Production of biodiesel from algal biomass collected from Solani River using Ultrasonic Technique

Production of biodiesel from algal biomass collected from Solani River using Ultrasonic Technique

Abstract-The present paper presents the production of bio-diesel from algal biomass collected from Solani aqua duct in Roorkee. The identification of algal sample shows the presence of Hydrodictyon recticulatum (L) Lagerheium with few vegetative filaments of ulotrichalean strain in it. The algal biomass contains about 14.47 wt % of lipid. The algal biomass was collected from Solani aqua duct and washed several times with water and dried on sunlight for three days then the algal-oil was extracted from pulverized biomass (100-125 µm particles).The most suitable conditions for the extraction of bio-oil using ultrasonic technique were found to be solvent to biomass ratio of 6, extraction time of 50 min. and amplitude percentage of 70% at 0.6 cycle/sec. Under these conditions around 51% of oil/lipid in the algal cells was extracted. The produced bio-oil was upgraded to biodiesel by transesterification using CH3ONa as catalyst. The catalyst shows ~ 80 % conversion of bio-oil to bio diesel. A comparison of ultrasonic extraction and Soxhlet extraction showed that ultrasonic extraction provides higher extraction efficiency with shorter extraction time.

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  • M. G. Kulkarni and A. K. Dalai, “Waste Cooking Oils An Economical Source for Biodiesel  : A Review,” pp. 2901–2913, 2006.
  • D. L. Klass, “Biomass for Renewable Energy and Fuels,” vol. 1, 2004.
  • C. Chellamboli and M. Perumalsamy, “Application of response surface methodology for optimization of growth and lipids in Scenedesmus abundans using batch culture system,” RSC Adv., vol. 4, no. 42, p. 22129, 2014.
  • X. Lang, A.K. Dalai, N. N. Bakhshi, M. J. Reaney, and P. B. Hertz, “Preparation and characterization of bio-diesels from various bio-oils,” Bioresour. Technol., vol. 80, no. 1, pp. 53–62, Oct. 2001.
  • P. Spolaore, C. Joannis-Cassan, E. Duran, and A. Isambert, “Commercial applications of microalgae,” J. Biosci. Bioeng., vol. 101, no. 2, pp. 87–96, Feb. 2006.
  • A. Singh, P. S. Nigam, and J. D. Murphy, “Mechanism and challenges in commercialisation of algal biofuels,” Bioresour. Technol., vol. 102, no. 1, pp. 26–34, Jan. 2011.
  • E. G. Shay, “Diesel fuel from vegetable oils: Status and opportunities,” Biomass and Bioenergy, vol. 4, no. 4, pp. 227–242, Jan. 1993.
  • S. Emeish, “Production of Biodiesel from Microalgae,” Journal of Energy Technology and Policy, vol. 3, no. 10, pp. 58–69, 2013.
  • J. Ferrentino and L.H Farag, “Microalgae oil extraction and in situ transesterification”, Master thesis, Chemical Engineering Department, University of New Hampshire, Durham, New Hampshire, 2007.
  • J. Luque-Garcı́a and M. Luque de Castro, “Ultrasound: a powerful tool for leaching,” TrAC Trends Anal. Chem., vol. 22, no. 1, pp. 41–47, Jan. 2003.
  • A.B.M. Sharif Hossain, A. Salleh , A. N. Boyce, P. Chowdhury, and M. Naqiuddin “Biodiesel Fuel Production from Algae as Renewable Energy”, American Journal of Biochemistry and Biotechnology, vol. 4, no. 3, pp. 250–254, 2008.
  • N. K. Soni, A. K. Varma, P. Mondal, M.N.Srivastava, “Production of bio-oil from native algae of Solani Aqueduct Roorkee”, Green,vol.3, pp. 225-234, Dec. 2013.
  • Y. Tian, Z. Xu, B. Zheng, and Y. Martin Lo, “Optimization of ultrasonic-assisted extration of pomegranate (Punica granatum L.) seed oil.,” Ultrason. Sonochem., vol.20,no.1,pp.202-208, Jan. 2013.
  • G. Rajeswari and V. Rajagopalan, “Evaluation of Anti- Diabetic Effects of Chrysopogon zizanioides Linn Root Extracts in Streptozotocin Induced Diabeteic Wistar Rats,” vol. 2, no. 3, pp. 555–574, 2013.
  • K. Stehfest, J. Toepel, and C. Wilhelm, “The application of micro-FTIR spectroscopy to analyze nutrient stress- related changes in biomass composition of phytoplankton algae,” Plant Physiol. Biochem., vol. 43, no. 7, pp. 717– 26, Jul. 2005.
  • J. Coates, R. A. M. Ed, and J. Coates, “Interpretation of Infrared Spectra, A Practical Approach Interpretation of Infrared Spectra, A Practical Approach,” pp. 10815– 10837, 2000.
  • M. Malpani, “Study of a heterogeneous catalyst for the production of biodiesel from oil extracted from algae collected locally from Solani River”, Master thesis, Department of Chemical Engineering, Indian Institute of Technology, Roorkee., 2013.
  • http://www.ultrasonic systems.com/ultrasonics/algae_extraction_01.htm
  • L. Yang, Y. Liu, Y. Zu, C. Zhao, L. Zhang, X. Chen, and Z. Zhang, “Optimize the process of ionic liquid- based ultrasonic-assisted extraction of aesculin and aesculetin from Cortex fraxini by response surface methodology,” Chem. Eng. J., vol. 175, pp. 539–547, Nov. 2011.
  • H. Abbasi, K. Rezaei, and L. Rashidi, “Extraction of Essential Oils From the Seeds of Pomegranate Using Organic Solvents and Supercritical CO2,” J. Am. Oil Chem. Soc., vol. 85, no. 1, pp. 83–89, Nov. 2007.