ENVIRONMENTAL TOXICITY CHARACTERISTICS OF NEMRUT VOLCANISM PYROCLASTIC, BITLIS/TURKEY CASE

ENVIRONMENTAL TOXICITY CHARACTERISTICS OF NEMRUT VOLCANISM PYROCLASTIC, BITLIS/TURKEY CASE

This study aims to determine and evaluate the toxicity characteristics of Ahlat stone and pumice, which are pyroclastic rocks specific to Nemrut Volcanism and are common construction materials in the region. There are several studies in the literature that deals with constructional properties, but environmental properties have not been evaluated yet. Behaviour of Pyroclastic rocks due to the environmental conditions are important because pyroclastic rocks contain heavy metals (lead, chromium arsenic, etc.) in their structures due to geological activities. Depending on environmental conditions, these heavy metals can be released from the rock structure and cause hazardous health problems in people who contact them. This situation is directly related to the stability of the rock structure. The TCLP procedure was applied in this study to determine the stability of the rock structure and to determine the potential effect of heavy metals released from the structure on human health and the results obtained were evaluated. The obtained XRF results show that the different colored examined Ahlat stones consist mainly of SiO2, Al2O3, K2O, and Fe2O3 compounds.TCLP results show that the materials are in stable structures, they are not affected by environmental conditions and the amount of heavy metal leakage from structures is very low. However, chromium and arsenic in volcanic areas can have a carcinogenic effect on children. For this reason, a comprehensive soil and water pollution monitoring and analysis study is recommended in the volcanic area for public health.

___

  • [1] Ma Q., Han, L., Zhang, J., Zhang, Y., Lang, Q., Li, F., ... & Alu, S. (2019). Environmental Risk Assessment of Metals in the Volcanic Soil of Changbai Mountain. International Journal of Environmental Research and Public Health, 16(11), 2047. [2] Sparks RSJ., Walker GPL. (1973). The Ground Surge Deposit: a Third Type of Pyroclastic Rock. Nature Physical Science, 241(107), 62-64.
  • [3] Fisher RV., Schmincke HU. (2012). Pyroclastic Rocks. Springer Science & Business Media, Germany.
  • [4] Spieler O., Kennedy B., Kueppers U., Dingwell DB., Scheu B., Taddeucci J. (2004). The Fragmentation Threshold of Pyroclastic Rocks. Earth and Planetary Science Letters, 226(1-2), 139-148.
  • [5] Simşek O., Erdal M. (2004) Investigation of Some Mechanical And Physical Properties of The Ahlat Stone (Ignimbrite), Gazi University Journal of Science, 17(4), 71-78.
  • [6] Erguvanlı K.(2004) Engineering Geology (4. Edition).Seç Publication Delivery, Turkey.
  • [7] Sedef G. (2017) The Effects of Using Natural Materials in Civil Architecture on Architecture and Sustainability: The Example of Ahlat Stone, PhD Thesis, Iller Bankasi A.S., Ankara, Turkey.
  • [8] Koralay T., Özkul M., Kumsar H., Çelik SB., Pektaş K. (2011). The Effect of Welding Degree on Geotechnical Properties of an Ignimbrite Flow Unit: the Bitlis Castle Case (Eastern Turkey). Environmental Earth Sciences, 64(3), 869-881.
  • [9] Pamuk E., Büyüksaraç A. (2017). Investigation of Strength Characteristics of Natural Stones in Ürgüp (Nevşehir/Turkey). Bitlis Eren University Journal of Science and Technology, 7(2), 74-79
  • [10] Işık E., Antep B., Karaşin İB. (2018). Structural Analysis of Ahlat Emir Bayındır Bridge. Bitlis Eren University Journal of Science and Technology, 8(1), 11-18.
  • [11] Bicer A. (2019). Thermal and Mechanical Properties of Ahlat – Malazgirt Building Blocks. Fırat University Journal of Engineering Sciences, 31(2), 301-307.
  • [12] Kazanci N., Gürbüz A. (2014). Natural Stones Qualified as Geological Heritage in Turkey. Geological Bulletin of Turkey, 57(1), 19-44.
  • [13] Wessel, P., & Smith, W. H. F. (1995). New version of the GenericMapping Tools. Eos Transactions, American Geophysical Union,76, 329.
  • [14] Özpeker L. (1973) Volcanological Investigation of Nemrut Volcano. Tübitak 4. Science Congress, Earth Sciences Section Papers Book, 1-17.
  • [15] Ercan T., Fujitani T., Madsuda JI., Notsu K., Jokel S., Ui T. (1990) Interpretation of New Geochemical, Radiometric and Isotopic Data on Eastern and Southeastern Anatolia Neogene-quaternary Volcanic. Mineral Research and Exploration Magazine, 110(110), 87.
  • [16] Sözeri TE. (2007). Investigation of Facies and Reservoir Properties of the Burdigalian Limestones around Muş (Eastern Anatolia Region). M.Sc. Thesis, Ankara University, Institute of Science, Ankara.
  • [17] Akay E. (1989). Evolution of the Kratonic Basins After the Collision in the Eastern Taurus Mountains. MTA Magazine.
  • [18] Senol M. (2002). The Origin and Sustainable Use of Unnatural Crops on Agricultural Lands Located in the Southern and Eastern Parts of Van Lake basin, YYÜ, Scientific Research Projects, FED-094, Van, Turkey.
  • [19] Özdemir Y., Karaoğlu Ö., Tolluoğlu AÜ., Güleç N. (2006). Volcano Stratigraphy and Petrogenesis of the Nemrut Stratovolcano (East Anatolian High Plateau): the Most Recent Post-collisional Volcanism in Turkey. Chemical Geology 226(3-4), 89-211.
  • [20] Karaoğlu Ö., Özdemir Y., Tolluoğlu AÜ., (2003).Nemrut Açılma Çatlağı'nın Etkinliğine ait Bulgular. ATAG-7 Aktif Tektonik Araştırma Grubu 7. Toplantısı Bildiri Özleri, Yüzüncü Yıl Üniversitesi Jeoloji Mühendisliği Bölümü, Van.
  • [21] Karaoğlu Ö., Özdemir Y., Tolluoğlu AÜ., Karabiyikoğlu M., Köse O., Froger JL. (2005). Stratigraphy of the Volcanic Products Around Nemrut Caldera: Implications for Reconstruction of the Caldera Formation. Turkish Journal of Earth Sciences, 14 (2), 123-143.
  • [22] Işık E., Antep B., Büyüksaraç A. (2019). Structural Analysis and Mapping of Historical Tombs in Ahlat District (Bitlis, Turkey). Electronic Journal of the Faculty of Civil Engineering Osijek-e-GFOS 18, 22-35.
  • [23] Isik E., Büyüksaraç A., Aydın MC., Ekinci YL. (2019). Comparison of Mechanical and Physical Properties of Nemrut Ingimbrites. International Engineering and Science Symposium, Siirt, Turkey.
  • [24] Isik E., Antep B., Karaşin İB., Öncü ME. (2019). Analysis of the Bezirhane Main Wall in the Ahlat District by Using the Finite Element Method. Dicle University Journal of Engineering, 10(2), 721-730.
  • [25] Isik E., Antep B., Buyuksarac A., Isık, MF. (2019). Observation of Behavior of the Ahlat Gravestones (Turkey) at Seismic Risk and Their Recognition by QR Code. Structural Engineering and Mechanics, 72(5), 643.
  • [26] Aygun Z., Aygun M. (2016). Spectroscopic Analysis of Ahlat Stone (Ignimbrite) and Pumice Formed by Volcanic activity, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 166, 73–78.
  • [27] Bakis A., Isik E , El AA., Ülker M. (2019). Mechanical Properties of Reactive Powder Concretes Produced Using Pumice Powder. Journal of Wuhan University of Technology-Mater. Sci. Ed. 34(2), 353-360.
  • [28] Karaman ME., Kibici Y. (2008). Basic Geological Principles, Belen Publishing and Printing, Ankara.
  • [29] Heibati B., Yetilmezsoy K., Zazouli MA., Rodriguez-Couto S., Tyagi I., Agarwal S., & Gupta VK. (2016). Adsorption of Ethidium Bromide (EtBr) from Aqueous Solutions by Natural Pumice and Aluminium-coated Pumice. Journal of Molecular Liquids, 213, 41-47.
  • [30] Elmastas N. (2012). A Mine Becoming Increasingly Important or Economy of Turkey: Pumice. The Journal of International Social Research, 5(23), 197-206.
  • [31] Wu NM. (2019). Biotoxicity Assessment of Incinerator Bottom Ash Leachates Using Daphnia Magna. Environment and Ecology Research. 7(3), 117-120.
  • [32] Lu CC., Hsu MH., Lina YP. (2019). Evaluation of Heavy Metal Leachability of Incinerating Recycled Aggregate and Solidification/stabilization Products for Construction Reuse Using TCLP, Multi-final pH and EDTA-mediated TCLP Leaching Tests. Journal of Hazardous Materials, 368, 336–344.
  • [33] Url, https://www.epa.gov/sites/production/files/2015-12/documents/1311.pdf (Accessed date: 20.01.2020).
  • [34] Bayraktar CA., Avşar E., Toröz İ., Alp K., Hanedar A. (2015). Stabilization and Solidification of Electric Arc Furnace Dust Originating from Steel Industry by Using Low Grade MgO. Archives of Environmental Protection, 41(4), 62–66.
  • [35] Url, https://eskisite.agri.edu.tr/tr/merkezler/merlab/kategori/icp-ms-aas (Accessed date: 20.01.2020).
  • [36] Url, EPA(1994). Determination of Trace Elements in Waters and Wastes by Inductively Coupled Plasma-Mass Spectrometry, https://www.epa.gov/sites/production/files/2015-08/documents/method_200-8_rev_5-4_1994.pdf, (Accessed date: 26.03.2019).
  • [37] Avsar E., Isik E. (2019). Investigation of The Usage of Bitlis Stone As A Building Material In Terms of Product Toxicity. Third International Mediterranean Congress on Natural Sciences, Health Sciences and Engineering (MENSEC III) University of Donja Gorica Podgorica, Montenegro June 18-20, 2019.
  • [38] Url, http://artmer.beun.edu.tr/x-isinlari-floresans-spektrometresi-xrf.html (Accessed date: 20.01.2020).
  • [39] Url, http://www.speciation.net/Database/Instruments/PANalytical-BV/Epsilon-5-;i1663 (Accessed date: 20.01.2020).
  • [40] Url, http://yebim.ankara.edu.tr/2013/04/25/x-isinlari-floresans-spektrometresi-xrf/ (Accessed date: 20.01.2020).
  • [41] Url5, http://emreyalamac.cbu.edu.tr/wp-content/uploads/2018/05/XRF.pdf (Accessed date: 20.01.2020).
  • [42] Kuluöztürk MF.,Büyüksaraç A., Özbey F., Yalçin S., Doğru M. (2019). Determination of Indoor Radon Gas Levels in Some Buildings Constructed with Ahlat Stone in Ahlat/Bitlis. International Journal of Environmental Science and Technology. 16, 5033–5038.