Atık sulardan metilen mavisi gideriminde polianilin/ceviz kabuğu atığı kompozitlerinin kullanımı

Sentetik boyaların atık sularda yarattığı kirlilik önemli bir sorun haline gelmiştir. Bilhassa selülozik malzemelerin boyanmasında kullanılan metilen mavisinin atık sulardan giderimi önemi artan bir konudur. Bu çalışmada, Polianilin/Ceviz kabuğu atığı kompozitleri düşük maliyetli ve kullanışlı adsorbanlar olarak sunulmuştur. Kompozitler farklı karışım oranlarında hazırlanmıştır. Adsorbanların kimyasal yapıları Fourier Dönüşümü Kızılötesi Spektroskopisi ile ve yüzey morfolojileri Taramalı Elektron Mikroskobu ile araştırılmıştır. pH, adsorban miktarı, başlangıç boyarmadde konsantrasyonu, zaman ve sıcaklığın, Metilen Mavisi adsorpsiyonu üzerine etkisi incelenmiştir. Çeşitli sıcaklıklarda kinetik ve izoterm çalışmaları yapılmıştır. Adsorpsiyon davranışı, üç ana izoterm modeli yardımıyla incelenmiştir. Elde edilen izoterm verilerinin Freundlich izoterminden ziyade Langmuir izotermiyle daha çok eşleştiği görülmüştür. Kompozit adsorbanın adsorpsiyon kapasitesinin 105 mg/g olduğu bulunmuştur. En yüksek adsorpsiyon verimlilik değeri %98,93 olarak tesbit edilmiştir. Reaksiyon kinetiğinin sözde ikinci derece kinetik model ile eşleştiği görülmüştür.

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  • Robinson T, McMullan G, Marchant R, Nigam P., Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. Bioresource Technology (Bioresour.Technol.), 77 (12), 247-255, 2001.
  • Hai, F.I., Yamamoto, K., Fukushi, K., Hybrid treatment systems for dye wastewater, Critical Reviews in Environmental Science and Technology (Crit.Rev.Environ.Sci.Technol.), 37 (4), 315-377, 2007.
  • Phalakornkule, C., Polgumhang, S., Tongdaung, W., Karakat, B. ve Nuyut, T., Electrocoagulation of blue reactive, red disperse and mixed dyes, and application in treating textile effluent, Journal of environmental management (J.Environ.Manage.), 91, 918-926, 2010.
  • Slokar, Y. M. ve Le Marechal, A. M., Methods of decoloration of textile wastewaters, Dyes and pigments (Dyes pigm.), 37, 335-356, 1998.
  • Wu, J.S., Liu, C.H., Chu, K.H. ve Suen, S.Y., Removal of cationic dye methyl violet 2B from water by cation exchange membranes, Journal of membrane science (J.Membr.Sci.), 309, 239-245, 2008.
  • Kim, H.G., Park, C., Yang, J., Lee, B., Kim, S.S., Kim, S., Optimization of backflushing conditions for ceramic ultrafiltration membrane of disperse dye solutions, Desalination, 202, 150-155, 2007.
  • Abbasi, M. ve Asl, N. R., Sonochemical degradation of Basic Blue 41 dye assisted by nanoTiO2 and H2O2, Journal of hazardous materials (J.Hazard.Mater.), 153, 942-947, 2008.
  • Gupta, V., Jain, R., Mittal, A., Mathur, M., Sikarwar, S., Photochemical degradation of the hazardous dye Safranin-T using TiO2 catalyst, Journal of colloid and interface science (J.Colloid İnt. Sci.), 309, 464-469, 2007.
  • Khataee, A.R., Dehghan, G., Ebadi, A., Zarei, M., Pourhassan, M., Biological treatment of a dye solution by Macroalgae Chara sp.:effect of operational parameters, intermediates identification and artificial neural network modeling, Bioresource Technology (Bioresour. Technol.), 101, 2252–2258, 2010.
  • Cheng,, S., Oatley, D.L., Williams, P.M., Wright, C.J., Characterisation and application of a novel positively charged nanofiltration membrane for the treatment of textile industry wastewaters, Water Research (Water Res.), 46, 33–42, 2012.
  • Neamtu, M., Yediler, A., Siminiceanu, I., Macoveanu, M., Kellrup, A., Decolorization of disperse red 354 azo dye in waterby several oxidation processes-a comparative study, Dyes and Pigments (Dyes Pigm.), 60, 61–68, 2004.
  • Reddy, M. S., Sivaramakrishna, L. ve Reddy, A. V., The use of an agricultural waste material, Jujuba seeds for the removal of anionic dye (Congo red) from aqueous medium, Journal of hazardous materials (J.Hazard.Mater.), 203, 118-127, 2012.
  • Saiful Azhar, S., Abdul Ghaniey Liew, A., Suhardy, D., Farizul Hafiz, K., Hatim, M. I., Dye Removal from Aqueous Solution by using Adsorption on Treated Sugarcane Bagasse, American Journal of Applied Sciences 2 (Am.J.Appl.Sci.), 1499-1503, 2005.
  • Tan, I., Ahmad, A., Hameed, B., Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies, Journal of Hazardous Materials (J.Hazard.Mater.), 154 (1-3), 337-346, 2008.
  • Bayomie, O.S., Kandeel, H., Shoeib, T., Yang, H., Youssef, N., El-Sayed, M.M.H., Novel approach for effective removal of methylene blue dye from water using fava bean peel waste, Scientific reports (Sci Rep), 10, 7824, 2020.
  • Lonappan, L., Rouissi, T., Das, R.K., Brar, S.K., Ramirez, A.A.,Verma, M., Surampalli, R.Y., Valero J.R., Adsorption of methylene blue on biochar microparticles derived from different waste materials, Waste Management (Waste Manage.), 49, (537–544, 2016.
  • Guo, J.Z., Li, B., Liu, L., Kangle L., Removal of methylene blue from aqueous solutions by chemically modified bamboo, Chemosphere, 111, 225–231, 2014.
  • Bulut, Y. ve Aydın, H., A kinetics and thermodynamics study of methylene blue adsorption on wheat shells, Desalination, 194 (1-3), 259-267, 2006.
  • Dai, H. ve Huang, H., Modified pineapple peel cellulose hydrogels embedded with sepia inkfor effective removal of methylene blue, Carbohydrate Polymers (Carbohydr.Polym.), 148, 1–10, 2016.
  • Li, Z., Jia, Z., Ni, T., Li, S., Adsorption of methylene blue on natural cotton based flexible carbon fiber aerogels activated by novel air-limited carbonization method, Journal of Molecular Liquids (J.Mol.Liq.), 242, 747–756, 2017.
  • Ghosh, S.K. ve Bandyopadhyay, A., Adsorption of methylene blue onto citric acid treated carbonized bamboo leaves powder: Equilibrium, kinetics, thermodynamics analyses, Journal of Molecular Liquids (J.Mol.Liq.), 248, 413–424, 2017.
  • Pathania, D., Sharma, S., Singh, P., Removal of methylene blue by adsorption onto activated carbon developed from Ficus carica bast, Arabian Journal of Chemistry (Arab.J.Chem.), 10, 1445–1451, 2017.
  • Mouni L., Belkhiri L., Bollinger J.C., Bouzaza A., Assadi A., Tirri A., Dahmoune F., Madani K., Remini H., Removal of Methylene Blue from aqueous solutions by adsorption on Kaolin: Kinetic and equilibrium studies, Applied Clay Science (Appl. Clay Sci.), 153, 38-45, 2018.
  • Miraboutalebi, S.M., Nikouzad, S.K., Peydayesh, M., Allahgholi, N., Vafajoo, L., McKay, G., Methylene blue adsorption via maize silk powder: Kinetic, equilibrium, thermodynamic studies andresidual error analysis, Process Safety and Environmental Protection (Process Saf.Environ.), 106, 191–202, 2017.
  • Sun, L., Wan,S., Luo, W., Biochars prepared from anaerobic digestion residue, palm bark, and eucalyptus for adsorption of cationic methylene blue dye: Characterization, equilibrium, and kinetic studies, Bioresource Technology (Bioresour.Technol.), 140, 406–413, 2013.
  • Bahjaat N., Polianilin/hindistan cevizi kabuğu bazlı adsorbanların hazırlanması, karakterizasyonu ve metilen mavisi boyasının adsorpsiyonunda kullanımı, Master Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, Konya, 2018.
  • Hassan, W., Farooq, U., Ahmad, M., Athar, M., Khan, M.A., Potential biosorbent, Haloxylon recurvum plant stems, for the removal of methylene blue dye, Arabian Journal of Chemistry (Arab.J.Chem.), 10, 1512–1522, 2017.
  • Lim, L.B.L., Priyantha, N., Tennakoon, D.T.B., Chieng, H.I., Dahri, M.K., Suklueng, M., Breadnut peel as a highly effective low-cost biosorbent for methylene blue: Equilibrium, thermodynamic and kinetic studies, Arabian Journal of Chemistry (Arab.J.Chem.), 10, 3216–3228, 2017.
  • Markovic, S., Stankovic, A., Lopicic, Z., Lazarevic, S., Stojanovic, M., Uskokovic, D., Application of raw peach shell particles for removal of methylene blue, Journal of Environmental Chemical Engineering (J.Environ.), 3, 716–724, 2015.
  • Namasivayam, C., Radhika, R., Suba, S., Uptake of dyes by a promising locally available agricultural solid waste: coir pith, Waste Management (Waste Manage), 21 (4), 381-387, 2001.
  • Yusan, S., Investigation of the Kinetic and Thermodynamic Properties of U(VI) Ions onto Raw and Modified Diatomite, Celal Bayar University Journal of Science (CBU Journal of Science), 13 (3), 761-768, 2017.
  • Lagergren, S., For the theory of so-called adsorption gelosterous substance, Royal Swedish Academy of Sciences, Actions, 24, 1-39, İsveç, 1898.
  • Bayramoglu, G., Altintas, B., Arica, M.Y., Synthesis and characterization of magnetic beads containing aminated fibrous surfaces for removal of Reactive Green 19 dye: kinetics and thermodynamic parameters, Journal of Chemical Technology and Biotechnology (J.Chem.Technol.Biotechnol.), 87, 705–713, 2012.
  • Etim, U., Umoren, S. and Eduok, U., Coconut coir dust as a low cost adsorbent for the removal of cationic dye from aqueous solution, Journal of Saudi Chemical Society (J.Saudi Chem.Soc.), 20, 67-76, 2016.
  • Temkin, M. ve Pyzhev, V., Kinetics of ammonia synthesis on promoted iron catalyst, Acta Phys. Chim., 12 (1), 327, SSCB, 1940.
  • Shahadat, M., Khan, M. Z., Rupani, P. F., Embrandiri, A., Sultana, S., Shaikh, Z., Ali, S. W. and Sreekrishnan, T., A critical review on the prospect of polyaniline-grafted biodegradable nanocomposite, Advances in Colloid and Interface Science (Adv.Colloid Interface Sci.), 249, 2-16, 2017.
  • Pandimurugan, R., Thambidurai, S., Synthesis of seaweed-ZnO-PANI hybrid composite for adsorption of methylene blue dye, Journal of Environmental Chemical Engineering (J.Environ.Chem.Eng.), 4 (1), 1332-1347, 2016.
  • McKay, G. ve Ho, Y., Pseudo-second order model for sorption processes, Process Biochemistry (Process Biochem), 34 (5), 451-465, 1999.
  • Theydan, S. K. ve Ahmed, M. J., Adsorption of methylene blue onto biomass-based activated carbon by FeCl3 activation: Equilibrium, kinetics, and thermodynamic studies, Journal of Analytical and Applied Pyrolysis (J.Anal.Appl.Pyrolysis), 97, 116-122, 2012.
  • Bhatnagar, A., Vilar, V. J., Botelho, C. M. ve Boaventura, R. A., Coconut-based biosorbents for water treatment—a review of the recent literature, Advances in Colloid and İnterface Science (Adv.Colloid Interface Sci.), 160 (1-2), 1-15, 2010.
  • Argun, M. E., Dursun, S., Ozdemir, C. ve Karatas, M., Heavy metal adsorption by modified oak sawdust: Thermodynamics and kinetics, Journal of Hazardous Materials (J.Hazard.Mater.), 141 (1), 77-85, 2007.
  • Low, K. ve Lee, C., The removal of cationic dyes using coconut husk as an adsorbent, Pertanika, 13 (2), 221-228, 1990.
  • Franca, A. S., Oliveira, L. S. and Ferreira, M. E., Kinetics and equilibrium studies of methylene blue adsorption by spent coffee grounds, Desalination, 249 (1), 267-272, 2009.
  • El-Sayed, G. O., Removal of methylene blue and crystal violet from aqueous solutions by palm kernel fiber, Desalination, 272 (1-3), 225-232, 2011.
  • Ferrero, F., Dye removal by low cost adsorbents: Hazelnut shells in comparison with wood sawdust, Journal of Hazardous Materials (J.Hazard.Mater.), 142 (1-2), 144-152, 2007.
  • Annadurai, G., Juang, R. S. ve Lee, D. J., Use of cellulose-based wastes for adsorption of dyes from aqueous solutions, Journal of Hazardous Materials (J.Hazard.Mater.), 92 (3), 263-274, 2002.
  • Agarwal, S., Tyagi, I., Gupta, V. K., Golbaz, F., Golikand, A. N., Moradi, O., Synthesis and characteristics of polyaniline/zirconium oxide conductive nanocomposite for dye adsorption application, Journal of Molecular Liquids (J.Mol.Liq.), 218, 494-498, 2016.
  • Gupta, V. K., Pathania, D., Kothiyal, N., Sharma, G., Polyaniline zirconium (IV) silicophosphate nanocomposite for remediation of methylene blue dye from waste water, Journal of Molecular Liquids (J.Mol.Liq.), 190, 139-145, 2014.
Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi-Cover
  • ISSN: 1300-1884
  • Yayın Aralığı: Yılda 4 Sayı
  • Başlangıç: 1986
  • Yayıncı: Oğuzhan YILMAZ
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