DOĞAL ELYAF KARIŞIMLI POLİÜRETAN KOMPOZİTLERİN SES VE ISI YALITIM ÖZELLİKLERİNİN İNCELENMESİ

Bir kompozitin ses yutum ve ısı yalıtım özelliklerini iyileştirmek amacıyla poliüretan esaslı bir matrise doğal pamuk, bambu ve yün elyaf katılmıştır. Bu çalışmanın arkasındaki hedeflerden biri de tekstil atıklarının değerlendirilmesi ve malzeme üretiminde daha az poliüretan kullanılmasıdır. Genel olarak bakıldığında, doğal elyaf ilavesi, poliüretan köpüğün ses yalıtım özelliğini iyileştirmektedir. Yapılan deneylerde, pamuk elyaf destekli poliüretan kompozitin en iyi ses yutum katsayısı değerlerini verdiği gözlenmiştir. Poliüretan köpüğe katılan bambu ve yün elyaf oranlarının arttırılması, kompozitin yüksek frekanslardaki ses yutum katsayı değerlerini azaltmaktadır. Poliüretan köpük içerisine pamuk, bambu veya yün elyaf katılması ısıl özelliklerde kayda değer bir değişim oluşturmamaktadır. En iyi ısıl iletkenlik özelliği %4 pamuk elyaf içeren kompozit için gözlenmiştir

THERMAL CONDUCTIVITY AND ACOUSTIC PROPERTIES OF NATURAL FIBER MIXED POLYURETHANE COMPOSITES

Natural cotton, bamboo and wool fibers were used as reinforcement agents in a polyurethane-based matrix to improve the sound absorption and thermal conductivity properties of the composite. Generally, adding cotton, bamboo or wool fibers to polyurethane foam, improves its sound absorption coefficient. In this study, cotton fibers were observed to provide the best sound absorption coefficient. At higher frequencies, increasing the bamboo or wool fiber content decreases the sound absorption coefficient for the composite. Adding cotton, wool or bamboo fibers to polyurethane foam does not result in a significant change in the thermal conductivity of the material. The best thermal conductivity value was observed with a composite including 4% cotton fiber

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  • 1. Verdejo R, Stampfli R, Alvarez-Lainez M, Mourad S, Rodriguez-Perez MA, Bruhwiler PA Shaffer M., 2009, “Enhanced acoustic damping in flexible polyurethane foams filled with carbon nanotubes”, Compos Sci Technol, 69(10):1564-1569.
  • 2. Chen CH, Ma CCM, 1992, “Pultruded fibre reinforced polyurethane composites I. process feasibility and morphology”, Compos Sci Technol, 45(4): 335-344.
  • 3. Chen CH, Ma CCM, 1992, “Pultruded fibre reinforced blocked polyurethane (PU) composites II. Processing variables and dynamic mechanical properties”, J Appl Polym Sci, 46(6): 949-957.
  • 4. Chen CH, Ma CCM., 1994, “Pultruded fibre-reinforced polyurethane composites. III. Static mechanical, thermal, and dynamic mechanical properties”, Compos Sci Technol, 52(3): 427-432.
  • 5. Vaikhanksi L, Nutt SR., 2003, “Synthesis of composite foam from thermoplastic “microspheres and 3D long fibers”, Compos A Appl Sci Manuf, 34(8):755-763.
  • 6. Vaikhanksi L, Nutt SR., 2003, “Fiber reinforced composite foam from expandable PVC Microspheres”, Compos A Appl Sci Manuf, 34(12):1245-1253.
  • 7. Chen W, Tao X, Liu Y., 2006, “Carbon Nanotube-Reinforced Polyurethane Composite Fibers”, Compos Sci Technol, 66(15):3029-3034.
  • 8. Xiong J, Zheng Z, Song W, Zhou D, Wang X., 2008, “Microstructure and properties of polyurethane nanocomposites reinforced with methylene-bis-orthochloroanilline-grafted multi-walled carbon nanotubes”, Compos A Appl Sci Manuf, 39(5): 904–910.
  • 9. Yang ZG, Zhao B, Qin SL, Hu ZF, Jin ZK, Wang JH., 2004, “Study on the mechanical properties of hybrid reinforced rigid polyurethane composite foam”, J Appl Polym Sci, 92(3):1493-1500.
  • 10. Saliba CC, Oréfice RL, Carneiro JRG, Duarte AK, Schneider WT. Fernandes MRF, 2005, “Effect of the incorporation of a novel natural inorganic short fiber on the properties of polyurethane composites”, Polym Test, 24(7): 819-824.
  • 11. de Mello D, Pezzin, SH, Amico SC, 2009, “The effect of post-consumer PET particles on the performance of flexible polyurethane foams”, Polym Test; 28(7): 702-708.
  • 12. Saint-Michel F, Chazeau L, Cavaille JY., 2006, “Mechanical properties of high density polyurethane foams: II. Effect of the filler size”, Compos Sci Technol, 66(15): 2709–2718.
  • 13. KUCEROVA Z, ZAJİCKOVA L, BURSİKOVA V, KUDRLE V, ELİAS M, JASEK O, SYNEK P, MATEJKOVA J, BURSİK J., 2009, “MECHANİCAL AND MİCROWAVE ABSORBİNG PROPERTİES OF CARBON-FİLLED POLYURETHANE”, MİCRON, 40(1):70-73.
  • 14. Vaidya AS, Vaidya UK, Udin N., 2008, “Impact response of three-dimensional multifunctional sandwich composite”, Mater Sci Eng A, 472(1-2):52-58.
  • 15. Liu K, Ovaert TC, Mason JJ., 2008, “Preparation and mechanical characterization of a PNIPA hydrogel composite”, J Mater Sci Mater Med, 19:1815–1821.
  • 16. Miao X, Lim WK, Huang X, Chen Y., 2005, “Preparation and characterization of interpenetrating phased TCP/HA/PLGA composites”, Mater Lett, 59(29- 30): 4000 – 4005.
  • 17. Ye L, Meng XY, Ji X, Li ZH, Tang JH., 2009, “Synthesis and characterization of expandable graphite–poly(methyl methacrylate) composite particles and their application to flame retardation of rigid polyurethane foams”, Polym Degrad Stab, 94: 971–979.
  • 18. Verdolotti L, Di Maio E, Lavorgna M, Iannace S, Nicolais L, 2008, “Polyurethane-cement-based and potential uses foams: Characterization and potential uses”, J Appl Polym Sci, 107(1):1-8.
  • 19. Bian XC, Tang JH, Li ZM., 2008, “Flame retardancy of whisker silicon oxide/rigid polyurethane foam composites with expandable graphite”, J Appl Polym Sci, 110(6):3871–3879.
  • 20. Ono T, Miyakoshi S, Watanabe U., 2002, “Acoustic characteristics of unidirectionally fiber-reinforced polyurethane foam composites for musical instrument soundboards”, Acoust Sci Tech, 23(3):135-142.
  • 21. Ono T, Isomura D., 2004, “Acoustic characteristics of carbon fiber-reinforced synthetic wood for musical instrument soundboards”, Acoust Sci Tech, 25(6):475-477.
  • 22. Corrêa RA, Nunes RCR, Lourenço VL. 1996, “Investigation of the degradation of thermoplastic polyurethane reinforced with short fibres”, Polym Degrad Stab, 52(3):245-251.
  • 23. Modesti M, Lorenzetti A, Besco S. 2007, “Influence of nanofillers on thermal insulatingproperties of polyurethane nanocomposites foams” Polym Eng Sci, 47(9):1351-1358.
  • 24. ZHOU H, Lİ B, HUANG G., 2006, “SOUND ABSORPTİON CHARACTERİSTİCS OF POLYMER MİCROPARTİCLES”, J APPL POLYM SCİ, 101(4):2675-2679.
  • 25. OKUDAİRA Y, ANDO H, SATOH M, MİYANAMİ K., 1998, “SOUND ABSORPTİON BY MULTİ-LAYERED CONSTRUCTİONS COMPOSED OF POWDER LAYERS AND POROUS SHEETS”, ELECTR ENG Jpn, 122(2):1-11.
  • 26. Zhou H, Li B, Huang G, He J., 2007, “A novel composite sound absorber with recycle rubber particles”, J Sound Vib, 304(1-2):400-406.
  • 27. Xu XB, Li ZM, Shi L, Bian XC, Xiang ZD., 2007, “Ultralight conductive carbon-nanotube-polymer composite”, Small, 3:408 – 411.
  • 28. Park KY, Lee SE, Kim CG, Han JH., 2006, “Fabrication and electromagnetic characteristics of electromagnetic wave absorbing sandwich structures”, Compos Sci Technol, 66(3-4):576–584.
  • 29. GAO Z, SU W, WU D., 2009, “Polyurethane–Solid Wood Composites. II. Flammability Parameters”, J APPL POLYM SCİ, 113(5):3279–3285.
  • 30. Patro TU, Harikrishnan G, Misra A, Khakhar DV., 2008, “Formation and characterization of polyurethane-vermiculite clay nanocomposite foams”, Polym Eng Sci, 48(9):1778-1784.
  • 31. Silva RV, Spinelli D, Bose Filho WW, Claro Neto S, Chierice GO, Tarpani JR., 2006, “Fracture toughness of natural fibers/castor oil polyurethane composites”, Compos Sci Technol, 66(10):1328-1335.
  • 32. Aranguren MI, Rácz I, Marcovich NE., 2007, “Microfoams based on costor oil polyurethanes and vegetables fibers”, J Appl Polym Sci, 105(5):2791-2800.
  • 33. JANG SY, KİM DJ, SEO KH., 2001, “PHYSİCAL PROPERTİES OF GARNET-FİLLED POLYURETHANE FOAM COMPOSİTE”, J APPL POLYM SCİ, 79(7):1336–1343.
  • 34. Bledzki AK, Zhang W, Chate A, 2001, Natural-fiber-reinforced Polyurethane microfoams”, Compos Sci Technol, 61(16):2405-2411.
  • 35. Seyidbeyoğlu MÖ, Oksman K., 2008, “Novel nanocomposites based on polyurethane and micro fibrillated cellulose”, Compos Sci Technol, 68(3-4)908- 914.
  • 36. Çelebi S, Development of a Natural Fiber Mixed Composite, Marmara University, Istanbul, Turkey, Ms. Thesis, 2010.
Tekstil ve Konfeksiyon-Cover
  • ISSN: 1300-3356
  • Yayın Aralığı: Yılda 4 Sayı
  • Yayıncı: Ege Üniversitesi Tekstil ve Konfeksiyon Araştırma & Uygulama Merkezi