Mehmet A. OTURAN, A. Shirish PATIL, Maurice MEDEBIELLE, Robert S. KLEIN

2811

Steric Effects on the Oxidation Potential of 1-aryl Thioglycosides

The electrochemical oxidation of several 1-arylthioglycosides has been studied by cyclic voltammetry in acetonitrile. We found that the oxidation potential of the a anomer always occurs at a less positive oxidation potential than of the b anomer. The difference in the oxidation potential depends on the substituent attached on the C-3 of the sugar moiety and is greatly influenced by the stability of the radical cation obtained after the first electron transfer.
Anahtar Kelimeler:

Thioglycosides, cyclic voltammetry, oxidation potentials, steric effects.

Steric Effects on the Oxidation Potential of 1-aryl Thioglycosides

The electrochemical oxidation of several 1-arylthioglycosides has been studied by cyclic voltammetry in acetonitrile. We found that the oxidation potential of the a anomer always occurs at a less positive oxidation potential than of the b anomer. The difference in the oxidation potential depends on the substituent attached on the C-3 of the sugar moiety and is greatly influenced by the stability of the radical cation obtained after the first electron transfer.
Keywords:

Thioglycosides, cyclic voltammetry, oxidation potentials, steric effects.,

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Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
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