UTILIZATION OF UREA POWDERS WITH DIFFERENT SIZES AS A FORMALDEHYDE-SCAVENGER IN THE PARTICLEBOARD MANUFACTURING

In this study, the effects of different size and rate of urea powder usage in particleboard manufacturing on the formaldehyde emission of the boards were investigated. Two different sizes (Large, Small) and five different rates of urea powder (1, 2, 3, 4 and 5%) were used for particleboard manufacturing. Urea formaldehyde (1.35 moles) adhesive was used for production of three layered particleboards. Formaldehyde contents were determined by perforator method according to EN 120. Furthermore, mechanical and physical properties including bending strength, modulus of elasticity, internal bond strength, surface stability, thickness swelling and water absorption of the samples were determined according to EN 310, EN 319 and EN 317 standards, respectively. Formaldehyde emission values were decreased with the mixing of the urea powder with chips prior to gluing and the produced boards had E0 grade in terms of formaldehyde emission. The size and rate of the urea powder were statistically effective on the mechanical and physical properties of the produced boards. In addition, all of the boards produced with small size urea powders satisfied the required standards for mechanical, physical and formaldehyde emission properties, except groups produced with 5% small size urea powder. It should be noted that slight decrease of mechanical and physical properties were observed with the loading of urea powder. As a result, it was determined that using of the small size urea powder provided better results than large size.

___

  • [1] International Agency for Research on Cancer (IARC) (1995) Wood dust and formaldehyde. IARC Monogr Eval Carcinog Risks Hum, 62:1–405.
  • [2] International Agency for Research on Cancer (IARC) (2006) Formaldehyde, 2-butoxyethanol and 1-tertbutoxypropan-2-ol. IARC Monogr Eval Carcinog Risks Hum, 88:1–478. PMID:17366697.
  • [3] Şahin H.T., Filiz M., Kaya A.İ., Usta P., Çiçekler M., Bozkurt C. (2011) Formaldehid Tutkalı ve Formaldehid Emisyonu. Laminart, Sayı:39.
  • [4] Beer J., Schmidt H. and Bistram E.V. 1994. Method for the Fabrication of Particle Boards and Fibreboards with Low Formaldehyde Content Using Tannin Based Binders. European Patent Office. Patent number: EP0788866B1
  • [5] Çolak S., Öztürk H., Demir A., 2009. Yonga Levhaların Formaldehit Emisyonu Üzerine Tanen ve Kitosanın Etkileri.
  • [6] Pizzi A. 1994. Advanced Wood Adhesives Technology. Marcel Dekker, Inc.
  • [7] Boran S., Usta M., Gümüşkaya E. 2011. Decreasing Formaldehyde Emission from Medium Density Fiberboard Panels Produced by Adding Different Amine Compounds to Urea Formaldehyde Resin. International Journal of Adhesion and Adhesives, 31(7):674-678.
  • [8] Atar İ., Nemli G., Ayrilmis N., Baharoğlu M., Sarı B. and Bardak S. 2014. Effects of Hardener Type, Urea Usage and Conditioning Period On the Quality Properties of Particleboard. Materials & Design (1980-2015) 56, 91-96.
  • [9] Costa N.A., Pereira J., Ferra J., Cruz P., Martins J., Magalhaes F.D., Mendes A. and Carvalho L.H. 2013. Scavengers for Achieving Zero Formaldehyde Emission of Wood-Based Panels. Wood Sci Technol (2013) 47:1261–1272.
  • [10] Boran, S., Usta, M. and Gümüşkaya, E. 2011. Decreasing formaldehyde emission from medium density fibreboard panels produced by adding different amine compounds to urea formaldehyde resin. International Journal of Adhesion and Adhesives 31: p. 674-678.
  • [11] Boran, S., Usta, M., Ondaral, S. and Gümüşkaya, E. 2012. The Efficiency of tannin as a formaldehyde scavenger chemical in medium density fibreboard. Composites: Part B 43: p. 2487-2491.
  • [12] Ghani, A., Bawon, P., Ashaari, Z., Wahab, M.W. and Hua, L.S. 2017. Addition of Propylamine as Formaldehyde Scavenger for Urea Formaldehyde-Bonded Particleboard. WOOD RESEARCH 62 (2): p. 329-334.