Levels of Organchlorinated Pesticides and PCB in OliveOil of Vlora Region, Albania

Levels of Organchlorinated Pesticides and PCB in OliveOil of Vlora Region, Albania

In this study were evaluated levels of organochlorinated pesticides and polychlorinated biphenyls in extra virgin olive oil samples from Vlora region (South Albania), in January 2015. Vlora region is known for olive oil production. Organoclorinated pesticides are used wide for agricultural purposes until 90’ in Albania. PCBs were used in Albania as electric transformer oil after 90’ therefore these compound were reported in many areas because of their atmospheric deposition. In general these pollutants are stable compounds, lipophilic, withtoxic properties. Ultrasonic bath extraction assisted with n-Hexane as organic solvent and two clean-up steps have been used for analytical treatment of olive oil samples. The quantitative analysis of organochlorinateds pesticides and PCBs were performed by the gas chromatography method with electron capture detector. The profiles of detected pesticides were: Endosulphanes > HCHs > Aldrines Mirex > Methoxychlor > DDTs. PCB 28, the volatile PCB marker was the main congener for all analyzed samples.  The levels of contaminants observed for the olive oil samples could be because of their before use for agricultural purposes, oil production proces, atmospheric deposition for Vlora region. 

___

Erickson MD, (2001) Introduction: PCB properties, uses, occurrence, and regulatory history. In: Robertson LW, Hansen LG, (Eds.), PCBs: Recent Advances in Environmental Toxicology and Health Effects. The University Press of Kentucky, Lexington, Kentucky, pp. 131–152.

EN 1528-1. (2000) Part 1: Fatty Food-Determination of Pesticides and polychlorinated biphenyls [PCBs]

EN 1528-2 (2000) Part 2: Extraction of fat, Pesticides and polychlorinated biphenyls [PCBs and -Determination of Fat Content

EN 1528-3 (2000) Part 3: Clean-up methods

EN 1528-4 (2000) Part 4: Determination, Confirmatory tests, miscellaneous

Harwood J. L., Aparicio R. (2000) Handbook of olive oil: Analysis and properties. Aspen Publishers: Gaitherburg, MD Kalantzi, O.I., Thomas, G.O., Alcock, R.E., Stephenson, A. & Jones, K.C. (2000) A global survey of PCBs and organochlorine pesticides in butter. Organohalogen Compounds 47: 357-360

Kapaj AM, Kapaj I, (2012) Olive Oil Sector in Albania and Its Perspective, Olive Oil - Constituents, Quality, Health Properties and Bioconversions, Dr. Dimitrios Boskou (Ed.), InTech,

Kiritsakis AK, Lenert EB, Willet WC, Hernandez RJ, (1998) Olive oil: From tree to table. Trumbull, CT: Food and Nutrition Press, Inc, 2nd edition

Lazaro R, Herrera A, Arino A, Pilar Conchello M, Bayrri S, (1996) Organochlorine pesticide residues in total diet samples from Aragon (Northeastern Spain). J. Agric. Food Chem. 44, 2742-2747.

Nuro A, Koci K, Marku E, (2007) Occurrence of Persistent Chlorinated Contaminants using Butter as an Integrative Matrix., J. Environ. Protect. Eco. 8, 544-555.

Safe S, (1994) Polychlorinated biphenyls (PCBs): environmental impact, biochemical and toxic responses, and implications for risk assessment. Crit. Rev. Toxicol. 24, 87–149.

Santillo D, Stringer RL, Johnston PA, (2004) The global distribution of PCBs, organochlorine pesticides, PCDDs and PCDFs using butter as an integrative matrix. Chemosphere. 40, 1033-1040

Smartt J, Simmonds N, (1995) Evolution of Crop Plants. Wiley-Blackwell: 2 edition, pp. 496-500.

Vossen PM, Devarenne KA, (2011) California Agriculture, 65, 34-40.