Fatma ÇETİN TELLİ, Selin YILDIRAN, Serpil DENİZALTI

Newly synthesized furanoside-based NHC ligands for the arylation of aldehydes

New furanoside-based NHC precursor salts (2) were synthesized using amino alcohols from the chloralosederivatives of glucose (a), galactose (b), and mannose (c). The novel compounds were fully characterized by1H NMR,13C NMR, and elemental analyses. The catalytic activities of these salts were tested in the arylation of aldehydes ascatalysts that were generated in situ from [RhCl(COD)]2. In addition,2awas converted to the rhodium complex3ainorder to compare the results obtained in situ. The newly synthesized compounds were very efficient in terms of yield;nevertheless they did not exhibit a chiral induction.

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