Samaneh NADALI, Ali KHOSHROO, Ghasem AGHAPOUR

Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids

Öz A rapid and selective iron-mediated reductive Claisen rearrangement of various prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones to 1-hydroxy-2-(prop-2'-enyl)anthraquinones and anthrafurandiones is presented. All reactions are carried out in a mixture of ionic liquids, [Bzmim]Cl (1-benzyl-3-methylimidazolium chloride) and [Hmim]BF$_{4}$ (1-methylimidazolium tetrafluoroborate), in short reaction times (5-35 min). Our study showed that 1-(prop-2'-enyloxy)anthraquinone is more active than 1-(2'-chloroprop-2'-enyloxy)anthraquinone to perform this rearrangement.

Anahtar Kelimeler:

2'-Chloroprop-2'-enyloxyanthraquinone, anthrafurandione, Claisen rearrangement, iron, ionic liquid

Tam Metin

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Bibtex	`@ { tbtkchem572706, journal = {Turkish Journal of Chemistry}, issn = {1300-0527}, eissn = {1303-6130}, address = {}, publisher = {TÜBİTAK}, year = {2018}, volume = {42}, pages = {883 - 895}, doi = {}, title = {Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids}, key = {cite}, author = {Nadalı, Samaneh and Khoshroo, Ali and Aghapour, Ghasem} }`
APA	Nadalı, S , Khoshroo, A , Aghapour, G . (2018). Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids . Turkish Journal of Chemistry , 42 (3) , 883-895 .
MLA	Nadalı, S , Khoshroo, A , Aghapour, G . "Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids" . Turkish Journal of Chemistry 42 (2018 ): 883-895 <
Chicago	Nadalı, S , Khoshroo, A , Aghapour, G . "Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids". Turkish Journal of Chemistry 42 (2018 ): 883-895
RIS	TY - JOUR T1 - Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids AU - Samaneh Nadalı , Ali Khoshroo , Ghasem Aghapour Y1 - 2018 PY - 2018 N1 - DO - T2 - Turkish Journal of Chemistry JF - Journal JO - JOR SP - 883 EP - 895 VL - 42 IS - 3 SN - 1300-0527-1303-6130 M3 - UR - Y2 - 2021 ER -
EndNote	%0 Turkish Journal of Chemistry Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids %A Samaneh Nadalı , Ali Khoshroo , Ghasem Aghapour %T Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids %D 2018 %J Turkish Journal of Chemistry %P 1300-0527-1303-6130 %V 42 %N 3 %R %U
ISNAD	Nadalı, Samaneh , Khoshroo, Ali , Aghapour, Ghasem . "Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids". Turkish Journal of Chemistry 42 / 3 (Haziran 2018): 883-895 .
AMA	Nadalı S , Khoshroo A , Aghapour G . Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids. Turk J Chem. 2018; 42(3): 883-895.
Vancouver	Nadalı S , Khoshroo A , Aghapour G . Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids. Turkish Journal of Chemistry. 2018; 42(3): 883-895.
IEEE	S. Nadalı , A. Khoshroo ve G. Aghapour , "Efficient reductive Claisen rearrangement of prop-2'-enyloxyanthraquinones and 2'-chloroprop-2'-enyloxyanthraquinones with iron powder in ionic liquids", Turkish Journal of Chemistry, c. 42, sayı. 3, ss. 883-895, Haz. 2018