The Importance of Corrosion Protection of Metal-Containing Historical Artifacts and Common Methods Used for Preservation

The Importance of Corrosion Protection of Metal-Containing Historical Artifacts and Common Methods Used for Preservation

Metal objects were used for various purposes like in the production, decoration, and painting of metallic coins, kitchenwares, and as structural components from ancient ages to the present. Metal extraction and processing ability became one of the important factors to determine the development level of society. For this reason, repairing and protecting the ancient artifacts buried underground or in an aqueous environment that recovered from the archaeological excavations and historical sites is extremely important to protect the history and cultural heritage of society. Historical artifacts are very fragile against environmental factors after their removal from the dig sites and thus rapid intervention procedures are required. Furthermore, historical artifacts exhibited without an application of a protective coating can easily corrode at an increased rate against atmospheric conditions over time. Therefore, developing new approaches for the preservation of metallic objects of cultural heritage has significant importance. It is necessary to know the type of metal to be processed as the coating to be developed for protection will be determined according to the type of metal. Primarily, metal surfaces must be cleansed from the corroded layer followed by developing and applying a structure able to isolate the metal from the environment in order to prevent corrosion. Various materials such as waxes, oils and greases, polymers, glasses and glassy enamels, metallic, and organic coatings have been used to develop corrosion-resistant coatings. Soluble corrosion inhibitors have also been used, which can promote the spontaneous formation of a protective barrier film on surfaces. The structures to be used in the protection of the ancient artifacts must have specific features: • must not cause a change in color and has to preserve authenticity in visual appearance, • easy to apply, • low cost, • reversibility in some cases, i.e. easy to remove from the surface, • environmentally friendly, non-toxic. In this review, the methods commonly used for the protection of archaeological artifacts are examined and their advantages and disadvantages are stated.

___

  • Abrantes, L. M., Melato, A. I. 2013. Corrosion and Conservation of Cultural Heritage Metallic Artefacts. European Federation of Corrosion (EFC) Series. Pages 518-539. University of Lisbon, Portugal.
  • Barouni, K., Kassale, A., Albourine, A., Jbara, O., Hammouti, B., Bazzi, L., 2014. Amino acids as corrosion inhibitors for copper in nitric acid medium: Experimental and theoretical study. J. Mater. Environ. Sci., 5(2), 456-463.
  • Behpour, M., Ghoreishi, S.M., Khayatkashani, M., Soltani, N., 2012. Green approach to corrosion inhibition of mild steel in two acidic solutions by the extract of Punica granatum peel and main constituents. Materials Chemistry and Physics, 131(3), 621-633. DOI, 10.1016/j.matchemphys.2011.10.027
  • Black, L. and Allen, G.C. 1999. “Nature of lead patination” Brit. Corros. J., 34(3), 192-197. DOI, 10.1179/000705999101500833 Christofer, L.; Odnevall, W.I.; Johan, T,; Thomas, G. 2016. Atmospherıc Gases And Theır Involvement In Corrosıon. Atmospheric Corrosion (2nd ed.), 34-45. Wiley. DOI, 10.1002/9781118762134.ch4
  • Davison, S. 1984. “A review of adhesives and consolidants used on glass antiquities.” Stud. Conserv. 29(sup1), 191–194. doı,10.1179/sic.1984.29.supplement-1.191
  • Favre-quattropani, L., Groening, P., Ramseyer, D., Schlapbach, L. 2000. The protection of metallic archaeological objects using plasma polymer coatings. Surf. Coat. Technol. 125(1-3), 377–382. DOI, 10.1016/s0257-8972(99)00579-4
  • Feller, R. L., Stolow and N. Jones, E. H. 1972. On Picture Varnishes and their Solvents, Case Western Reserve University, Cleveland. Figueira, R. B., Silva, C. J. R., Pereira, E. V., 2014. Organic–inorganic hybrid sol–gel coatings for metal corrosion protection: a review of recent progress. J. Coat. Technol. Res., 12(1), 1–35. DOI,10.1007/s11998-014-9595-6
  • Finšgar, M., Milošev, I., 2010. Inhibition of copper corrosion by 1, 2, 3-benzotriazole: a review. Corrosion science, 52(9), 2737-2749. DOI, 10.1016/j.corsci.2010.05.002
  • Hollander, O., May, R.C., 1985. The chemistry of azole copper corrosion inhibitors in cooling waters. Corrosion, 41(1), 39-45. DOI, 10.5006/1.3581967
  • Khan, P.F., Shanthi, V., Babu, R.K., Muralidharan, S., Barik, R.C., 2015. Effect of benzotriazole on corrosion inhibition of copper under flow conditions. Journal of Environmental Chemical Engineering, 3(1), 10-19. DOI, 10.1016/j.jece.2014.11.005
  • Kolasinski, K. W. 2012. Surface and Adsorbate Structure. Surface Science: Foundations of Catalysis and Nanoscience. John Wiley & Sons, New York, John Wiley and Sons. DOI,10.1002/9781119941798.ch1
  • Koob, P. Stephen, “Paraloid B-72®: 25 years of use as a consolidant and adhesive for ceramics and glass”, Holding It All Together: Ancient and Modern Approaches to Joining, Repair and Consolidation, (Ed. J. Ambers, C. Higgitt, L. Harrison, and D. Saunders), Londra, 2009, 113-119.
  • Lyklema, J. 2001. Fundamentals of Interface and Colloid Science (vol. I). New York, Academic Press.
  • Makarenko, N., Kharchenko, U., Zemnukhova, L., 2011. Effect of amino acids on corrosion of copper and steel in acid medium. Russian Journal of Applied Chemistry 84(8), 1362-1365. DOI, 10.1134/s1070427211080118
  • Moffett, D. L. 1996. Wax Coatıngs On Ethnographıc Metal Objects: Justıfıcatıons For Allowıng A Tradıtıon To Wane. Journal of the American Institute for Conservation, 35(1), 1-7. DOI, 10.1179/019713696806124557
  • Molina, G., Odin, G. P., Pradell, T., Shortland, A. J., & Tite, M. S. (2014). Production technology and replication of lead antimonate yellow glass from New Kingdom Egypt and the Roman Empire. Journal of Archaeological Science, 41, 171–184. DOI,10.1016/j.jas.2013.07.030
  • Moretti, G., Guidi, F., 2002. Tryptophan as copper corrosion inhibitor in 0.5 M aerated sulfuric acid. Corrosion science, 44(9), 1995-2011. DOI, 10.1016/s0010-938x(02)00020-3
  • Radivojević, M.; Rehren, T.; Farid, S.; Pernicka, E.; Camurcuoğlu, D. (2017). Repealing the Çatalhöyük extractive metallurgy: The green, the fire and the “slag.” Journal of Archaeological Science, 86, 101-122. DOI, 10.1016/j.jas.2017.07.001
  • Robbiola, L.; Blengino, J.M.; Fiaud, C. 1998. Morphology and mechanisms of formation of natural patinas on archaeological Cu-Sn alloys. Corros. Sci., 40(12), 2083–2111. DOI, 10.1016/s0010-938x(98)00096-1
  • Scott, David A. (1990). Bronze Disease: A Review of Some Chemical Problems and the Role of Relative Humidity. Journal of the American Institute for Conservation. 29(2), 193-206. DOI, 10.1179/019713690806046064
  • Stupnišek-Lisac, E., Bozic, A.L., Cafuk, I., 1998. Low-toxicity copper corrosion inhibitors. Corrosion, 54(9), 713-720. DOI, 10.5006/1.3284890
  • Terpstra, T. (2019). Roman Technological Progress in Comparative Context: The Roman Empire, Medieval Europe and Imperial China. Explorations in Economic History, 101300. DOI,10.1016/j.eeh.2019.101300
  • Tromans, D., Sun, R.h., (1991). Anodic polarization behavior of copper in aqueous chloride/benzotriazole solutions. Journal of the Electrochemical Society, 138(11), 3235-3244. DOI, 10.1149/1.2085397
  • Winther, T. Bannerman, J., Skogstad, H., Johansson, M. K. G., Jacobson, K. and Samuelsson, J. (2015). Adhesives for adhering polystyrene plastic and their long-term effect. Studies in Conservation, 60(2):107-120. DOI, 10.1179/2047058413Y.0000000105
  • Wilson, H. and Erbe, A. (2019). Convection induced by illumination-based metal surface heating increases corrosion potential, corrosion rates. Electrochemistry Communications, 106,106513. DOI: 10.1016/j.elecom.2019.106513
  • Yang, B; Johnson, D A; Shim, S H. (1993). Effect of ozone on corrosion of metals used in cooling towers. Corrosion, 49(6): 499-513. DOI, 10.5006/1.3316079
  • Zhang, D.Q., Gao, L.X., Cai, Q.R., Lee, K., (2010). Inhibition of copper corrosion by modifying cysteine self-assembled film with alkylamine/alkylacid compounds. Materials and corrosion, 61, 16-21. DOI, 10.1002/maco.200905225