RABİA DELİKUŞ, EMİNE ÇAKIR, NADİR DEMİREL, METİN BALCI, BETÜL KARATAŞ

103124

Synthesis of novel chiral bisoxazoline ligands with a norbornadiene backbone: use in the copper-catalyzed enantioselective Henry reaction

Novel chiral bisoxazoline ligands based on norbornadiene were synthesized and used for the asymmetric Henry reaction. Various aromatic aldehydes were converted into chiral $\beta $-nitro alcohols with high yields and moderate to acceptable enantioselectivities under the optimized reaction conditions.
Keywords:

Asymmetric synthesis, Henry reaction, chiral bisoxazolines, nitroaldol, copper,

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Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
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Synthesis of novel chiral bisoxazoline ligands with a norbornadiene backbone: usein the copper-catalyzed enantioselective Henry reaction

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