İki Boyutlu Malzemelerin Tekstil Yüzeylerine Transferi

Son yıllarda 2 boyutlu malzemeler üzerinde yapılan çalışmalar büyük bir ilgi uyandırmıştır. Bu çalışmada iki boyutlu malzemelerden birisi olan molibden disülfür (MoS2), kimyasal buhar biriktirme tekniği ile sentezlenerek çeşitli tekstil yüzeylerine transfer edilmiştir. Tekstil yüzeyleri üzerindeki MoS2 film optik mikroskop, AFM, SEM, ve Raman cihazları kullanılarak karakterize edilmiştir. Bu çalışmanın sonuçları iki boyutlu malzemelerin tekstil yüzeylerine kolayca transfer edilebileceğini göstermektedir. Böylelikle iki boyutlu malzemelerin tekstil mamullerine aplikasyonu ve çeşitli uygulamalarda kullanılmasının önü açılmıştır.

Anahtar Kelimeler:

İki boyutlu malzemeler, molibden disülfür, grafen, transfer

Transferring 2-Dimensional Materials on Textile Surfaces

Scientific studies conducted on 2 Dimensional materials have been receiving great interest in recent years. In this study we have synthesized two dimensional molybdenum disulfide via chemical vapor deposition technique and then transferred onto several textile surfaces. MoS2 film on textile surfaces has been characterized using optical microscope, AFM, SEM, and Raman instruments. Our results indicate that two-dimensional materials can be easily transferred onto textile substrates. These findings pave the way of combining two dimensional materials with textile products in several applications.

Keywords:

2-Dimensional materials, molybdenum disulfide, graphene, transfer,

PDF

___

Geim, A.K., Novoselov, K.S. (2007), The rise of graphene. Nat. Mater. 6, 183-191.
Novoselov, K.S. (2009) Graphene: The magic of flat carbon. ECS Transactions 19(5), 3-7.
L., Huang, G., Li, A., Gurarslan, Y., Yu, R., Kirste, W., Guo, J., Zhao, R., Collaza, Z., Sitar, G.N., Parsons, M., Kudenov, L., Cao. (2016) Atomically Thin MoS2 Narrowband and Broadband Light Superabsorbers, ACS Nano 10, 7493-7499
Y Yu, Y Yu, Y Cai, W Li, A Gurarslan, H Peelaers, DE Aspnes, CG Van de Walle, NV Nguyen, YW Zhang, L Cao. (2015) Exciton-dominated Dielectric Function of Atomically Thin MoS2 Films, Scientific Reports, 5, 16996.
Pu, J., Yomogida, Y., Liu, K.K., Li, L.J., Iwasa, Y. and Takenobu, T., (2012) Highly flexible MoS2 thin-film transistors with ion gel dielectric, Nano letters, 12(8), 4013-4017.
Yoon, J., Park, W., Bae, G.Y., Kim, Y., Jang, H.S., Hyun, Y., Lim, S.K., Kahng, Y.H., Hong, W.K., Lee, B.H. and Ko, H.C., (2013), Highly flexible and transparent multilayer MoS2 transistors with graphene electrodes, Small, 9(19), 3295-3300.
Salvatore, G.A., Münzenrieder, N., Barraud, C., Petti, L., Zysset, C., Büthe, L., Ensslin, K. and Tröster, G., (2013), Fabrication and transfer of flexible few-layers MoS2 thin film transistors to any arbitrary substrate, ACS nano, 7(10).
Miao, X., Tongay, S., Petterson, M.K., Berke, K., Rinzler, A.G., Appleton, B.R. and Hebard, A.F., (2012), High efficiency graphene solar cells by chemical doping, Nano letters, 12(6), 2745-2750.
Xiao, J., Choi, D., Cosimbescu, L., Koech, P., Liu, J. and Lemmon, J.P., (2010), Exfoliated MoS2 nanocomposite as an anode material for lithium ion batteries, Chemistry of Materials, 22(16), 4522-4524.
Chow, P.K., Singh, E., Viana, B.C., Gao, J., Luo, J., Li, J., Lin, Z., Elias, A.L., Shi, Y., Wang, Z. and Terrones, M., (2015) Wetting of mono and few-layered WS2 and MoS2 films supported on Si/SiO2 substrates, ACS nano, 9(3), 3023-3031.
Gurarslan, A., Jiao, S., Li, T.D., Li, G., Yu, Y., Gao, Y., Riedo, E., Xu, Z. and Cao, L., (2016), Van der waals force isolation of monolayer MoS2, Advanced Materials, 28(45), 10055-10060.
Yu, Y., Li, C., Liu, Y., Su, L., Zhang, Y. and Cao, L., 2013. Controlled scalable synthesis of uniform, high-quality monolayer and few-layer MoS2 films. Scientific reports, 3.
Gurarslan, A., Yu, Y., Su, L., Yu, Y., Suarez, F., Yao, S., Zhu, Y., Ozturk, M., Zhang, Y. and Cao, L., 2014. Surface-energy-assisted perfect transfer of centimeter-scale monolayer and few-layer MoS2 films onto arbitrary substrates. ACS Nano, 8(11), pp.11522-11528.
Neves, A.I.S., Bointon, T.H., Melo, L.V., Russo, S., Schrijver, I., Craciun, M.F. and Alves, H., 2015. Transparent conductive graphene textile fibers. Scientific Rerpots, 5, pp. 9866-9872.
Neves, A.I.S., Rodrigues, D.P., Sanctis, A., Alonso, E.T., Pereira, M.S., Amaral, V.S, Melo, L.V., Russo, S., Schrijver, I., Alves, H. and Craciun, M.F., 2017. Towards conductive textiles: coating polymeric fibres with graphene. Scientific Rerpots, 7, pp. 4250-4260.
Shakir, I., Ali, Z., Bae, J., Park, J. And Kang, D.J., 2014. Layer by layer assembly of ultrathinV2O5 anchored MWCNTs and graphene on textile fabrics for fabrication of high energy density flexible supercapacitor electrodes. Nanoscale, 6, pp. 4125-4130.
Wu, C., Kim, T.W., Guo, T. and Li, F., 2017. Wearable ultra-lightweight solar textiles based on transparent electronic fabrics. Nano Energy, 32, pp. 367-373.
He, Q., Zeng, Z., Yin, Z., Li, H., Wu, S., Huang, X. and Zhang, H., 2012. Fabrication of Flexible MoS2 Thin-Film Transistor Arrays for Practical Gas-Sensing Applications. Small, 8 (19), pp. 2994-2999.
Zhao, C., Zhou, Y., Ge, Z., Zhao, C. and Qian, X,. 2018. Facile construction of MoS2/RCF electrode for high-performance supercapacitor. Carbon, 127, pp. 699-706.
Brenna, C.J., Nguyen, J., Yu, E.T. and Lu, N., 2015. Interface Adhesion between 2D Materials and Elastomers Measured by Buckle Delaminations. Adv. Mater. Interfaces, 2, pp. 1500176-1500182.