Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini

Mikrokristal naftalin (MN) üzerinde pH 3.0-8.0 aralığında potasyum 2,6-dimetilmorfolinditiyokarbamat (KMDMMDTC) ligantı kullanılarak büyük hacimli sulu çözeltilerden Cu(II) iyonu önderiştirilmiştir. Cu(II)-DMMDTC  kompleksi içeren MN, 5 mL asetonda çözülerek Cu(II) iyonu kör çözeltiye karşı 431 nm’de spektrofotometrik metot ile tayin edildi. pH, numune çözeltisinin hacmi, DMMDTC yüklü MN miktarı, çalkalama süresi, yabancı iyon etkisi gibi katı faz ekstraksiyon (SPE) metodunun temel parametreleri incelendi. Aseton çözeltisinde 0,09 µgmL-1 tayin sınırı ile lineer kalibrasyon aralığı 0,05-5,0 µgmL-1’dir. Sudaki potansiyel yabancı iyonların etkisi araştırıldı ve önerilen metot ilaç ve çevresel numunelerden Cu(II) iyonunun tayini için uygulanarak % 90 üzerinde geri kazanım değerleri elde edildi. Doğruluk, sertifikalı referans madde NW-TMDA-70.2 analizi ve geri kazanım deneyleri ile değerlendirildi.

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Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi-Cover
  • ISSN: 1307-9085
  • Yayın Aralığı: Yılda 3 Sayı
  • Başlangıç: 2008
  • Yayıncı: Erzincan Binali Yıldırım Üniversitesi, Fen Bilimleri Enstitüsü
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