Zeynel OZTURK, Dursun Ali KOSE, Abdurrahman ASAN, Goksel OZKAN

Porous metal-organic Cu II complex of L-Arginine; synthesis, characterization, hydrogen storage properties and molecular simulation calculations

Cu II -arginine coordination compound was synthesized and characterized by using DSC, DTA, EA, FT-IR, XRD, SEM and EDX analysis techniques and then the hydrogen storage properties were investigated. Hydrogen storage performance of synthesized compound was determined both experimental and theoretically by using Materials Studio which is one of the Molecular simulation software and adsorption measurement equipment. It is found out that the arginine compound uptakes approximately 1.2 wt. % experimentally and 0.8 wt. % theoretically hydrogen in 77K and 100 bars pressure. Also the surface characteristics was calculated and also the possible cites which could uptake hydrogen in a single lattice cell were determined. At the end of this research, in addition to drug and other applications of L-arginine, it is proved that could be used as a part of adsorbent for hydrogen storage application.

Keywords:

Hydrogen Storage Cu-II compound, L-Arginine, Coordination Compound, Molecular Simulation.,

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1. Crabtree GW, Dresselhaus MS, Buchannan MV. The Hydrogen Economy. Physics Today 57 (2004) 39-46.
2. Rowsell JLC, Yaghi OM. Strategies for Hydrogen Storage in Metal–Organic Frameworks. Angewandte Chemie 44 (2005) 4670–4679.
3. Muradov NZ, Veziroglu TN. From hydrocarbon to hydrogen– carbon to hydrogen economy. International Journal of Hydrogen Energy 30 (2005) 225-237.
4. Zuttel A. Materials for hydrogen storage. Materials Today 6 (2003) 24-33.
5. Bogdanovic B, Schwickardi M. Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials. Journal of Alloys and Compounds 253 (1997) 1-9.
6. Dillon AC, Jones KM, Bekkedahl TA, Kiang CH, Bethune DS, Heben MJ. Storage of hydrogen in single-walled carbon nanotubes. Nature 386 (1997) 377-379.
7. Ozturk Z, Baykasoglu C, Celebi AT, Kirca M, Mugan A. Hydrogen storage in heat welded random CNT network structures. International Journal of Hydrogen Energy 40 (2015) 403-411.
8. Hu YH, Zhang L. Hydrogen storage in metal–organic frameworks. Advanced Materials 22 (2010) E117-E130.
9. U.S. Department of Energy, EERE, Hydrogen, Fuel cells & Infrastructure Technologies Program,Multi-Year RD&D Plan, 2005. http://www.eere.energy.gov/hydrogenandfuelcells/ mypp/pdfs/storage.pdf
10. Li JR, Kuppler RJ, Zhou HC. Selective gas adsorption and separation in metal–organic frameworks. Chemical Society Reviews 38 (2009) 1477-1504.
11. Luzan SM, Talyzin AV. Hydrogen adsorption in Pt catalyst/ MOF-5 materials. Microporous and Mesoporous Materials 135 (2010) 201-205.
12. Fu Y, Su D, Chen Y, Huang R, Ding Z, Fu X, Li Z. An AmineFunctionalized Titanium Metal–Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction. Angewandte Chemie 14 (2012) 3364–3367.
13. Rowsell JLC, Milward AR, Park KS, Yaghi OM. Hydrogen Sorption in Functionalized Metal-Organic Frameworks. Journal of the American Chemical Society 126 (2004) 5666-5667.
14. Prelli RB, Klevin KP, Herrington DM. Vascular effects of dietary l-arginine supplementation. Atherosclerosis 162 (2002) 1-15.
15. Nieves JrC, Langkamp-Henken B. Arginine and immunity: a unique perspective. Biomedicine & Pharmacotherapy 56 (2002) 471-482.
16. Han SS, Goddard WA. Lithium-doped metal-organic frameworks for reversible H2 storage at ambient temperature. Journal of the American Chemical Society 129 (2007) 8422-8423.
17. Cao D, Lan J, Wang W, Smit B. Lithium-doped 3D covalent organic frameworks: high-capacity hydrogen storage materials. Angewandte Chemie International Edition in English 48 (2009) 4730-4733.
18. Wood BCD, Tan B, Trewin A, Su F, Rosseinsky MJ, Bradshaw D, Sun Y, Zhou L, Cooper I. Microporous Organic Polymers for Methane Storage. Advanced Materials 20 (2008) 1916- 1921.
19. Dimitrakakis GK, Tylianakis E, Froudakis GE. Pillared Graphene: A New 3-D Network Nanostructure for Enhanced Hydrogen Storage. Nano Letters 8 (2008) 3166-3170.
20. Fisher M, Hoffmann F, Fröba M. Preferred Hydrogen Adsorption Sites in Various MOFs—A Comparative Computational Study. ChemPhysChem 10 (2009) 2647- 2657.
21. Wang CY, Tsao CS, Yu MS, Liao PY, Chung TY, Wu HC, Miller MA, Tzeng YR. Hydrogen storage measurement, synthesis and characterization of metal–organic frameworks via bridged spillover. Journal of Alloys and Compounds 2008. doi:10.1016/j.jallcom.2009.11.203.
22. Yang J, Zhao Q, Li J, Dong J. Synthesis of metal–organic framework MIL-101 in TMAOH-Cr(NO3) 3-H2BDC-H2O and its hydrogen-storage behavior. Microporous and Mesoporous Materials (2009). doi:10.1016/j.micromeso.2009.11.001.
23. Chen H, Lin SL. A combined experiment and molecular dynamics simulation study on the influence of the crosslinking on the crystallization of comb fluorinated acrylate copolymers. Journal of Materials Science 49 (2014) 986-993.
24. Recommendations: Reporting Physisorption Data for Gas/ Solid Systems with Special Reference to the Determination of Surface Area and Porosity, IUPAC Commission on Colloid and Surface Chemistry Including Catalysis, Pure Applied Chemistry 57 (1985) 603.
25. Recommendations for the Characterization of Porous Solids, IUPAC Commission on Colloid and Surface Chemistry, Pure Applied Chemistry 66 (1994) 1311.
26. Li Y, Xie L, Yang R, Li X. Favorable Hydrogen Storage Properties of M(HBTC)(4,4ƍ-bipy)•3DMF (M = Ni and Co). Inorganic Chemistry 47 (2008) 10372-10377.
27. Yang C, Wang X, Omary MA. Fluorous Metal-Organic Frameworks for High-Density Gas Adsorption. Journal of the American Chemical Society 129 (2007) 15454-15455.
28. Assfour B, Leoni S, Yurchenko S, Seifert G. Hydrogen storage in zeolite imidazolate frameworks. A multiscale theoretical investigation. International Journal of Hydrogen Energy 36 (2011) 6005-6013.