Ecologic Impact Analysis of Epoxidized Vegetable Oils Used at Polymer Production
Ecologic Impact Analysis of Epoxidized Vegetable Oils Used at Polymer Production
As reported in recent reviews and books, vegetable-based oils have been utilized for centuries in the manufacturing of inks, coatings, agrochemicals, plasticizers, and lubricants. Lately, epoxidized vegetable-based oils are having larger interest as they are obtained from renewable, sustainable natural sources and are environment-friendly. Epoxidized vegetable-based oil can act as a feedstock for synthesis of chemicals’ diversity including lubricants, carbonyl compound, glycol, polyols, plasticizers for polymerization etc. due to their oxirane ring’s high reactivity and significant oxirane oxygen content. At the same time, epoxidized vegetable-based oil has the potential to turn into a principal sustainable raw material in regards to the beneficial environmental effects. The environmental effects of general properties are different as in the case of the accumulated ecological effects from epoxidized vegetable-based oil plantation through refining to manufacture each of vegetable-based oils. In this study, comparison of eight different epoxidized vegetable oils in terms of ten factors is analyzed with multi-criteria decision making model. The primary factors (acid value, iodine value, oxirane value, thermal conductivity coefficient, density, boiling point, ignition point, viscosity, resin, and cross-linker) of general properties of epoxidized oil manufactured from vegetable-based oil are evaluated. The most environment-friendly epoxidized vegetable-based oil is determined.
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- [1]. Adekunle, K., Patzelt, C., Kalantar, A., & Skrifvars, M. (2011). Mechanical and viscoelastic properties of soybean oil thermoset reinforced with jute fabrics and carded lyocell fiber. Journal of Applied Polymer Science, 122(5), 2855-2863.
- [2]. Biermann, U., Bornscheuer, U., Meier, M. A., Metzger, J. O., & Schäfer, H. J. (2011). Oils and fats as renewable raw materials in chemistry. Angewandte Chemie International Edition, 50(17), 3854-3871.
- [3]. Belgacem, M.N. & Gandini, A. (2008) Materials from Vegetable Oils: Major Sources, Properties and Applications. Monomers, Polymers and Composites from Renewable Resources, Chapter 3, 39-66.
- [4]. Samarth, N. B., & Mahanwar, P. A. (2015). Modified vegetable oil based additives as a future polymeric material. Open Journal of Organic Polymer Materials, 5(01), 1.
- [5]. Hui, Y. H. (1995). Bailey’s Industrial Oil and Fats Products, Edible Oil and Fat Products: General Application. Vol. 1.
- [6]. Xia, Y., & Larock, R. C. (2010). Vegetable oil-based polymeric materials: synthesis, properties, and applications. Green Chemistry, 12(11), 1893-1909.
- [7]. Wool, R.P., & Sun, X.S. (2005) Polymers and Composite Resins from Plant Oils in Bio-Based Polymers and Composites. Elsevier Academic Press, Burlington, 6-113.
- [8]. Ronda, J. C., Lligadas, G., Galià, M., & Cádiz, V. (2011). Vegetable oils as platform chemicals for polymer synthesis. European Journal of Lipid Science and Technology, 113(1), 46-58.
- [9]. Güner, F. S., Yağcı, Y., & Erciyes, A. T. (2006). Polymers from triglyceride oils. Progress in Polymer Science, 31(7), 633-670.
- [10]. Sharma, V., & Kundu, P. P. (2006). Addition polymers from natural oils—a review. Progress in polymer science, 31(11), 983-1008.
- [11]. Qureshi, S., Manson, J. A., Sperling, L. H., & Murphy, C. J. (1983). Polymer Applications of Renewable-Resource Materials. Plenum Press, New York, NY, 249-71.
- [12]. Barrett, L. W., Sperling, L. H., & Murphy, C. J. (1993). Naturally functionalized triglyceride oils in interpenetrating polymer networks. Journal of the American Oil Chemists’ Society, 70(5), 523-534.
- [13]. Mustata, F., Tudorachi, N., & Rosu, D. (2011). Curing and thermal behavior of resin matrix for composites based on epoxidized soybean oil/diglycidyl ether of bisphenol A. Composites Part B: Engineering, 42(7), 1803-1812.
- [14]. Miyagawa, H., Misra, M., Drzal, L. T., & Mohanty, A. K. (2005). Biobased epoxy/layered silicate nanocomposites: thermophysical properties and fracture behavior evaluation. Journal of Polymers and the Environment, 13(2), 87-96.
- [15]. Miyagawa, H., Mohanty, A. K., Burgueño, R., Drzal, L. T., & Misra, M. (2007). Novel biobased resins from blends of functionalized soybean oil and unsaturated polyester resin. Journal of Polymer Science Part B: Polymer Physics, 45(6), 698-704.
- [16]. Miyagawa, H., Mohanty, A. K., Drzal, L. T., & Misra, M. (2004). Nanocomposites from biobased epoxy and single-wall carbon nanotubes: synthesis, and mechanical and thermophysical properties evaluation. Nanotechnology, 16(1), 118.
- [17]. Tsujimoto, T., Uyama, H., & Kobayashi, S. (2003). Green Nanocomposites from Renewable Resources: Biodegradable Plant Oil‐Silica Hybrid Coatings. Macromolecular rapid communications, 24(12), 711-714.
- [18]. Dutta, N., Karak, N., & Dolui, S. K. (2004). Synthesis and characterization of polyester resins based on Nahar seed oil. Progress in organic coatings, 49(2), 146-152.
- [19]. Li, F., Hanson, M. V., & Larock, R. C. (2001). Soybean oil–divinylbenzene thermosetting polymers: synthesis, structure, properties and their relationships. Polymer, 42(4), 1567-1579.
- [20]. Zlatanić, A., Lava, C., Zhang, W., & Petrović, Z. S. (2004). Effect of structure on properties of polyols and polyurethanes based on different vegetable oils. Journal of Polymer Science Part B: Polymer Physics, 42(5), 809-819.