HCFC-22 YERİNE KULLANILAN BAZI HFC'LERİN ÇEVRESEL ETKİLERİNİN DENEYSEL OLARAK KARŞILAŞTIRILMASI

Bu çalışmada, HCFC-22 gazı yerine ozon tabakasına zarar vermeyen R417A ve R424A soğutucu akışkanlarının TEWI değerleri hesaplanıp, mukayese edilmiştir. Bir split klima cihazı için, ortalama 38?C çevre sıcaklığında, üç farklı soğutucunun tükettiği enerji miktarları deneysel olarak tespit edilmiştir. Soğutma ihtiyacı olan Mayıs-Eylül döneminde belli çalışma saatleri için yıllık enerji tüketimi hesaplanmıştır. Hesaplamalar sonucunda, GWP değeri yüksek olan R424A'nın doğrudan etkisi de yüksek olmuştur. R424A ve R417A'nın enerji tüketimleri R22'den %10 düşük olmasına rağmen, GWP değerlerinin yüksek olması sebebiyle, TEWI değerlerinin %2 -%4 oranında yüksek çıktığı tespit edilmiştir.

THE EXPERIMENTAL COMPARISON OF ENVIRONMENTAL IMPACTS OF SOME HFC'S USED INSTEAD OF HCFC-22

In this study, the TEWI values for R417A and R424A refrigerants instead of HCFC-22 gas which don't deplete ozone layer were calculated and then compared. For a split type air conditioning equipment, the energy consumption amounts were experimentally determined for the three different refrigerants at an average ambient temperature of 38?C. The annual energy consumption that is the cooling requirement was evaluated for the specific operating hours in May-September period. As a result of calculations, direct impact of R424A with the higher GWP value was also higher. It was found that although energy consumptions for both R424A and R417A were less than that for R22 by 10%, their TEWI values were to be higher with 2 to 4% because of their greater GWP magnitudes.

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  • Aprea C., Greco A., 1998, An experimental evaluation of the greenhouse effect in R22 substitution, Energy Conversion and Management 39, 877-887.
  • Aprea, C., Mastrullo, R., Renno, C. 2004, An analysis of the performances of a vapour compression plant working both as a water chiller and a heat pump using R22 and R417A, Applied Thermal Engineering, 24, 487-499.
  • Aprea, C., Renno, C. 2004, Experimental comparison of R22 with R417A performance in a vapour compression refrigeration plant subjected to a cold store, Energy Conversion and Management, 45, 1807-1819.
  • Aprea, C., Maiorino, A., Mastrullo, R. 2011, Change in energy performance as a result of a R422D retrofit: An experimental analysis for a vapor compression refrigeration plant for a walk-in cooler, Applied Energy, 88, 4742-4748.
  • Aprea, C., Maiorino, A. 2011, An experimental investigation of the global environmental impact of the R22 retrofit with R422D, Energy, 36, 1161-1170.
  • Aprea C., Greco A., Maiorino A., 2012, An experimental evaluation of the greenhouse effect in the substitution of R134a with CO2, Energy 45, 753-761.
  • Bolaji B.O., Huan Z., 2013, Ozone depletion and global warming: Case for the use of natural refrigerant - a review, Renewable and Sustainable Energy Reviews, 18, 49-54.
  • Cabello, R., Torrella, E., Llopis, R., Sánchez, D., Larumbe, J.A. 2013, Energy influence of the IHX with R22 drop-in and long-term substitutes in refrigeration plants, Applied Thermal Engineering, 50, 260-267.
  • Chen W., 2008, A comparative study on the performance and environmental characteristics of R410A and R22 residential air conditioners, Applied Thermal Engineering, 28, 1-7.
  • Davies T.W., Caretta O., 2004, A low carbon, low TEWI refrigeration system design, Applied Thermal Engineering, 24, 1119-1128.
  • Devotta S., Waghmare A.V., Sawant N.N., Domkundwar B.M., 2001, Alternatives to HCFC-22 for air conditioners, Applied Thermal Engineering, 21, 703-715.
  • DuPont, Thermodynamic properties of DuPont Freon 22 (R22) Refrigerant. "Technical Information". http://www2.dupont.com/Refrigerants/en_US/assets/downloads/k05736_Freon22_thermo_prop.pdf.
  • DuPont, Thermodynamic properties of DuPont Isceon MO59 (R417A). "Technical Information". http://www2.dupont.com/Refrigerants/en_US/assets/dow nloads/k15291_ISCEON_MO59_thermo_prop_si.pdf.
  • Kumbaroğlu G., Arıkan Y., 2009, Farkındalık ve fark yaratmak: Türkiye'nin CO2 salımları (Birinci Baskı), Açık Toplum Vakfı, İstanbul.
  • La Rocca V., Panno G., 2011, Experimental performance evaluation of a vapour compression refrigerating plant when replacing R22 with alternative refrigerants, Applied Energy, 88, 2809-2815.
  • Lemmon, E.W., Huber, M.L., McLinden, M.O., 2013. NIST Standard Reference Database 23: Reference Fluid Thermodynamic and Transport Properties-REFPROP, Version 9.1, National Institute of Standards and Technology, Standard Reference Data Program, Gaithersburg.
  • Llopis, R., Cabello, R., Sánchez, D., Torrella, E., Patiño, J., Sánchez, J.G. 2011, Experimental evaluation of HCFC-22 replacement by the drop-in fluids HFC-422A and HFC-417B for low temperature refrigeration applications, Applied Thermal Engineering, 31, 1323- 1331.
  • Llopis R., Torrella E., Cabello R., Sanchez D. 2012, HCFC-22 replacement with drop-in and retrofit HFC refrigerants in a two-stage refrigeration plant for low temperature, International Journal of Refrigeration, 35, 810-816.
  • Maykot R., Weber G. C., Maciel R.A., 2004, Using the TEWI Methodology to Evaluate Alternative Refrigeration, International Refrigeration and Air Conditioning Conference, Purdue, http://docs.lib.purdue.edu/cgi/viewcontent.cgi?article=1708&context=iracc.
  • Mohanraj M., 2013, Energy performance assessment of R430A as a possible alternative refrigerant to R134a in domestic refrigerators, Energy for Sustainable Development, 17, 471-476.
  • Oruç, V., Devecioğlu, A.D., 2015, Thermodynamic performance of air conditioners working with R417A and R424A as alternatives to R22, International Journal of Refrigeration, 55, 120-128.
  • Park, K.-J., Shim, Y.-B., Jung, D. 2009, A 'drop-in' refrigerant R431A for replacing HCFC22 in residential air-conditioners and heat pumps, Energy Conversion and Management, 50, 1671-1675.
  • Refrigerant Solutions Limited. "RS-44 (R424A)". http://www.refsols.com/files/RS-44/RS-44_Physical_data_&_retrofit.pdf.
  • Söğüt M.Z., 2012, Exergetic and environmental assessment of room air conditionersin Turkish market, Energy, 46, 32-41.
  • Söğüt M.Z., Karakoç H., 2013, Klimalarda enerji verimliliği sınıflandırılmasında farklı bir yaklaşım: ekserjetik verimlilik oranı ve çevresel etki oranı, 11. Ulusal Tesisat Mühendisliği Kongresi, İzmir, 859-871.
  • Wu X., Hu S., Mo S., 2013, Carbon footprint model for evaluating the global warming impact of food transport refrigeration systems, Journal of Cleaner Production, 54, 115-124.
  • Yang Z., Wu X., 2013, Retrofits and options for the alternatives to HCFC-22, Energy, 59, 1-2