One-step potentiostatic codeposition and electrochemical studies of poly(1-pyrenyl)-2,5-di(2-thienyl)pyrrole-co-pyrrole) film for electrochemical supercapacitors
In this paper, we report a simple, low-cost, and
environmentally friendly electrochemical method to obtain a novel copolymer
consisting of 1-pyrenyl-2,5-di(2-thienyl)pyrrole and pyrrole on a pencil
graphite electrode (PGE).
Poly(1-pyrenyl)-2,5-di(2-thienyl)pyrrole-co-pyrrole) that is P(PyrPy-co-Py)
film was prepared by one-step potentiostatic codeposition in an ethanol
solution containing PyrPy and Py monomers for supercapacitor applications.
The electrodeposition of homopolymer and copolymer modified electrodes was
carried out on the surface of the PGE via chronocoulometry. For comparison,
P(Py)/PGE and P(PyrPy)/PGE were also electrochemically synthesized under the
same reaction conditions. The surface morphologies of all the electrode
materials were analyzed by field emission scanning electron microscopy. The
capacitive properties of the modified PGEs were investigated in 1 M
H22_{2}SO44_{4} electrolyte solution by cyclic voltammetry, electrochemical
impedance spectroscopy, and galvanostatic charge-discharge methods. Compared
with P(Py)/PGE and P(PyrPy)/PGE, the P(PyrPy-co-Py)/PGE composite exhibited
the best electrochemical behavior and had the highest specific capacitance
value of 397.18 F g−1−1^{-1} in 1 M H22_{2}SO44_{4} at a scan rate of 2 mV
s−1−1^{-1}. These results indicated that this modified electrode can be used
as an electrode material for electrochemical supercapacitors.
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