Arda YALÇUK, Berrin TOPUZ, Şennur Merve ADANUR

A new method for simultaneous determination of trace amounts of Cu(II) and Ni(II) ions by preconcentration and spectrophotometric analysis

Immediate preconcentration and spectrophotometric methods have been developed for the determination of trace amounts of cupric ion (Cu(II)) and nickel ion (Ni(II)) through a solid phase extraction with XAD-4-N,N -bis- (salicylidene) cyclohexanediamine (XAD-4-SCHD) resin and a complex color reaction of the ions with 2,6-dimethylmorpholine dithiocarbamate (DMMDTC) in Triton X-100 media. A high preconcentration factor of 125 was achieved. The spectrophotometric method was based on the measurements of the absorption of colored chelates of ions complexing with DMMDTC, and the adsorptions of the complex solutions were measured at their maximum absorption peaks at 460 and 328 nm for Cu(II) and Ni(II) ions, respectively. The impact of the complexing reaction variables including type and amount of surfactant, pH, amount of ligand, and complexation time on the sensitivity of the proposed method was optimized. Calibration graphs were found to be linear in the ranges of 0.02 3 and 0.02 2.5 mg L −1 with detection limits of 5 and 7 µg L −1 for Cu(II) and Ni(II), respectively. The accuracy of the developed method was calculated by recovering all Cu(II) and Ni(II) ions in synthetic and TMDA-70.2 certified reference water samples. Results of the proposed method were also compared with inductively coupled plasma-mass spectrometry results for the determination of trace Cu(II) and Ni(II) ions in water samples.

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1. Tapiero, H.; Townsend, D. M.; Tew, K. D. Biomed. Pharmacother. 2003, 57, 386-398.
2. Chipasa, K. B. Waste Manage. 2003, 23, 135-143.
3. Safavi, A.; Abdollahi, H.; Nezhad, M. H.; Kamali, R. Spectrochim. Acta A 2004, 60, 2897-2901.
4. Louie, H., Wu, M.; Di, P.; Snitch, P.; Chapple, G. J. Anal. At. Spectrom. 2002, 17, 587-591.
5. Prange, A.; Kn¨ochel A.; Michaelis, W. Anal. Chim. Acta 1985, 172, 79-100.
6. Gordeeva, V. P.; Statkus, M. A.; Sorokina, N. M.; Tsizin, G. I.; Zolotov, Y. A. J. Anal. Chem. 2002, 57, 834-841.
7. Achterberg, E. P.; Braungardt, C. Anal. Chim. Acta 1999, 400, 381-397.
8. Komjarova, I.; Blust, R. Anal. Chim. Acta 2006, 576, 221-228.
9. D¨abrowski, A.; Hubicki, Z.; Podko´scielny, P.; Robens, E. Chemosphere 2004, 56, 91-106.
10. Shukla, S. R.; Pai, R. S. Bioresour. Technol. 2005, 96, 1430-1438.
11. Elci, L.; Soylak, M.; Ozcan, B. ¨ Anal. Lett. 2003, 36, 987-999.
12. Candir, S.; Narin, I.; Soylak, M. Talanta 2008, 77, 289-293.
13. Bezerra, M. A.; Arruda, M. A. Z.; Ferreira, S. L. C. Appl. Spectrosc. Rev. 2005, 40, 269-299.
14. Paleologos, E. K.; Giokas, D. L.; Karayannis, M. I. Trends Anal. Chem. 2005, 24, 426-436.
15. Chen, J.; Teo, K. C. Anal. Chim. Acta 2001, 450, 215-222.
16. Narin, I.; Soylak, M.; Elci, L.; Dogan, M. Anal. Lett. 2001, 34, 1935-1947.
17. Marahel, F.; Ghaedi, M.; Montazerozohori, M.; Biyareh, M. N.; Kokhdan, S. N.; Soylak, M. Food Chem. Toxicol. 2011, 49, 208-214.
18. Gholivand, M. B.; Ahmadi, F.; Rafiee, E. Sep. Sci. Technol. 2007, 42, 897-910.
19. Cesur, H. Chem. Pap. 2007, 61, 342-347.
20. Bulut, V. N.; Gundogdu, A.; Duran, C.; Senturk, H. B.; Soylak, M.; Elci, L.; Tufekci, M. J. Hazard. Mater. 2007, 146, 155-163.
21. Amin, A. S.; Al-Attas, A. S. J. Saudi Chem. Soc. 2012, 16, 451-459.
22. Pancras, J. P.; Puri, B. K. Anal. Bioanal. Chem. 2002, 374, 1306-1311.
23. Ramesh, A.; Mohan, K. R.; Seshaiah, K. Talanta 2002, 57, 243-252.
24. Yang, G.; Dong, X.; Hu, Q.; Yin, J. Anal. Lett. 2002, 35, 1735-1745.
25. Sharma, R. K.; Puri, A.; Kumar, A.; Monga, Y.; Gaba, G.; Adholeya, A. Sep. Sci. Technol. 2014, 49, 709-720.
26. Rezaei, B.; Sadeghi, E.; Meghdadi, S. J. Hazard. Mater. 2009, 168, 787-792.
27. Chandra Rao, G. P.; Veni, S. S.; Pratap, K.; Koteswara Rao, Y.; Seshaiah, K. Anal. Lett. 2006, 39, 1009-1021.
28. Kanchi, S.; Singh, P.; Bisetty, K. Arabian J. Chem. 2014, 7, 11-25.
29. Tuzen, M.; Saygi, K. O.; Soylak, M. J. Hazard. Mater. 2008, 152, 632-639.
30. Arain, M. A.; Wattoo, F. H.; Wattoo, M. H. S.; Ghanghro, A. B.; Tirmizi, S. A.; Iqbal, J.; Arain, S. A. Arabian J. Chem. 2009, 2, 25-29.
31. Afkhami, A.; Madrakian, T.; Bozorgzadeh, E., Bahram, M. Talanta 2007, 71, 1103-1109.
32. Arvand, M.; Abolghasemi, S.; Zanjanchi, M. A. J. Anal. Chem. 2007, 62, 342-347.
33. Karayunlu, S.; Ay, U. J. Anal. Chem. 2010, 65, 244-48.
34. Ghaedi, M. Spectrochim. Acta A 2007, 66, 295-301.
35. Shar, G. A.; Bhanger, M. I. J. Chem. Soc. Pak. 2002, 24, 185-189.
36. Zaijun, L.; Yuling, Y.; Jian, T.; Jiaomai, P. Talanta 2003, 60, 123-130.
37. Topuz, B.; Macit, M. Environ. Monit. Assess. 2011, 173, 709-722.
38. Hejazi, L.; Mohammadi, D. E.; Yamini, Y.; Brereton, R. G. Talanta 2004, 62, 185-191.
39. Golcu, A. Transit. Met. Chem. 2006, 31, 405-412.
40. Sharma, S.; Rahman, N.; Azmi, S. N. H.; Iqbal, B.; Amburk, M. I. B. B.; Al Barwani, Z. M. H. J. Chin. Chem. Soc. 2010, 57, 622-631.
41. Reddy, K. J.; Kumar, J. R.; Narayana, S. L.; Ramachandraiah, C.; Thriveni, T.; Reddy, A. V. Environ. Monit. Assess. 2007, 124, 309-320.
42. Sarma, L. S.; Kumar, J. R.; Reddy, K. J.; Reddy, A. V. J. Agr. Food. Chem. 2005, 53, 5492-5498.
43. Topuz, B.; Macit M. In: 6th Aegean Analytical Chemistry Days; Pamukkale University: Denizli, Turkey, 2008.
44. Topuz, B.; Okur, G. In: 1st International Black Sea Congress on Environmental Sciences ; Giresun, Turkey, 2016.