Şeker Kısımları ile Graftlanmış olan Polimetilsiloksan Bazlı Polimerik Yüzey Aktif Madde Sentezi

İlk olarak, platin katalizörü varlığında hidrosililasyon reaksiyonuna girebilen enofuranoz türevi 1 hazırlandı. Sentezlenen enofuranoz türevinin allil grubunun çifte bağından silikon oligomerine bağlanması gerçekleştirildi. Polimerik yüzey aktif madde 2 şeker kısımları ile graftlanmış olan bir polimetilsilikon bazlı malzeme kullanılarak hazırlandı. Sentezlenen 1 ve 2 nolu bileşiklerin yapıları, Nükleer Manyetik Rezonans NMR ve FITR spektroskopisi ile aydınlatıldı

Anahtar Kelimeler:

Yüzey Aktif Madde, Biyolojik Yüzey Aktif Maddeler, Polimetilsiloksan, Şeker Bazlı Yüzey Aktif Maddeler

Sythesis of Polymeric Surfactant with Polymethylsilicone Backbone which is Grafted with A Sugar

The enofuranose derivative 1 was synthesised which was thought to be suitable for reaction with polymethylhydrogensiloxane, by hydrosilylation reaction in the presence of a platinum catalyst. Allyl group was introduced to the protected sugar derivative, which were further used for bonding these molecule to silicone oligomer through double bond addition. The polymeric surfactant 2 has been prepared using a polymethylsilicon backbone which was grafted with a glucose moiety. The synthesized compounds 1 and 2 were characterized by nuclear magnetic resonance NMR and Fourier transforminfrared spectroscopy FTIR .

Keywords:

Surfactants, Biosurfactants, Polymethylsilicon, Sugar based surface active agents,

PDF

___

Abert, M., Mora, N., Lacombe, J.M. 2002. Synthesis and surface-active properties of a new class of surfactants derived from D-gluconic acid. Carbohyd Res, 337: 997-1006.
Andersson, KN., Sauer, S., Panknin, O., Söderlind, E., Somfai, P.2006. Sythesis of New Sugar-Based Surfactants and Evaluation of Their Hemolytic Activities. J. Org. Chem., 71: 3623-3626.
Bauer, J., Hüsing, N., Kickelbick, G. 2001.Synthesis of new types of polysiloxane basedsurfactants, Chem Commun. 1:137-138.
Bazito, RC., El Seoud, OA.2001. Sugar-based anionic surfactants: sythesis and miccelle formation of sodium methyl 2-acylamido-2-deoxy-6-O-sulfo-D-glucopyranosides, Carbohyd Res, 332: 95-102.
Boehm, P., Mondeshki, M., Frey, H. 2012. Polysiloxane- Backbone Block Copolymers in a One-Pot Synthesis: A Silicone Platform for Facile Functionalization. Macromol Rapid Comm, 33: 1861-1867.
Han, F., Deng, Y., Zhou, Y., Xu, B. 2012. Carbohydrate- Modified Silicone Surfactants. J Surfact Deterg, 15:123-129.
Hill, RM. 1999. Silicone Surfactants, Surfactant Science Series, 86. Marcel Dekker, New York, 2-4 pp.
Hill, K., Le Hen-Ferrenbach, C. 2009. Sugar-based surfactants for consumer products and technical applications. Surfactant Sci. Ser.,143: 1–20.
Lewis, LN., Stein, J., Gao, Y., Colborn, RE., Hutchins, G. 1991. Platinum Catalysts Used in the Silicones Industry. Platinum Metals Rev, 41: 66-75.
attributed to Si–C groups and Si–O–Si groups, respectively. It was also seen that allyl (C=C) peak at 1647 cm-1 was lost (Zeng et al. 2015).
Retailleau, L., Laplace, A., Fensterbank, H., Larpent, C. 1998. Synthesis, Structural Analysis and properties of N-Alkylglucosyl(meth)acrylamides: New Reactive Augar Surfactants. J.Org.Chem., 63: 608-617.
Sejpka, J., Wimner, F. 1994.Proses for Peraparing Organosilicon Compounds Containing Glycoside Radicals. European Patent, 0612759 to Wacker Chemie GmbH, Germany, 1-10 pp.
Shing, TKM., Leung, GYC. 2002. Asymetric epoxidation catalyzed by D-glucose-derived uloses. Tetrahedron, 58: 7545- 7552.
Tadros, TF. 2005. Aplied Surfactants: Principles and Aplication,WILEY-VCH Verlag GmbH & Co. KGaA, Weinhe- im, 1-16 pp.
Telli, FÇ.2015.Syntheses and Characterization of New 3-O-Allyl Ether Chloralose Derivatives. Asian J. Chem., 27: 353-356.
Zeng, X., Wang, H., Chen, Y., Wang, L. 2015. Synthesis and Solution Properties of Carbohydrate-Modified Polysiloxane Bola Surfactants. J Surfact Deterg, 18: 1089–1094.
Reinsborough, VC., Stephenson, VC. 2004. Inclusion comple- xation involving sugar-containing species: β-cyclodextrin and sugar surfactants. Can J. Chem., 82: 45-49.