Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs

An oxygen sensitive optical chemical sensor has been developed based on fluorescence quenching of the meso-tetraphenylporphyrin (H2TPP) immobilized in a silicone derivative along with silver nanoparticles (AgNPs) and different ionic liquids (ILs). Emission spectra of the H2TTP doped thin film exhibited an increment due to the formation of an associated complex between H2TPP and AgNPs. The offered thin films responded to the oxygen in the direction of quenching with extreme sensitivity. Emission and decay-time measurements of the H2TPP in thin solid matrices were studied in the concentration range of 0-100% p(O2). Utilization of the porphyrin dye along with AgNPs and ionic liquid as an additive exhibited higher oxygen sensitivity with respect to the additive-free forms and resulted in many advances such as linear response, improvement in sensor dynamics and extreme sensitivity. Together with additives, the meso-tetraphenylporphyrin-based composites yielded higher Stern-Volmer constant (Ksv), faster response time, and larger linear response range when compared with the additive-free form. The response time of the sensor has been recorded as 90 s

Keywords:

meso-tetraphenylporphyrin (H2TPP), silver nanoparticles, ionic liquids, O2 sensing,

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1. Potyrailo, RA, Hieftje, GM, Oxygen detection by fluorescence quenching of tetraphenylporphyrin immobilized in the original cladding of an optical fiber, Analytica Chimica Acta, 1998; 370, 1–8.
2. Bussetti, G, Campione, M, Sassella, A, Duò, L, Optical and morphological properties of ultra-thin H2TPP, H4TPP and ZnTPP films, Physica Status Solidi (B), 2015, 252(1), 100–104.
3. Weegen, R, Abraham, JP, Meijer, EW, Directing the self-assembly behaviour of porphyrin-based supramolecular systems, Chemistry – A European Journal, 2017, 23, 3773 –3783.
4. Hasselman, GM, Watson, DF, Stromberg JR, Bocian, DF, Holten, D, Lindsey, JS, Meyer, GJ, Theoretical solar-to-electrical energy-conversion efficiencies of perylene−porphyrin light-harvesting arrays, The Journal of Physical Chemistry B, 2006, 110 (50), 25430–25440.
5. Yang, X, Peng, L, Yuan, L, Teng, P, Tian, F, Li, L, Luo, S, Oxygen gas optrode based on microstructured polymer optical fiber segment, Optics Communications, 2011, 284, 3462–3466.
6. Mosinger, J, Lang, K, Plistil, L, Jesenska, S, Hostomsky, J, Zelinger, Z, Kubat, P, Fluorescent polyurethane nanofabrics: A source of singlet oxygen and oxygen sensing, Langmuir, 2010, 26, 10050–10056.
7. Topal, SZ, Onal, E, Ertekin, K, Oter, O, Gürek AG, Hirel C, Significant sensitivity and stability enhancement of tetraphenylporphyrin-based optical oxygen sensing material in presence of perfluorochemicals, Journal of Porphyrins and Phthalocyanines, 2013, 17(6), 431-439.
8. Onal, E, Ay, Z, Yel, Z, Ertekin, K Gürek AG, Topal, SZ, Hirel C, Design of oxygen sensing nanomaterial: Synthesis, encapsulation of phenylacetylide substituted Pd(II) and Pt(II) meso-tetraphenylporphyrins into poly(1- trimethylsilyl-1-propyne) nanofibers and influence of silver nanoparticles, Royal Society of Chemistry Advances, 2016, 6, 9967–9977.
9. Kotiaho, A, Lahtinen, RM, Tkachenko, NV, Efimov, A, Kira, A, Imahori, H, Lemmetyinen, H, Gold nanoparticle enhanced charge transfer in thin film assemblies of porphyrin-fullerene dyads. Langmuir, 2007, 23, 13117–13125.
10. Oter, O, Sabancı, G, Ertekin, K, Enhanced CO2 sensing with ionic liquid modified electrospun nanofibers: Effect of ionic liquid type, Sensor Letters, 2013, 11(9), 1591-1599.
11. Solomon, SD, Bahadory, M, Jeyarajasingam, AV, Rutkowsky, SA, Boritz C, Mulfinger, L, Synthesis and study of silver nanoparticles, Journal of Chemical Education, 2007, 84(2), 322-325.
12. Lowe, KC, Perfluorochemical respiratory gas carriers: Benefits to cell culture systems, Journal of Fluorine Chemistry, 2002, 118, 19–26.
13. Topal, SZ, Ongun, MZ, Onal, E, Ertekin, K Hirel, C, Hyperporphyrin effect on oxygen sensitivity of free meso-tetraphenylporphyrins, Dyes and Pigments, 2017, 144, 102-109.
14. Anthony, JL, Maginn, EJ, Brennecke, JFJ, Solubilities and thermodynamic properties of gases in the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate, The Journal of Physical Chemistry B, 2002, 106, 7315–7320.
15. Ongun, MZ, Oter, O, Sabancı, G, Ertekin, K, Celik, E, Enhanced stability of ruthenium complex in ionic liquid doped electrospun fibers, Sensors and Actuators B, 2013, 183, 11–19.
16. Lakowicz, J.R, Principles of Fluorescence Spectroscopy; University of Maryland School of Medicine Baltimore, Press: Springer,Third Edition Maryland, USA, 2006.
17. MacCraith, BD, McDonagh, CM, O’Keeffe, G, Keyes, ET, Vos, JG, O’Kelly, B, McGlip, JF, Fibre optic oxygen sensor based on fluorescence quenching of evanescent-wave excited ruthenium complexes in sol–gel derived porous coatings, Analyst, 1993, 118, 385–388.
18. Ozturk, O, Oter, O, Yildirim, S, Subasi, E, Ertekin, K, Celik, E, Temel, H, Tuning oxygen sensitivity of ruthenium complex exploiting silver nanoparticles, Journal of Luminescence, 2014, 155, 191-197.

Celal Bayar Üniversitesi Fen Bilimleri Dergisi-Cover

ISSN: 1305-130X
Başlangıç: 2005
Yayıncı: Manisa Celal Bayar Üniversitesi Fen Bilimleri Enstitüsü

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