Saliha ÖZARSLAN, Mustafa DURGUN, Mustafa KAYA

Metal İçerikli Asit Çözeltisi ile Muamele Edilmiş Atık Asfaltın Hidrojen Üretiminde Katalizör Olarak Kullanımı

Orijinal Bilimsel Makale Bu çalışmada, asetik asit ile muamele edilmiş metal katkılı atık asfalt katalizörü kullanılarak sodyum bor hidrürün metanolizinde hidrojen sentezi gerçekleştirilmiştir. Farklı metal türleri denenerek en verimli metal türü belirlenmesinin ardından farklı oranlarda metal kullanılmış ve en etkin katalizör üretilmiştir. En verimli katalizör, 3M asetik asit ve % 30 Cu ile muamele edilmiş atık asfalt katalizörüdür. Seçilen katalizör varlığında, en yüksek hidrojen verimini elde etmek için farklı katalizör miktarları, farklı sodyum bor hidrür konsantrasyonları ve farklı sıcaklıklar kullanılarak deneyler yapılmış ve sonuçlar yorumlanmıştır. Maksimum hidrojen üretimi verimi 9518,3 mLdk-1g-1 ve katalizörün aktivasyon enerjisi 38,2 kj/mol olarak belirlenmiştir.

Anahtar Kelimeler:

Atık Asfalt, Bakır, Hidrojen, Katalizör, Metal

Usage Of Waste Asphalt Treated with Metal Contained Acid Solution as a Catalyst in Hydrogen Production

In this study, hydrogen synthesis was carried out in the methanolysis of sodium borohydride using a metal added waste asphalt catalyst treated with acetic acid. After trying different metal types and determining the most efficient metal type, different ratios of metal were used and the most effective catalyst was produced. The most efficient catalyst is waste asphalt catalyst treated with 3M acetic acid and 30% Cu. In the presence of the selected catalyst, experiments were carried out using different catalyst amounts, different sodium boron hydride concentrations and different temperatures to obtain the highest hydrogen yield, and the results were interpreted. The maximum hydrogen generation efficiency was determined as 9518.3 ml min-1 g-1 and the activation energy of the catalyst was determined as 38.2 kj/mol.

Keywords:

Catalyst, Copper, Hydrogen, Metal, Waste Asphalt,

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