PHENANTHROIMIDAZOLE-AZO DERIVED POLYMER BASED FLUORESCENCE SENSOR DESIGN FOR MONITORING OF Fe (III) IONS

Dye doped polymer films which are sensitive to Fe (III) ions have been developed for using in the aqueous medium. PVC films were obtained by spreading the cocktail mixture onto a mylar film used as a supporting material. PMMA films were prepared with solvent casting method. Cation responses were examined for two different polymer films. Emission bands were obtained at different concentrations of Fe (III) ions. Because polymer films had the highest response to them. The calibration graphics were plotted for emission values at different Fe (III) concentrations. Besides, interference effects of Cr (III) and Fe (II) ions to Fe (III) ions were studied. Additionally, regeneration studies were carried out to examine application properties of the dye doped polymer films developed as a sensor for Fe (III) cations.

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  • [1] Bilcikova J, Fialkova V, Kovacikova E, Miskeje M, Tombarkiewicz B, Knazicka Z. Influence Of Transition Metals On Animal And Human Health: A Review. Contemporary Agriculture 2018; 67: 187-195.
  • [2] Aydemir B, Kızıler AR, Onaran İ, Alıcı B, Özkara H, Akyolcu MC. Impact of Cu and Fe Concentrations on Oxidative Damage in Male Infertility. Biol Trace Elem Res 2006; 112: 193-203.
  • [3] Ando K, Ogawa K, Misaki S, Kikuwaga K. Increased Release of Free Fe Ions in Human Erythrocytes During Aging in the Circulation. Free Radical Res 2002; 36: 1079-1084.
  • [4] Borst JW, Visser AJVG. Fluorescence lifetime imaging microscopy in life sciences. Meas Sci Technol 2010; 10: 1-21.
  • [5] Wagnieres GA, Star WM, Wilson BC. In Vivo Fluorescence Spectroscopy and Imaging for Oncological Applications. Photochem Photobiol 1998; 68: 603-632.
  • [6] Gillenwater A, Jacob R, Richards-Kortum R. Fluorescence spectroscopy: A technique with potential to improve the early detection of aerodigestive tract neoplasia. Head Neck-J Scı Spec 1998; 20: 556–562.
  • [7] Müller MG, Valdez TA, Georgakoudi I, Backman V, Fuentes C, Kabani S, Laver N, Wang Z, Boone CW, Dasari RR et al. Spectroscopic detection and evaluation of morphologic and biochemical changes in early human oral carcinoma. Cancer 2003; 97: 1681-1692.
  • [8] Carter KP, Young AM, Palmer AE. Fluorescent Sensors for Measuring Metal Ions in Living Systems. Chem Rev 2014; 114: 4564-4601.
  • [9] Cabaniss SE, Shuman MS. Combined ion selective electrode and fluorescence quenching detection for copper-dissolved organic matter titrations. Anal Chem 1986; 58: 398-401.
  • [10] Wolfbeis OS. Materials for fluorescence-based optical chemical sensors. J Mater Chem 2005; 15: 2657-2669.
  • [11] Rakow NA, Suslick KS. A colorimetric sensor array for odour visualization. Letter 2000 ; 406: 710-713.
  • [12] Hebner TR, Wu CC, Marcy D, Lu MH, Sturm JC. Ink-jet printing of doped polymers for organic light emitting devices. Appl Phys Lett 1998; 72: 519-521.
  • [13] Sun Y-F, Wang H-P, Chen Z-Y, Duan W-Z. Solid-state Fluorescence Emission and Second-Order Nonlinear Optical Properties of Coumarin-based Fluorophores. J Fluoresc 2012; 23: 123-130.
  • [14] Mahanta, D, Madras G, Radhakrishnan S, Patil S. Adsorption and Desorption Kinetics of Anionic Dyes on Doped Polyaniline. J Phys Chem B 2009; 113: 2293-2299.
  • [15] Espósito BP, Epsztejn S, Breuer W, Cabantchik ZI. A Review of Fluorescence Methods for Assessing Labile Iron in Cells and Biological Fluids. Anal Bıochem 2002; 304: 1-18.
  • [16] Zeng Z, Jewsbury RA. Fluorimetric determination of iron using 5-(4-methoxyphenylazo)-8-(4-toluenesulfonamido)quinoline. The Analyst 2000; 125: 1661-1665.
  • [17] Khalil R. Optical Properties of Rhodamine - B Dye Doped in Transparent Polymers for Sensor Application. Chinese J Phys 2013; 51: 570-580.
  • [18] Oter O, Ertekin K, Kirilmis C, Koca M, Ahmedzade M. Characterization of a newly synthesized fluorescent benzofuran derivative and usage as a selective fiber optic sensor for Fe(III). Sensors and Actuators B: Chemical 2007; 122: 450-456.
  • [19] Gülle S, Çelik Erbaş S. A Selective Fluorescence Sensor for Fe (III) Based on Phenanthroimidazole Imine Compound. J Fluoresc 2017; 28: 445-451.
  • [20] Tofiño PP, Moreno JM, Pérez-Conde MC. A flow-through fluorescent sensor to determine Fe (III) and total inorganic iron.Talanta 2000; 51:537–545.
  • [21] Erbaş SÇ, Gülle S. Synthesis and Photophysical Behaviours of Novel Phenanthro [9,10-d] Imidazole Substituted Azo Dyes in Solvent Media. CBUJOS 2018; 14: 285-289.