Hydrothermal Synthesis, Crystal Structures and Properties of 1D Coordination Polymers Based on 5-Nitroisophthalic Acid and 1-Methylimidazole Linkers

Two new coordination polymers, namely [Mn(µ3-5-nip)(1-meim)2(H2O)]n (1) and {[Co(µ-5-nip)(1-meim)3]∙H2O}n (2) (5-nip: 5-nitroisophthalate, 1-meim: 1-methylimidazole), were hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, single crystal diffraction and simultaneous thermal analysis techniques. The 5-nip ligand exhibited two different coordination modes in its structures. In 1 and 2, 1D chains were generated by 5-nip ligands and metal (II) ions. In 1 and 2, 5-nip ligand coordinated to three Mn(II) and two Co(II) ions as bis(monodentate) bridging mode and a monodentate and bidentate chelating modes, respectively. For 1 and 2, 2D supramolecular layers were formed by hydrogen bonds which were extend into 3D supramolecular structures via π···π interactions between two symmetry–related imidazole rings of neighboring molecules. Furthermore, optical and thermal properties of the complexes were also studied.

Keywords:

5-nitroisophthalate, coordination polymer optical properties,

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1. He Y, Zhou W, Qian G, Chen B. Methane storage in metal–organic frameworks. Chemical Society Reviews. 2014;43(16):5657-78.
2. Noro S-i, Ochi R, Inubushi Y, Kubo K, Nakamura T. CH4/CO2 and CH4/C2H6 gas separation using a flexible one-dimensional copper (II) porous coordination polymer. Microporous and Mesoporous Materials. 2015;216:92-6.
3. Gu J-Z, Liang X-X, Cui Y-H, Wu J, Shi Z-F, Kirillov AM. Introducing 2-(2-carboxyphenoxy) terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism. CrystEngComm. 2017;19(18):2570-88.
4. Arici M, Yeşilel OZ, Taş M, Demiral H. CO2 and iodine uptake properties of Co (II)-coordination polymer constructed from tetracarboxylic acid and flexible bis (imidazole) linker. Crystal Growth & Design. 2017;17(5):2654-9.
5. Arıcı M, Yeşilel OZ, Büyükgüngör O. Four coordination polymers based on 5-tert-butyl isophthalic acid and rigid bis (imidazol-1yl) benzene linkers: Synthesis, luminescence detection of acetone and optical properties. Journal of Solid State Chemistry. 2017;249:141-8.
6. Wezendonk TA, Santos VP, Nasalevich MA, Warringa QS, Dugulan AI, Chojecki A, et al. Elucidating the Nature of Fe Species during Pyrolysis of the Fe-BTC MOF into Highly Active and Stable Fischer–Tropsch Catalysts. ACS Catalysis. 2016;6(5):3236-47.
7. Zhu X, Sun P-P, Ding J-G, Li B-L, Li H-Y. Tuning cobalt coordination architectures by bis (1, 2, 4-triazol-1-ylmethyl) benzene position isomers and 5-nitroisophthalate. Crystal Growth & Design. 2012;12(8):3992-7.
8. Guo F, Zhu B, Xu G, Zhang M, Zhang X, Zhang J. Tuning structural topologies of five photoluminescent Cd (II) coordination polymers through modifying the substitute group of organic ligand. Journal of Solid State Chemistry. 2013;199:42-8.
9. Zhao F-H, Che Y-X, Zheng J-M. Syntheses, structures and magnetic properties of two new complexes constructed from mixed rigid ligands. Inorganic Chemistry Communications. 2012;16:55-60.
10. Lin J-D, Lin M-Z, Tian C-B, Lin P, Du S-W. Syntheses, topological structures and physical properties of two 2D lanthanide–organic frameworks constructed from 5-nitroisophthalic acid. Journal of Molecular Structure. 2009;938(1):111-6.
11. Huang Y, Yan B, Shao M. Synthesis, crystal structure and photoluminescent properties of four lanthanide 5-nitroisophthalate coordination polymers. Journal of solid state chemistry. 2009;182(4):657-68.
12. Ye J, Wang J, Wu Y, Ye L, Zhang P. Supramolecular coordination networks constructed from infinite one-dimensional chains with 5-nitroisophthalate as bridge. Journal of Molecular Structure. 2008;873(1):35-40.
13. Wang X-L, Xia Z-Q, Wei W, Xie G, Chen S-P, Gao S-L. Synthesis, structure, and thermodynamics of a lanthanide coordination compound incorporating 5-nitroisophthalic acid. The Journal of Chemical Thermodynamics. 2012;55:124-9.
14. Chen Q, Zhu X, Ding J-G, Li B-L, Li H-Y. Syntheses, structures and properties of three cobalt coordination polymers based on flexible bis (triazole) and 5-nitroisophthalate coligands. Journal of Molecular Structure. 2013;1038:194-9.
15. Semerci F. Syntheses and photoluminescence properties of new Zn (II) and Cd (II) coordination polymers prepared from 5-sulfoisophthalate ligand. Turkish Journal of Chemistry. 2017;41(2):243-55.
16. López R, Gómez R. Band-gap energy estimation from diffuse reflectance measurements on sol–gel and commercial TiO2: a comparative study. Journal of Sol-Gel Science and Technology. 2012;61(1):1-7.
17. Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JA, Puschmann H. OLEX2: a complete structure solution, refinement and analysis program. Journal of Applied Crystallography. 2009;42(2):339-41.
18. Macrae CF, Edgington PR, McCabe P, Pidcock E, Shields GP, Taylor R, et al. Mercury: visualization and analysis of crystal structures. Journal of Applied Crystallography. 2006;39(3):453-7.

Journal of the Turkish Chemical Society Section A: Chemistry-Cover

Başlangıç: 2014
Yayıncı: Türkiye Kimya Derneği

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