Mechanical characterization of pack-boronized AISI 4140 and AISI H13 steels

Wear losses have a great importance in the world machinery industry. They cause billions of dollars in financial losses every year. Studies on surface treatments are increasing day by day in order to minimize the wear losses of materials. In this study, the pack boronizing process was applied to AISI 4140 and AISI H13 steels, which are frequently used in the manufacturing and molding industry, by using Ekabor II powder at 900 °C and 950 °C for 4 and 6 hours. Microstructural examinations of the samples subjected to metallographic processes were carried out. Afterwards, microhardness measurements were performed by applying 50 gf load for 10 seconds. Wear tests were carried out using pin-on-disk tribotests in a dry environment under 2 N and 5 N loads on the CSM Tribometer device. Wear losses were measured as volumetric loss. Thanks to the boronizing process, surface quality, surface hardness, and wear resistance of both steel materials were increased at a high rate.

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  • 1. Budinski, K.G., The Wear of Diffusion Treated Surfaces, Wear, 1993. 162-164: p. 757-762.
  • 2. Venkataraman, B. and Sundararajan, G., The High Speed Sliding Wear Behavior of Boronized Medium Carbon Steel, Surface and Coatings Technology, 1995. 73: p. 177-184.
  • 3. Küper, A., Qiao, X., Stock, H.R. and Mayr, P., A Novel Approach to Gas Boronizing, Surface and Coatings Technology, 2000. 130(1): p. 87-94.
  • 4. Tabur, M., Izciler, M., Gul, F. and Karacan, I. Abrasive wear behavior of boronized AISI 8620 steel, Wear, 2009. 266: p. 1106–1112.
  • 5. Ulutan, M., Celik, O., Gasan, H. and Er, U. Effect of Different Surface Treatment Methods on the Friction and Wear Behavior of AISI 4140 Steel, Journal of Materials Science & Technology. 2010. 26: p. 251–257.
  • 6. Gunes, I., Wear Behavior of Plasma Paste Boronized of AISI 8620 Steel with Borax and B2O3 Paste Mixtures, Journal of Materials Science & Technology, 2013. 29: p. 662–668.
  • 7. Sinha, A.K., Boriding (Boronizing). 1991, Materials Park USA: ASM International Handbook, The Materials International Society. 4: p. 437–447.
  • 8. Stewart, K., Boronizing protects metals against wear, Advanced Materials and Processes, 1997. 151(3): p. 23–25.
  • 9. Gök, M., Küçük, Y., Erdoğan, A., Öge, M., Kanca, E. and Günen, A., Dry sliding wear behavior of borided hot-work tool steel at elevated temperatures, Surface and Coatings Technology, 2017. 328: p. 54–62.
  • 10. Soydan, Y., Köksal, S., Demirer, A. and Çelik, V., Sliding Friction and Wear Behavior of Pack-Boronized AISI 1050, 4140, and 8620 Steels, Tribology Transactions, 2008. 51(1): p. 74–81.
  • 11. Hu, R., Fenske, G.R., Rehn, L.E., Baldo, P.M., Erdemir, A., Lee, R.H. and Erck, R.A., Tribological performance of ion-beam-mixed Fe/B multilayers on M50 steel, Surface and Coatings Technology, 1990. 42(3): p. 283–297.
  • 12. Petrova, R.S., Suwattananont, N. and Samardzic, V., The effect of boronizing on metallic alloys for automotive applications, Journal og Materials Engineering and Performance, 2008. 17: p. 340–345.
  • 13. Lin, Y.C., Chen, M.S. and Zhong, J., Effects of deformation temperatures on stress/strain distribution and microstructural evolution of deformed 42CrMo steel, Materials&Design, 2009. 30: p. 908–913.
  • 14. Lin, Y.C., Chen, M.S. and Zhong, J., Effect of temperature and strain rate on the compressive deformation behavior of 42CrMo steel, Journal of Materials Processing Technology, 2008. 205: p. 308–315.
  • 15. Kara, R., Çolak, F. and Kayali, Y., Effect of temperature and strain rate on the compressive deformation behavior of 42CrMo steel, Transactions of the Indian Institute of Metals, 2016. 69(6): p. 1169–1177.
  • 16. Taktak, S., Some mechanical properties of borided AISI H13 and 304 steels, Materials&Design, 2007. 28(6), p. 1836-1843.
  • 17. Hernandez, S., Hardell, J., Winkelmann, H., Ripoll, M.R. and Prakash, B., Influence of temperature on abrasive wear of boron steel and hot forming tool steels, Wear, 2015. 338-339, p. 27–35.
  • 18. Birol, Y., Sliding wear of CrN, AlCrN and AlTiN coated AISI H13 hot work tool steels in aluminium extrusion, Tribology International, 2013. 57, p. 101–106.
  • 19. We, M., Wang, S., Wang, L. and Chen, K., Effect of microstructures on elevated-temperature wear resistance of a hot working die steel, Journal of Iron and Steel Research, 2011. 18(10), p. 47-53.
  • 20. Birol, Y. and Isler, D., Abrasive wear performance of AlCrN-coated hot work tool steel at elevated temperatures under three-body regime, Wear, 2011. 270(3-4), p. 281-286.
  • 21. Degirmenci, D., Kisa, M., Ozen, M. and Demircan, G., Environmental effects on tribological behaviour of composite materials, International Advanced Researches and Engineering Journal, 2018. 2(3): p. 234-239.
  • 22. Vural, E. and Özel, S., The investigation of effect of the ceramic coatings with bond-layer coated on piston and valve surface on engine performance of a diesel engine, International Advanced Researches and Engineering Journal, 2020. 4(2): p. 87-93.
  • 23. Özel, S., Vural, E. and Binici, M., Taguchi method for investigation of the effect of TBC coatings on NiCr bond-coated diesel engine on exhaust gas emissions, International Advanced Researches and Engineering Journal, 2020. 4(1): p. 14-20.
  • 24. Ulutan, M., Yildirim, M.M., Çelik, O.N. and Buytoz, S. Tribological properties of borided AISI 4140 steel with the powder pack-boriding method, Tribology Letters, 2010. 38: p. 231–239.
  • 25. Cimenoglu, H., Atar, E. and Motallebzadeh, A., High temperature tribological behaviour of borided surfaces based on the phase structure of the boride layer, Wear, 2014. 309(1-2): p. 152–158.
  • 26. Cárdenas, E.E.V., Lewis, R., Pérez, A.I.M., Ponce, J.L.B., Pinal F.J.P., Domínguez, M.O. and Arreola, E.D.R., Characterization and wear performance of boride phases over tool steel substrates, Advances in Mechanical Engineering, 2016. 8(2): p. 1–10.
  • 27. Keddam, M., Ortiz-Domínguez, M., Gómez-Vargas, O.A., Arenas-Flores, A., Flores-Rentería, M.A., Elias-Espinosa, M. and García-Barrientos, A., Kinetic study and characterization of borided AISI 4140 steel, Materiali in Tehnologije, 2015. 49(5): p. 665-672.
  • 28. Günen, A., Karahan, İ.H., Karakaş, M.S., Kurt, B., Kanca, Y., Çay, V.V. and Yıldız, M., Properties and corrosion resistance of AISI H13 hot‑work tool steel with borided B4C, Metals and Materials International, 2019. 26(11): p. 1-12.
  • 29. Krelling, A.P., Milan, J.C.G. and Costa, C.E., Tribological behaviour of borided H13 steel with different boriding agents, Surface Engineering, 2015. 31(8): p. 581-587.
  • 30. Selcuk, B., Ipek, R. and Karamis, M.B., A study on friction and wear behaviour of carburized, carbonitrided and borided AISI 1020 and 5115 steels, Journal of Materials Processing Technology, 2003. 141(2): p. 189–196.