Synthesis of Ti-TiAl3 Composite by Resistive Sintering

Synthesis of Ti-TiAl3 Composite by Resistive Sintering

In the present work, Ti-TiAl3 metallic-intermetallic in situ composites were synthesized by one step resistive sintering method. Process time had been completed in 90 second using 1.5-1.7 Volt and 2000 Amper direct current. Ti and Al elemental powders were mixed by the stoichiometric ratio corresponding to the TiAl3 intermetallic phases' with molar proportion of 1:3. We aimed to obtain some residual ductile Ti phase as well as the TiAl3 major phase in structure. XRD analyses detected the only phases in the composite were Ti and TiAl3. TiAl2 phase also detected as trace peak in the XRD Chart. SEM examinations showed a dense microstructure with low amount of porosity. The relative density of the sample measured according to Archimedes’ principle was 98,7%, and the microhardness of the sample was about 455±20 HV.

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  • [1] M. H. Erdoğan, M. İpek, G. F. Ç. Efe, S. Zeytin, C. Bindal, "Toz Metalurjisi Yöntemi ile Niyobyum Aluminid Üretimi ve Karakterizasyonu," in 14.th International Materials Symposium, IMSF 2012, Pamukkale University, Denizli, Turkey.
  • [2] J. Cao, J. Feng, Z. Li, Effect of reaction heat on reactive joining of TiAl intermetallics using Ti–Al–C interlayers, Scripta Materialia. 57, 421, (2007). DOI: 10.1016/j.scriptamat.2007.04.048.
  • [3] N. Cinca, C. R. C. Lima, J. M. Guilemany, An overview of intermetallics research and application: Status of thermal spray coatings, Journal of Materials Research and Technology. 2, 75, (2013). DOI: 10.1016/j.jmrt.2013.03.013.
  • [4] W. Chen, H. Xiao, Z. Fu, S. Fang, D. Zhu, Reactive hot pressing and mechanical properties of TiAl3/Ti3AlC2/Al2O3 in situ composite, Materials & Design. 49, 929, (2013). DOI: 10.1016/j.matdes.2013.02.053.
  • [5] R. Orrù, R. Licheri, A. M. Locci, A. Cincotti, G. Cao, Consolidation/synthesis of materials by electric current activated/assisted sintering, Materials Science and Engineering: R: Reports. 63, 127, (2009). DOI: 10.1016/j.mser.2008.09.003.
  • [6] T. Yener, S. Okumus, S. Zeytin, In Situ Formation of Ti-TiAl 3 Metallic-Intermetallic Composite by Electric Current Activated Sintering Method, Acta Physica Polonica A. 127, 917, (2015). DOI: 10.12693/APhysPolA.127.917.
  • [7] T. Yener, S. Zeytin, Synthesis And Characterization Of Metallic-Intermetallic Ti-TiAl3, Nb-Ti-TiAl3 Composites Produced With Electric-Current-Activated Sintering (ECAS), Materiali in tehnologije. 48, 847, (2014). DOI: UDK 66.017:621.762.5.
  • [8] T. Yener, S. C. Yener, and S. Zeytin, “Electromagnetic-shielding effectiveness and fracture behavior of laminated (Ni–NiAl3) composites,” Mater. Tehnol., vol. 50, no. 6, pp. 899–902, 2016.
  • [9] T. D. Huy, H. Fujiwara, R. Yoshida, D. T. Binh, H. Miyamoto, Microstructure and Mechanical Properties of TiAl3/Al2O3 in situ Composite by Combustion Process, Materials Transactions. 55, 1091, (2014). DOI: 10.2320/matertrans.Y-M2014823.