Analysis of electro chemical noise in NiCd batteries throughout their lifetime

Electrochemical noise measurements have been applied to electrochemical systems that show stochasticbehavior. The standard area of study that benefits from this stochastic analysis is localized corrosion modes like pittingand crevice corrosion. Application of electrochemical noise measurements to battery systems, though rare, is recentlybecoming more popular. The present contribution first establishes a method of analyzing electrochemical voltage noisedata for NiCd batteries, then follows four samples of batteries in terms of voltage noise throughout their lifetimes.The noises exhibited by battery systems are small, but finite. This noise is expected to be due to variations in theelectrochemistry on the electrode surfaces of the battery. After careful analysis, the voltage noise behavior of NiCdbatteries does not appear to show a statistically significant variation of electrochemical voltage noise throughout theirlifetimes.

PDF

___

1. Barker, G. C. Electroanal. Chem. Inter. Electrochem. 1969, 21, 127-136.
2. Blanc, G.; Gabrielli, C.; Keddam, M. Electrochim. Acta 1975, 20, 687-689.
3. Hladky, K.; Dawson, J. L. Corr. Sci. 1980, 21, 317-322.
4. Mansfeld, F.; Xiao, H. J. Electrochem. Soc. 1993, 140, 2205-2210.
5. Legat, A.; Doleˇcek, V. J. Electrochem. Soc. 1995, 142, 1851-1859.
6. Roberge, P. R.; Lenard, D. R.; J. Appl. Electrochem. 1998, 28, 405-410.
7. Cottis, R. A. Corrosion 2001, 57, 265-286.
8. Aballe, A.; Bethencourt, M.; Botana, F. J.; Marcos, M. Electrochem. Comm. 1999 1, 266-270.
9. Cottis, R. A.; Homborg, A. M.; Mol, J. M. C. Electrochim. Acta 2016, 202, 277-287.
10. Roberge, P. R. Corrosion 1999, 50, 502-513.
11. Knott, K. F. IEEE Electronics Letters 1965, 1, 132.
12. Roberge, P. R.; Beaudoin, R.; Verville, G.; Smit, J. J. Pow. Sources 1989, 27, 177-186.
13. Martinet, S.; Durand, R.; Ozil, P.; Leblanc, P.; Blanchard, P. J. Pow. Sources 1999, 83, 93-99.
14. Baert, D. H. J.; Vervaet, A. A. K. J. Pow. Sources 2003, 114, 357-365.
15. Martemianov, S.; Adiutantov, N.; Evdokimov, Yu. K.; Madier, L.; Malliard, F.; Thomas, A. J. Sol. State Electrochem. 2015, 29, 2803-2810.
16. Motchenbacher, C. D. Low Noise Electronic System Design; John Wiley and Sons: New York, NY, USA, 1993.
17. Mansfeld, F.; Sun, Z.; Hsu, C. H.; Nagiub, A. Corros. Sci. 2001, 43, 341-352.