Akıllı Malzemelerin Hazırlanmasında Kullanılacak Amin Türevi Monomerlerin Sentez ve Karakterizasyonu

Bu çalışmada; polimerleşme ve metal kompleksi oluşturabilme özelliklerine sahip amin türevi üç yeni monomer sentezlenmiştir. Sentezreaksiyonu olarak, petasis reaksiyonu seçilmiştir. Uygun optimizasyon koşullarında, herhangi bir katalizör kullanılmadan ve oldukçayüksek verimlerle hedef ürünler(monomer) elde edilmiştir. Reaksiyon verimine; sıcaklık, çözücü, atmosfer koşullarının yanısıra,substitüentlerin de etkili olduğu görülmüştür. Özellikle elektron salıcı substitüent içeren yapıların elektron çekici substitüent içerenbileşiklere göre daha istemli olduğu ve veriminin de yüksek olduğu görülmüştür. Alkilaminofenol bileşik sınıfına ait olan bumonomerlerin yapısal analizleri ise ${}^1H-NMR$ ve ${}^{13}C-NMR$ ile tamamlanmıştır. Sentezi yapılan monomerler, moleküler baskılanmışpolimer olarak biyomoleküler tanımada kullanılabilir. Bu durum; bir çok hedef molekül için onları tanıyan uygun materyallerin eldeedilmesi anlamına gelmektedir. Çalışma bu yönüyle oldukça önemlidir.

Synthesis and Characterization of Amine Derivative Monomers to be used in Preparing Smart Materials

In this study, amine derivative three new monomers forming polymer and metal complex synthesized. As the synthesis reaction, the petasis reaction was chosen. Under optimization conditions, target products (monomer) were obtained without any catalyst and with very high yields. Some parameters, such as temperature, solvent, atmospheric conditions, and substituents, has affected reaction yields.In particular, it observed that the structures containing the electron release substituent were more eager than the compounds containing the electron acceptor and the yield was high. Structural analyses of monomers of the alkylaminophenol class were made with ${}^1H-NMR$ and ${}^{13}C-NMR$. The synthesized monomers can use as molecular printed polymers in biomolecular recognition. That means to obtain suitable materials for synthesized of target molecules. Therefore, this aspect of the study is important.

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