Niyazi BULUT, Tankut ATEŞ, Serdar ACAR, Süleyman KÖYTEPE, Ömer KAYGILI, Turan İNCE, Serhat KESER

Fe ve Ti katkılı Çift Fazlı Kalsiyum Fosfatların Sentez ve Karakterizasyonu

Bu çalışmada, Ti katkısının Fe esaslı çift fazlı kalsiyum fosfat malzemelerinin yapısal, morfolojik ve termal özellikleri üzerine etkileri araştırılmıştır. X-ışını kırınımı (XRD) analizi, üretilen numunelerin hem hidroksiapatit (HAp) hem de beta trikalsiyum fosfat (β-TCP) fazlarına sahip olduğunu doğrulamaktadır. Ayrıca, Ti katkısındaki artışla β-TCP fazının miktarının arttığı görülmektedir. Fourier dönüşümlü kızılötesi (FTIR) spektroskopisi sonuçları, numunelerdeki karakteristik fonksiyonel grupların varlığını doğrulamaktadır. Ti miktarı morfolojiyi etkilemektedir. Numunelerin ısıl davranışları birbirine benzerdir ve oda sıcaklığından 1000 °C’ye kadar tüm numuneler termal olarak kararlıdırlar. Bu sıcaklık aralığında numunelerdeki kütle kayıpları % 1,63’e eşit veya altındadır.

Anahtar Kelimeler:

Hidroksiapatit, Beta trikalsiyum fosfat (β-TCP), X-ışını kırınımı (XRD), Morfoloji

Synthesis and Characterization of Fe and Ti Doped Biphasic Calcium Phosphates

In this study, the effects of Ti doping on the structural, morphological, and thermal properties of the Fe-based biphasic calcium phosphates have been investigated. X-ray diffraction (XRD) analysis has verified that the-as produced samples have both hydroxyapatite (HAp) and beta-tricalcium phosphate (β-TCP) phases. Besides, it has been seen that the amount of β-TCP phase increases with the increase in Ti doping. Fourier transform infrared (FTIR) spectroscopy results have verified the existence of the characteristic functional groups in the samples. Ti amount affects the morphology. The thermal behaviors of the samples are similar to each other, and all the samples are thermally stable from room temperature to 1000 °C. In this temperature range, the mass losses in the samples are equal to or smaller than 1.63 %.

Keywords:

Hydroxyapatite, Beta tricalcium phosphate (β-TCP), X-ray diffraction (XRD), Morphology,

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