksidasyonunun İncelenmesi

Tekstil endüstrisinde yüksek konsantrasyonda organik madde ve boya içerikli renkli atıksu açığa çıkmaktadır. Bu tür atıksuların arıtılabilirliğinde yaygın olarak kimyasal veya ileri oksidasyon prosesleri kullanılmaktadır. Son zamanlarda sıfır yüklü partiküller (Al0, Cu0, Fe0, Mg0, Ni0, Zn0) kullanılarak suda bulunan kirleticilerin giderimi konusunda çalışmalar yer almaktadır. Çalışma kapsamında, kesikli reaktör düzeneğinde ultrases (US–40 kHz) ve nano–boyutta sıfır yüklü alüminyum (nZVAl) partikülünün tekli ve birleşik (US/nZVAl) proses uygulamalarının Basic Blue 11 (BB11) boya gideriminde pH, nZVAl dozu ve reaksiyon süresi parametrelerinin etkisi araştırılmıştır. Elde edilen sonuçlara göre, nZVAl partikülünün adsorpsiyon kapasitesinin pH 10 değerinde daha iyi olduğu tespit edilmiştir. Ultrases prosesinin tek başına etkisi az iken, nZVAl partikülü tek başına kullanıldığında 0.40 g nZVAl dozunda 60 dk’ da elde edilen benzer sonuç, birleşik US/nZVAl prosesi kullanıldığında 0.20 g dozda elde edilmiştir. Ultrases etkisi altında nZVAl partikül çap boyutu küçüldüğünden ve yüzey alanı arttığından daha düşük dozda ve kısa sürede BB11 giderimi elde edilmiştir. nZVAl partikülünün BB11 gideriminde geri kazanımı ve tekrar kullanılabilirliği araştırılmış ve nZVAl tek kullanıldığında 5 kez kullanılırken, birleşik US/nZVAl uygulandığında 8 kez tekrar kullanılabileceği ortaya konmuştur. nZVAl ve ultrases proses ile boya adsorpsiyonun Langmuir izotermine ve ikinci dereceden adsorpsiyon kinetiğine uygun olduğu tespit edilmiştir.

Anahtar Kelimeler:

Basic Blue 11, İleri Oksidasyon Prosesi, Sıfır yüklü alüminyum, İzoterm, Kinetik, Ultrases

Investigation of the Effect of Nano-Scale Aluminum Particle and Ultrasound Process on Basic Blue 11 Removal

In the textile industry, colored wastewater containing high concentrations of organic matter and dyes is released. Chemical or advanced oxidation processes are commonly used in the treatment of such wastewaters. Recently, there have been studies on the removal of pollutants in water using zero–valent particles (Al0, Cu0, Fe0, Mg0, Ni0, Zn0). Within the scope of the study, the effects of the alone and combined (US/nZVAl) process applications of ultrasound (US–40 kHz) and nano-sized zero-charged aluminum (nZVAl) particles in batch reactor setup on pH, nZVAl dose, and reaction time parameters were investigated in terms of Basic Blue 11 (BB11) dye removal. According to the results obtained, it was determined that the adsorption capacity of the nZVAl particle was better at pH 10. When the effect of the ultrasound process alone was low, a similar result, which was obtained in 60 minutes at a dose of 0.40 g nZVAl when the nZVAl particle was used alone, was obtained at a dose of 0.20 g using the combined US/nZVAl process. Since the nZVAl particle diameter size decreased and the surface area increased under the effect of ultrasound, BB11 removal was obtained at a lower dose and in a short time. The recovery and reusability of the nZVAl particle in BB11 removal was investigated, and it was found out that while nZVAl was used 2 times when used alone, it could be reused 5 times when the combined US/nZVAl process was applied. It was also determined that dye adsorption with nZVAl and the ultrasound process was in accordance with the Langmuir isotherm and second order adsorption kinetics.

Keywords:

Basic Blue 11, Advanced Oxidation Process, Isotherm, Kinetic, Zero–valent aluminium, Ultrasound,

PDF

___

Abd El–Lateef, H.M., Khalaf, M., Saleh, M., 2018. Adsorption and removal of cationic and anionic surfactants using zero–valent iron nanoparticles. J. Mol. Liq. 268: 497–505. 10.1016/j.molliq.2018.07.093
Abid, M.F., Zablouk, M.A., Abid–Alameer, A.M., 2012. Experimental study of dye removal from industrial wastewater by membrane technologies of reverse osmosis and nanofiltration. IJEHSE. 9 (1): 1–9. 10.1186/1735-2746-9-17
AboliGhasemabadi, M., Mbarek, W.B., Cerrillo–Gil, A., Roca–Bisbe, H., Casabella, O., Blanquez, P., Pineda, E., Escoda, L., Sunol, J.J., 2020. Azo–dye degradation by Mn–Al powders. J. Environ. Manage. 25: 110012. 10.1016/j.jenvman.2019.110012
Ayyıldız, Ö., Acar, E., İleri, B., 2016. Sonocatalytic reduction of hexavalent chromium by metallic magnesium particles. Water Air Soil Pollut. 227: 1–9. 10.1007/s11270-016-3065-y
Atacag Erkurt, H., 2010. The Handbook of Environmental Chemistry. Biodegradation of Azo Dyes. Springer‐Verlag Berlin Heidelberg, 9. 222 s.
Beckett, M.A., Hua, I., 2001. Impact of ultrasonic frequency on aqueous sonoluminescence and sonochemistry. J. Phys. Chem. 105 (15): 3796–3802. 10.1021/jp003226x
Bisschops, I., Spanjers, H., 2003. Literature review on textile wastewater characterization. Environ. Technol. 24 (11): 1399–1411. 10.1080/09593330309385684
Bokare, A.D., Choi, W., 2009. Zero–valent aluminum for oxidative degradation of aqueous organic pollutants. Environ. Sci. Technol. 43 (18): 7130–7135. 10.1021/es9013823
Breitbach, M., Bathen, D., Schmidt–Traub, H., 2003. Effect of ultrasound on adsorption and desorption processes. Ind. Eng. Chem. Res. 42 (22): 5635–5646. 10.1021/ie030333f
Brotchie, A., Borisova, D., Belova, V., Möhwald, H., Shchukin, D., 2012. Ultrasonic modification of aluminum surfaces: comparison between thermal and ultrasonics effects. J. Phys. Chem. 116 (14): 7952–7956. 10.1021/jp3016408
Cai, M.Q., Wei, X.Q., Song, Z.J., Jin, M.C., 2015. Decolorization of azo dye Orange G by aluminum powder enhanced by ultrasonic irradiation. Ultrason. Sonochem. 22: 167–173. 10.1016/j.ultsonch.2014.06.023
Cai, M., Su, J., Lian, G., Wei, X., Dong, C., Zhang, H., Jin, M., Wei, Z., 2016. Sono–advanced fenton decolorization of azo dye Orange G: analysis of synergistic effect and mechanisms. Ultrason. Sonochem. 31: 193–200. 10.1016/j.ultsonch.2015.12.017
Chen B., Wang, X., Wang, C., Jiang, W., Li, S., 2011. Degradation of azo dye direct sky blue 5B by sonication combined zero–valent iron. Ultrason. Sonochem. 18 (5): 1091–1096. 10.1016/j.ultsonch.2011.03.026
Cheng, Z., Fu, F., Pang, Y., Tang, B., Lu, J., 2015. Removal of phenol by acid–washed zero–valent aluminum in the presence of H2O2. Chem. Eng. Sci. 260: 284–290. 10.1080/19443994.2015.1006259
Chien, S.H., Clayton, W.R., 1980. Application of elovich equation to the kinetics of phosphate release and sorption in soils. Soil Sci. Soc. Am. J. 44: 265–268. 10.2136/sssaj1980.03615995004400020013x
Deng, D., Lamssali, M., Aryal, N., Ofori–Boadu, A., Jha, M. K., Samuel, R.E., 2020. Textiles wastewater treatment technology: a review. Water Environ. Res. 92 (10): 1805–1810. 10.1002/wer.1437
Du, J., Che, D., Li, X., Guo, W., Ren, N., 2017. Factors affecting p–nitrophenol removal by microscale zero–valent iron coupling with weak magnetic field. RSC Adv. 7: 18231–18237. 10.1039/C7RA02002C
Dutta, S., Sahaa, R., Kalita, H., Bezbaruah, A.N., 2016. Rapid reductive degradation of azo andanthraquinone dyes by nanoscale zero–valent iron. Environ. Technol. Innov. 5: 176–187. 10.1016/j.eti.2016.03.001
Eren, Z., 2012a. Ultrasound as a basic and auxiliary process for dye remediation: a review. J. Environ. Manage. 104: 127–141. 10.1016/j.jenvman.2012.03.028
Eren, Z., 2012b. Degradation of an azo dye with homogeneous and heterogeneous catalysts by sonophotolysis. Clean – Soil, Air, Water. 40 (11): 1284–1289. 10.1002/clen.201100384
Eren, Z., O’Shea, K., 2020. Definition of the optimum conditions of dual frequency (20 kHz+640 kHz) ultrasonic system by decolorization of Crystal Violet dye. J. Fac. Eng. Archit. Gaz. 35 (3): 1257–1268.
Esfahani, A.R., Datta, T., 2018. Nitrate removal from water using zero–valent aluminium. J. Water Environ. Technol. 34 (2020): 25–36. 10.1111/wej.12438
Fan, J., Guo, Y., Wang, J., Fan, M., 2009. Rapid decolorization of azo dye methyl orange in aqueous solution by nanoscale zerovalent iron particles. J. Hazard. Mater. 166 (2–3): 904–910. 10.1016/j.jhazmat.2008.11.091
Forgacs, E., Cserhati, T., Oros, G., 2004. Removal of synthetic dyes from wastewaters: a review. Environ. Int. 30 (7): 953–971. 10.1016/j.envint.2004.02.001
Freundlich, H., 1906. Adsorption in solution. Phys. Chem. Soc. 40: 1361–1368.
Fu, F., Dionysiou, D.D., Liu, H., 2014. The use of zero–valent iron for groundwater remediation and wastewater treatment: a review. J. Hazard. Mater. 267: 194–205. 10.1016/j.jhazmat.2013.12.062
Fu, F., Han, W., Cheng, Z., Tang, B., 2015a. Removal of hexavalent chromium from wastewater by acid–washed zero–valent aluminum. Desalin. Water Treat. 57, 5592–5600. 10.1080/19443994.2015.1006259
Fu, F., Cheng, Z., Dionysiou, D.D., Tang, B., 2015b. Fe/Al bimetallic particles for the fast and highly efficient removal of Cr(VI) over a wide pH range: performance and mechanism. J. Hazard. Mater. 298: 261–269. 10.1016/j.jhazmat.2015.05.047
Hamdy, A., Mostafa, K., Nasr, N., 2018. Zero–valent iron nanoparticles for methylene blue removal from aqueous solutions and textile wastewater treatment, with cost estimation. Water Sci. Technol. 78 (2): 367–378. 10.2166/wst.2018.306
Hassaan, M.A., El Nemr, A., 2017. Advanced oxidation processes for textile wastewater treatment. J. Photochem. Photobiol. C. 2 (3): 85–93. 10.11648/j.ijpp.20170203.13
Ho, Y, McKay, G., 1998. Pseudo–second order model for sorption processes. Process Biochem. 34: 451–465. 10.1016/S0032-9592(98)00112-5
Hsu, L.C., Chen, K.Y., Chan, Y.T., Deng, Y., Hwang, C.E., Liu, Y.T., Wang, S.L., Kuan, W.H., Tzou, Y.M., 2016. MS title: catalytic oxidation and removal of arsenite in the presence of Fe ions and zero–valent Al metals. J. Hazard. Mater. 317: 237–245. 10.1016/j.jhazmat.2016.05.071
Hwang, Y.H., Kim, D.G., Shin, H.S., 2011. Mechanism study of nitrate reduction by nano zero valent iron. J. Hazard. Mater. 185: 1513–1521. 10.1016/j.jhazmat.2010.10.078
İleri, B., Ayyıldız, O., Apaydın, O., 2015. Ultrasound–assisted activation of zero–valent magnesium for nitrate denitrification: identification of reaction by–products and pathways. J. Hazard. Mater. 292: 1–8. 10.1016/j.jhazmat.2015.03.004
İleri, B., 2016. Ultrases ve sıfır yüklü metal parti̇külleri̇ (Al0 ve Mg0) i̇le ni̇tratin deni̇tri̇fi̇kasyonu. Yıldız Teknik Üniversitesi Fen Bilimleri Enstitüsü, Çevre Mühendisliği Ana Bilim Dalı, Doktora Tezi. 118 s.
İleri, B., 2019. Removal of methyl red dye by adsorption process using modified fly ash with ultrasound process. Dokuz Eylul Univ. Fac. Engin. J. Sci. Eng. 21 (61): 25–40. 10.21205/deufmd.2019216103
İleri, B., Terzioğlu, O, Çiçi, Y., 2019. Nitrate chemical denitrification with zero–valent manganese and ultrasound. 5 (1): 32–48. 10.28979/comufbed.529912
İleri, B., Şanlıyüksel Yücel, D., 2020. Metal removal from acid mine lake using ultrasound-assisted modified fly ash at different frequencies. Environ. Monit. Assess. 192: 1–18. 10.1007/s10661-020-8150-4
İleri, B., 2022. Sono–assisted adsorption of acid violet 7 and basic violet 10 dyes from aqueous solutions: evaluation of isotherm and kinetic parameters. Environ. Eng. Res. 27 (1): 200287. 10.4491/eer.2020.287
Jiang, B., Xin, S., Gao, L., Luo, S., Xue, J., Wu, M., 2017. Dramatically enhanced aerobic Cr(VI) reduction with scrap zero–valent aluminum induced by oxalate. Chem. Eng. J. 308: 588–596. 10.1016/j.cej.2016.09.098
Khatri, J., Nidheesh, P.V., Singh, T.S.A., Suresh Kumar, M., 2018. Advanced oxidation processes based on zero–valent aluminium for treating textile wastewater. Chem. Eng. 348: 67–73. 10.1016/j.cej.2018.04.074
Lagergren, S. 1898. About the theory of so–called adsorption of soluble substances. Kung Sven Vetens Hand Band. 24: 1–39.
Langmuir, I., 1917. The adsorption of gases on plane surfaces of glass, mica, and platinum. J. Am. Chem. Soc. 40: 1361–1403. 10.1021/ja02242a004
Li, L., Hu, J., Shi, X., Fan, M., Luo, J., Wei, X., 2016. Nanoscale zero–valent metals: a review of synthesis, characterization, and applications to environmental remediation. Environ. Sci. Pollut. Res. 23: 17880–17900. 10.1007/s11356-016-6626-0
Li, S., Wang, W., Liang, F., Wei–Xian, Z., 2016. Heavy metal removal using nanoscale zero–valent iron (nZVI): theory and application. J. Hazard. Mater. 322 (Part A): 163–171. 10.1016/j.jhazmat.2016.01.032
Lien, H.L., Zhang, W., 2002. Enhanced dehalogenation of halogenated methanes by bimetallic Cu/Al. Chemosphere. 49: 371–378. 10.1016/S0045-6535(02)00248-5
Lien, H.L., Yu, C.C., Lee, Y.C., 2010. Perchlorate removal by acidified zero–valent aluminum and aluminum hydroxide. Chemosphere. 80 (8): 888–893. 10.1016/j.chemosphere.2010.05.013
Lin, C.J., Wang, S.L., Huang, P.M., Tzou, Y.M., Liu, J.C., Chen, C.C., Chen, J.H., Lin, C., 2009. Chromate reduction by zero–valent Al metal as catalyzed by polyoxometalate. Water Res. 43: 5015–5022. 10.1016/j.watres.2009.08.015
Liu, W., Zhang, H., Cao, B., Lin, K., Gan, J., 2011. Oxidative removal of bisphenol A using zero valent aluminum–acid system. Water Res. 45 (4): 1872–1878. 10.1016/j.watres.2010.12.004
Mahmoud, A.S., Farag, R.S., Elshfai, M.M., Mohamed, L.A., Ragheb, S.M., 2020. Nano zero–valent aluminum (nZVAl) preparation, characterization, and application for the removal of soluble organic matter with artificial intelligence, isotherm study, and kinetic analysis. Water Air Soil Pollut. 12: 1–13. 10.1177/1178622119878707
Marcelo, C.R., Puiatti, G.A., Nascimento, M.A., Oliveira, A.F., Lopes, R.P., 2018. Degradation of the reactive blue 4 dye in aqueous solution using zero–valent copper nanoparticles. J. Nanomater. 2018: 1–10. 10.1155/2018/4642038
Mason, T.J., Peters, D., 2001. Advances in sonochemistry, ultrasound in environmental protection. 6, JAI an Imprint of Elsevier Science, England.
McCafferty, E., 2003. Sequence of steps in the pitting of aluminum by chloride ions. Corros. Sci. 45 (7): 1421–1438. 10.1016/S0010-938X (02)00231-7
Mdlovu, N.V., Lin, K.S., Chen, C.Y., Mavuso, F.A., Kunene, S.C., Carrera Espinoza, M.J., 2019. In–situ reductive degradation of chlorinated DNAPLs in contaminated groundwater using polyethyleneimine–modified zero–valent iron nanoparticles. Chemosphere. 224: 816–826. 10.1016/j.chemosphere.2019.02.160
Nidheesh, P.V., Khatri, J., Singh, T.S.A., Gandhimathi, R., Ramesh, S.T., 2018. Review of zero–valent aluminium–based water and wastewater treatment methods. Chemosphere. 200: 621–631. 10.1016/j.chemosphere.2018.02.155
Pokhrel, N., Vabbina, P.K., Pala, N., 2016. Sonochemistry: science and engineering. Ultrason. Sonochem. 29: 104–128. 10.1016/j.ultsonch.2015.07.023
Qui, G., Wu, Y., Qi, L., Chen, C., Bao, L., Qui, M., 2018. Study on the degradation of azo dye wastewater by zero–valent iron. Nat. Environ. Pollut. Technol. 17 (2): 479–483.
Radha, K.V., Sridevi, V., Kalaivani, K., 2009. Electrochemical oxidation for the treatment of textile industry wastewater. Biores. Technol. 100: 987–990. 10.1016/j.biortech.2008.06.048
Raman, C.D., Kanmani, S., 2016. Textile dye degradation using nano zero valent iron: a review. J. Environ. Manage. 177 (15): 341–355. 10.1016/j.jenvman.2016.04.034
Rezaee, A., Ghaneian, M. T., Hashemian, S.J., Moussavi, G., Khavanin, A., Ghanizadeh, G., 2008a. Decolorization of reactive blue 19 dye from textile wastewater by the UV/H2O2 Process. Res. J. Appl. Sci. 8, 1108–1112. 10.3923/jas.2008.1108.1112
Sharma, S. Kaur, A., 2018. Various methods for removal of dyes from industrial effluents–a review. Indian J. Sci. Technol. 11 (12): 1–21. 10.17485/ijst/2018/v11i12/120847
Singh, K., Arora, S., 2011. Removal of synthetic textile dyes from wastewaters: a critical review on present treatment technologies. Crit. Rev. Environ. Sci. Technol. 41: 807–878. 10.1080/10643380903218376
Taherkhani, S., Khani, A., 2019. Preparation of nanosized zero–valent zinc (Zn0) immobilized on ZnO as redox nanocomposite for degradation of methyl orange from aqueous solution. J Environ. Health Sustain. Dev. 4 (1): 557–66. 10.18502/jehsd.v4i1.486
Treviño, P., Ibanez, J.G., Vasquez–Medrano, R., 2014. Chromium (VI) reduction kinetics by zero–valent aluminum. Int. J. Electrochem. Sci. 9: 2556–2564.
Wang, A., Guo, W., Hao, F., Yue, X., Leng, Y., 2014. Degradation of acid orange 7 in aqueous solution by zero–valent aluminum under ultrasonic irradiation. Ultrason. Sonochem. 21 (2): 572–575. 10.1016/j.ultsonch.2013.10.015
Wang, W., Zhao, P., Hu, Y., Zan, R., 2020. Application of weak magnetic field coupling with zero–valent iron for remediation of groundwater and wastewater: a review. J. Clean. Prod. 262: 121341. 10.1016/j.jclepro.2020.121341
Weber, W.J., Morris, J.K., 1963. Kinetics of adsorption on carbon from solution. J. Sanit. Eng. Div. 89: 31–60. 10.1061/JSEDAI.0000467
Wu, S., Yang, S., Li, Q., Wang, M., Xue, Y., 2021. Iron(II) sulfate crystals assisted mechanochemical modification of microscale zero–valent aluminum (mZVAl) for oxidative degradation of phenol in water. Chemosphere. 274: 129767. 10.1016/j.chemosphere.2021.129767
Xei, S., Yang, Y., Gai, W.Z., Deng, Z.Y., 2021. Oxide modified aluminum for removal of methyl orange and methyl blue in aqueous solution. RSC Adv. 11: 867. 10.1039/D0RA09048D
Yagub, M.T., Sen, T.K., Afroze, S., Ang, H.M., 2014. Dye and its removal from aqueous solution by adsorption: a review. Adv. Colloid Interface Sci. 209: 172–184. 10.1016/j.cis.2014.04.002
Yang, B., Deng, S., Yu, G., Lu, Y., Zhang, H., Xiao, J., Chen, G., Cheng, X., Shi, L., 2013. Pd/Al bimetallic nanoparticles for complete hydrochlorination of 3–chlorophenol in aqueous solution. Chem. Eng. J. 219: 492–498. 10.1016/j.cej.2012.11.108
Yang, S., Zheng, D., Chang, S., Shi, C., 2016. Zero valent aluminum based oxidation/reduction technology applied in water treatment. Prog. Chem. 28 (5): 754–762. 10.7536/PC151047
Yang, S., Zheng, D., Ren, T., Zhang, Y., Xin, J., 2017. Zero–valent aluminum for reductive removal of aqueous pollutants over a wide pH range: performance and mechanism especially at near–neutral pH. Water Res. 123: 704–714. 10.1016/j.watres.2017.07.013
Yaseen, D.A., Scholz, M., 2018. Textile dye wastewater characteristics and constituents of synthetic effluents: a critical review. Int. J. Environ. Sci. Technol. 16 (4): 1193–1226. 10.1007/s13762-018-2130-z