Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety

Öz Full substituted p-(dodecyloxy)-phenol derivative of cyclotriphosphazene (trimer) was synthesized in orderto investigate its mesogenic properties. Firstly, p-(dodecyloxy)-phenol (1) was synthesized from the reactionof hydroquinone and 1-bromododecane. Hexachlorocyclotriphosphazene (trimer) was reacted in a 1:8molar ratio in tetrahydrofurane (THF) presence of sodium hyride (NaH) as base at room temperature for 24hours and then under the reflux for a day. Full substituted derivative (2) was obtained and its structure wasdetermined by mass analysis, and by FT–IR, 1H and 31P {1H} NMR spectroscopic techniques. Additionallythermal and mesomorphic behaviours were examined by differential scanning calorimetry (DSC),polarising optical microscopy (POM) and X-ray diffraction (XRD) techniques. By contrast with literature,results showed that compound 2 has liquid crystal behavior.

Kaynakça

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Kaynak Göster

Bibtex @araştırma makalesi { cbayarfbe280725, journal = {Celal Bayar University Journal of Science}, issn = {1305-130X}, eissn = {1305-1385}, address = {}, publisher = {Celal Bayar Üniversitesi}, year = {2016}, volume = {12}, pages = {535 - 542}, doi = {10.18466/cbayarfbe.280725}, title = {Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety}, key = {cite}, author = {Davarcı, Derya} }
APA Davarcı, D . (2016). Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety . Celal Bayar University Journal of Science , 12 (3) , 535-542 . Retrieved from https://dergipark.org.tr/tr/pub/cbayarfbe/issue/25998/280725
MLA Davarcı, D . "Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety" . Celal Bayar University Journal of Science 12 (2016 ): 535-542 <https://dergipark.org.tr/tr/pub/cbayarfbe/issue/25998/280725>
Chicago Davarcı, D . "Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety". Celal Bayar University Journal of Science 12 (2016 ): 535-542
RIS TY - JOUR T1 - Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety AU - Derya Davarcı Y1 - 2016 PY - 2016 N1 - DO - T2 - Celal Bayar University Journal of Science JF - Journal JO - JOR SP - 535 EP - 542 VL - 12 IS - 3 SN - 1305-130X-1305-1385 M3 - UR - Y2 - 2021 ER -
EndNote %0 Celal Bayar Üniversitesi Fen Bilimleri Dergisi Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety %A Derya Davarcı %T Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety %D 2016 %J Celal Bayar University Journal of Science %P 1305-130X-1305-1385 %V 12 %N 3 %R %U
ISNAD Davarcı, Derya . "Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety". Celal Bayar University Journal of Science 12 / 3 (Aralık 2016): 535-542 .
AMA Davarcı D . Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety. Celal Bayar Univ J Sci. 2016; 12(3): 535-542.
Vancouver Davarcı D . Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety. Celal Bayar University Journal of Science. 2016; 12(3): 535-542.
IEEE D. Davarcı , "Liquid Crystalline Cyclotriphosphazenes: Full Substitute Trimeric Derivative with 12-carbon-chain Mesogen Moiety", Celal Bayar University Journal of Science, c. 12, sayı. 3, ss. 535-542, Ara. 2017, doi:10.18466/cbayarfbe.280725

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