Biodiesel Production from Waste Frying Oil using Catalysts Derived from Waste Materials

Domestic resources such as vegetable oil, animal fats, tallows, and waste frying oil are common raw materials for making biodiesel. In contrast to ordinary diesel, biodiesel helps to reduce CO2 emissions. This study aimed to produce biodiesel using waste frying oil in the presence of suitable solid waste-derived heterogeneous catalysts. Firstly, CaO/K2O catalyst was synthesised using eggshells and banana peels. Then, the pre-prepared catalyst (CaO/K2O) modified with ZnO was utilized for biodiesel production. The prepared catalyst and biodiesel were characterized using X-ray diffraction (XRD) and FTIR spectroscopy. The AOAC and ASTM standard methods were employed to analyze the physicochemical properties of oils and biodiesel. The catalytic efficiency of CaO/K2O and CaO/K2O-ZnO tested for the transesterification of purified oil to biodiesel at the catalyst weight (1-7 %wt), temperature (60-80°C), and methanol to oil ratios ranging from 3:1 to 12:1. The highest biodiesel yield (92%) obtained when 5 %wt CaO/K2O catalyst used. However, a 95% yield resulted when using a 3 %wt CaO/K2O-ZnO catalyst load in 2 h with a methanol to oil (v/v) ratio of 9:1 at 65°C. The study revealed that waste frying oil is a good source of biodiesel which could replace nonrenewable energy in the future. The catalysts made from solid waste could also replace an expensive chemical catalyst.

Keywords:

Biodiesel;, frying oils CaO/K2O-ZnO catalyst;, Transesterification,

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1. Faruque MO, Razzak SA, Hossain MM. Application of Heterogeneous Catalysts for Biodiesel Production from Microalgal Oil—A Review. Catalysts [Internet]. 2020 Sep 7 [cited 2022 Jun 16];10(9):1025.
2. Azócar L, Ciudad G, Heipieper HJ, Navia R. Biotechnological processes for biodiesel production using alternative oils. Appl Microbiol Biotechnol [Internet]. 2010 Oct [cited 2022 Jun 16];88(3):621–36.
3. El Sherbiny SA, Refaat AA, El Sheltawy ST. Production of biodiesel using the microwave technique. Journal of Advanced Research [Internet]. 2010 Oct [cited 2022 Jun 16];1(4):309–14.
4. Lani N.S., Ngadi N., Taib M.R. Parametric study on the transesterification reaction by using cao/silica catalyst. Chemical Engineering Transactions [Internet]. 2017 Apr [cited 2022 Jun 16];56:601–6.
5. Win TT, Khine MM. Synthesis and Characterization of CaO and KF Doped CaO (KF/CaO) Derived from Chicken Eggshell Waste as Heterogeneous Catalyst in Biodiesel Production. ASRJETS [Internet]. 2017;38(2):134–51.
6. Kalligeros S, Zannikos F, Stournas S, Lois E, Anastopoulos G, Teas C, et al. An investigation of using biodiesel/marine diesel blends on the performance of a stationary diesel engine. Biomass and Bioenergy [Internet]. 2003 Feb [cited 2022 Jun 16];24(2):141–9.
7. Thangaraj B, Solomon PR, Muniyandi B, Ranganathan S, Lin L. Catalysis in biodiesel production—a review. Clean Energy [Internet]. 2019 Feb 27 [cited 2022 Jun 16];3(1):2–23.
8. Changmai B, Vanlalveni C, Ingle AP, Bhagat R, Rokhum SL. Widely used catalysts in biodiesel production: a review. RSC Adv [Internet]. 2020 [cited 2022 Jun 16];10(68):41625–79.
9. Lee AF, Bennett JA, Manayil JC, Wilson K. Heterogeneous catalysis for sustainable biodiesel production via esterification and transesterification. Chem Soc Rev [Internet]. 2014 [cited 2022 Jun 16];43(22):7887–916.
10. Navas MB, Ruggera JF, Lick ID, Casella ML. A sustainable process for biodiesel production using Zn/Mg oxidic species as active, selective and reusable heterogeneous catalysts. Bioresour Bioprocess. 2020;7:4.
11. Demirbas A, Bafail A, Ahmad W, Sheikh M. Biodiesel production from non-edible plant oils. Energy Exploration & Exploitation [Internet]. 2016 Mar [cited 2022 Jun 16];34(2):290–318.
12. Bach U, Lupo D, Comte P, Moser JE, Weissörtel F, Salbeck J, et al. Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies. Nature [Internet]. 1998 Oct [cited 2022 Jun 16];395(6702):583–5.
13. Li Y, Jiang Y. Preparation of a palygorskite supported KF/CaO catalyst and its application for biodiesel production via transesterification. RSC Adv [Internet]. 2018 [cited 2022 Jun 16];8(29):16013–8.
14. Sivasamy A, Cheah KY, Fornasiero P, Kemausuor F, Zinoviev S, Miertus S. Catalytic Applications in the Production of Biodiesel from Vegetable Oils. ChemSusChem [Internet]. 2009 Apr 20 [cited 2022 Jun 16];2(4):278–300.
15. Birla A, Singh B, Upadhyay SN, Sharma YC. Kinetics studies of synthesis of biodiesel from waste frying oil using a heterogeneous catalyst derived from snail shell. Bioresource Technology [Internet]. 2012 Feb [cited 2022 Jun 16];106:95–100.
16. Ismail SA, Ali RFM. Physico-chemical properties of biodiesel manufactured from waste frying oil using domestic adsorbents. Science and Technology of Advanced Materials [Internet]. 2015 Jun 20 [cited 2022 Jun 16];16(3):034602.
17. Mansir N, Hwa Teo S, Lokman Ibrahim M, Yun Hin TY. Synthesis and application of waste egg shell derived CaO supported W-Mo mixed oxide catalysts for FAME production from waste cooking oil: Effect of stoichiometry. Energy Conversion and Management [Internet]. 2017 Nov [cited 2022 Jun 16];151:216–26.
18. Khan HM, Iqbal T, Ali CH, Yasin S, Jamil F. Waste quail beaks as renewable source for synthesizing novel catalysts for biodiesel production. Renewable Energy [Internet]. 2020 Jul [cited 2022 Jun 16];154:1035–43.
19. Efavi JK, Kanbogtah D, Apalangya V, Nyankson E, Tiburu EK, Dodoo-Arhin D, et al. The effect of NaOH catalyst concentration and extraction time on the yield and properties of Citrullus vulgaris seed oil as a potential biodiesel feed stock. South African Journal of Chemical Engineering [Internet]. 2018 Jun [cited 2022 Jun 16];25:98–102.
20. David F, Matton P. AOAC official methods of Oils and Fats. In: Nutrition & Food Science. 2011. p. 38–43.
21. Sahasrabudhe SN, Rodriguez-Martinez V, O’Meara Meghan, Farkas BE. Density, viscosity, and surface tension of five vegetable oils at elevated temperatures: Measurement and modeling. International Journal of Food Properties [Internet]. 2017 Dec 29 [cited 2022 Jun 16];1–17.
22. Gunstone FD, editor. Vegetable oils in food technology: composition, properties and uses. 2. ed. Oxford: Wiley-Blackwell; 2011. 353 p.
23. Amsalu H, Wondimnew T, Mateos T, Fekadie M, Bogale G. The Effect of Palm Oil-Fried Street Kokor on Liver and Kidney Biomarkers of Swiss Albino Mice. Wertz PW, editor. Journal of Lipids [Internet]. 2020 Dec 4 [cited 2022 Jun 16];2020:1–5.
24. Gnanaprakasam A, Sivakumar VM, Surendhar A, Thirumarimurugan M, Kannadasan T. Recent Strategy of Biodiesel Production from Waste Cooking Oil and Process Influencing Parameters: A Review. Journal of Energy [Internet]. 2013 [cited 2022 Jun 16];2013:1–10.
25. Saeed M, Shola E. Extraction and physico chemical properties of some edible seed oils sampled in Kano metropolis, Kano state. Bayero J Pure App Sci [Internet]. 2016 Jun 2 [cited 2022 Jun 16];8(2):239.
26. Zuleta EC, Baena L, Rios LA, Calderón JA. The oxidative stability of biodiesel and its impact on the deterioration of metallic and polymeric materials: a review. J Braz Chem Soc [Internet]. 2012 Dec [cited 2022 Jun 16];23(12):2159–75.
27. Madhuvilakku R, Piraman S. Biodiesel synthesis by TiO2–ZnO mixed oxide nanocatalyst catalyzed palm oil transesterification process. Bioresource Technology [Internet]. 2013 Dec [cited 2022 Jun 16];150:55–9.
28. Refaat AA. Biodiesel production using solid metal oxide catalysts. Int J Environ Sci Technol [Internet]. 2011 Dec [cited 2022 Jun 16];8(1):203–21.
29. Hamester MRR, Balzer PS, Becker D. Characterization of calcium carbonate obtained from oyster and mussel shells and incorporation in polypropylene. Mat Res [Internet]. 2012 Feb 14 [cited 2022 Jun 16];15(2):204–8.
30. Navas MB, Ruggera JF, Lick ID, Casella ML. A sustainable process for biodiesel production using Zn/Mg oxidic species as active, selective and reusable heterogeneous catalysts. Bioresour Bioprocess [Internet]. 2020 Dec [cited 2022 Jun 16];7(1):4.
31. Patel A, Arora N, Sartaj K, Pruthi V, Pruthi PA. Sustainable biodiesel production from oleaginous yeasts utilizing hydrolysates of various non-edible lignocellulosic biomasses. Renewable and Sustainable Energy Reviews [Internet]. 2016 Sep [cited 2022 Jun 16];62:836–55.
32. Che Hamzah NH, Khairuddin N, Siddique BM, Hassan MA. Potential of Jatropha curcas L. as Biodiesel Feedstock in Malaysia: A Concise Review. Processes [Internet]. 2020 Jul 6 [cited 2022 Jun 16];8(7):786.
33. Atabani AE, Silitonga AS, Badruddin IA, Mahlia TMI, Masjuki HH, Mekhilef S. A comprehensive review on biodiesel as an alternative energy resource and its characteristics. Renewable and Sustainable Energy Reviews [Internet]. 2012 May [cited 2022 Jun 16];16(4):2070–93.
34. Ogunkunle O, Ahmed NA. Overview of Biodiesel Combustion in Mitigating the Adverse Impacts of Engine Emissions on the Sustainable Human–Environment Scenario. Sustainability [Internet]. 2021 May 13 [cited 2022 Jun 16];13(10):5465.
35. Banerjee S, Kumar S, Mandal A, Naiya TK. Design of novel chemical solvent for treatment of waxy crude. International Journal of Oil, Gas and Coal Technology. 2017;15(4):363–79.
36. Schönemann A, Edwards HGM. Raman and FTIR microspectroscopic study of the alteration of Chinese tung oil and related drying oils during ageing. Anal Bioanal Chem [Internet]. 2011 May [cited 2022 Jun 16];400(4):1173–80.
37. Istadi I, Mabruro U, Kalimantini BA, Buchori L, Anggoro DD. Reusability and Stability Tests of Calcium Oxide Based Catalyst (K2O/CaO-ZnO) for Transesterification of Soybean Oil to Biodiesel. Bull Chem React Eng Catal [Internet]. 2016 Mar 10 [cited 2022 Jun 16];11(1):34.
38. Taufiq-Yap YH, Lee HV, Hussein MZ, Yunus R. Calcium-based mixed oxide catalysts for methanolysis of Jatropha curcas oil to biodiesel. Biomass and Bioenergy [Internet]. 2011 Feb [cited 2022 Jun 16];35(2):827–34.
39. Navas MB, Ruggera JF, Lick ID, Casella ML. A sustainable process for biodiesel production using Zn/Mg oxidic species as active, selective and reusable heterogeneous catalysts. Bioresour Bioprocess [Internet]. 2020 Dec [cited 2022 Jul 19];7(1):4.

Journal of the Turkish Chemical Society Section A: Chemistry-Cover

Başlangıç: 2014
Yayıncı: Türkiye Kimya Derneği

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