Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment

Öz Major, trace, and rare earth element as well as C, O, and Sr isotope geochemistry is used to provide new insights into the characteristics and depositional environment of the protolith of the Föderata Group metacarbonates in the southern Veporicum cover sequence (Western Carpathians, Slovakia). The metacarbonates are characterized by high LOI and CaO and by small contents of various insoluble components. Among the trace elements investigated, only As, Ba, Co, Cu, Hg, Nb, Ni, Pb, Rb, Sb, Sr, Th, U, Y, Zn, and Zr display concentrations beyond their detection limits. The metacarbonates are strongly depleted in Rb, Ba, Th, Nb, Hf, Zr, and Y and enriched in U and Sr relative to the UCC. Chondrite-normalized rare earth element patterns of the metacarbonates show a moderate to strong fractionation in light rare earth elements over heavy rare earth elements and distinct negative Ce and Eu anomalies. Variation plots reveal several geochemical interrelationships, among which SiO2 - Al2O3 - K2O - TiO2 - Ba - Nb - Rb - Zr are associated with the rock's silicate fraction. The carbonate fraction comprise CaO, MgO, and Sr. The overall geochemical and C-, O-, and Sr-isotopic signatures indicate that the metacarbonates developed from sedimentary carbonate materials that were deposited in a saline, shallow-marine, low-energy environment. The negative Ce anomaly (Ce/Ce* = 0.15-0.93) and the δ13C (2.36%o to -3.34%o) values indicate warmer climatic conditions during deposition. The consistency of the rock's chemical properties could be attributed to the relative stability experienced during the parent sedimentary material's deposition.

Kaynak Göster

Bibtex @araştırma makalesi { tbtkearth390071, journal = {Turkish Journal of Earth Sciences}, issn = {1300-0985}, eissn = {1303-619X}, address = {}, publisher = {TÜBİTAK}, year = {2016}, volume = {25}, pages = {513 - 537}, doi = {}, title = {Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment}, key = {cite}, author = {Vdacny, Marek and Ruzıcka, Peter and Vozarova, Anna} }
APA Vdacny, M , Ruzıcka, P , Vozarova, A . (2016). Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment . Turkish Journal of Earth Sciences , 25 (6) , 513-537 .
MLA Vdacny, M , Ruzıcka, P , Vozarova, A . "Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment" . Turkish Journal of Earth Sciences 25 (2016 ): 513-537 <
Chicago Vdacny, M , Ruzıcka, P , Vozarova, A . "Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment". Turkish Journal of Earth Sciences 25 (2016 ): 513-537
RIS TY - JOUR T1 - Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment AU - Marek Vdacny , Peter Ruzıcka , Anna Vozarova Y1 - 2016 PY - 2016 N1 - DO - T2 - Turkish Journal of Earth Sciences JF - Journal JO - JOR SP - 513 EP - 537 VL - 25 IS - 6 SN - 1300-0985-1303-619X M3 - UR - Y2 - 2021 ER -
EndNote %0 Turkish Journal of Earth Sciences Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment %A Marek Vdacny , Peter Ruzıcka , Anna Vozarova %T Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment %D 2016 %J Turkish Journal of Earth Sciences %P 1300-0985-1303-619X %V 25 %N 6 %R %U
ISNAD Vdacny, Marek , Ruzıcka, Peter , Vozarova, Anna . "Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment". Turkish Journal of Earth Sciences 25 / 6 (Aralık 2016): 513-537 .
AMA Vdacny M , Ruzıcka P , Vozarova A . Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment. Turkish Journal of Earth Sciences. 2016; 25(6): 513-537.
Vancouver Vdacny M , Ruzıcka P , Vozarova A . Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment. Turkish Journal of Earth Sciences. 2016; 25(6): 513-537.
IEEE M. Vdacny , P. Ruzıcka ve A. Vozarova , "Geochemistry and C, O, and Sr isotope composition of the Föderata Group metacarbonates (southern Veporicum, Western Carpathians, Slovakia): constraints on the nature of protolith and its depositional environment", Turkish Journal of Earth Sciences, c. 25, sayı. 6, ss. 513-537, Ara. 2016