Stephane SCHWEIZER, Guillaume ERBLAND, Philippe BISSERET, Jacques LALEVEE, Didier Le NOUEN, Nicolas BLANCHARD

7983

Sonogashira reactions for the synthesis of polarized pentacene derivatives

Five dissymmetrically functionalized anthracene analogues (\textbf{3a}--\textbf{e}) were synthesized from commercially available 9,10-dibromoanthracene through an efficient bromine--iodine exchange followed by two successive Sonogashira coupling reactions. The resulting TMS-anthracene analogues are interesting building blocks for the preparation of highly $\pi$-conjugated dissymmetric pentacene-based dyads, which could be used as active semiconducting layers for organic field-effect transistors (OFETs).
Anahtar Kelimeler:

Sonogashira reaction, anthracene, pentacene, organic field-effect transistors

Sonogashira reactions for the synthesis of polarized pentacene derivatives

Five dissymmetrically functionalized anthracene analogues (\textbf{3a}--\textbf{e}) were synthesized from commercially available 9,10-dibromoanthracene through an efficient bromine--iodine exchange followed by two successive Sonogashira coupling reactions. The resulting TMS-anthracene analogues are interesting building blocks for the preparation of highly $\pi$-conjugated dissymmetric pentacene-based dyads, which could be used as active semiconducting layers for organic field-effect transistors (OFETs).
Keywords:

Sonogashira reaction, anthracene, pentacene, organic field-effect transistors,

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Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
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