Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu

[Cu(Hydet-en)2].(Tpht) (Tpht=Tereftalik asit dianyonu, Hydet-en=N-(2-hidroksietil)etilendiamin) kompleksi sentezlenmiştir. Kompleks tek kristal X-ışını tayini, FT-IR spektroskopisi, UV-Vis spektroskopisi, termogravimetrik analiz ve elementel analiz ile karakterize edilir. Her bir hydet-en ligandı bakır metaline iki dişli olarak koordine olurken, tpht2- anyonu ise birim hücrede serbest olarak bulunmaktadır. Bakır merkezi düzgün bir kare düzlem geometriye sahiptir. Kare düzlem geometriye sahip kompleksin ekvatoral düzlemini hydet-en ligantlarının birincil ve ikincil amin grupları oluşturmaktadır. Monomerler O-H∙∙∙O ve N-H∙∙∙O hidrojen bağlarıyla bağlanarak supramoleküler yapıyı oluşturur. Kompleksin FT-IR araştırması, orta IR bölgesi içinde gerçekleştirildi. Esas olarak tereftalik asit ve N-(2-hidroksietil)etilendiamin) ligantlarının karakteristik titreşimleri göz önünde bulundurarak kompleksin titreşimlerine odaklanıldı. TG, DTA ve DTG teknikleri kullanılarak kompleksin termal davranışları izlenmiştir.

Synthesis, Spectral, Thermal and Structural Characterization of Mixed ligand Copper(II) Complex Containing [N-(2-Hydroxyethyl)-Ethylenediamine] with Terephthalate

The complex [Cu(hydet-en)2].(tpht) synthesized is characterized by single crystal X-ray determination, FT-IR spectroscopy, UV-Vis spectroscopy, thermogravimetric analysis and elemental analysis (tpht=dianion of terephthalic acid, hydet-en=N-(2- hydroxyethyl)ethylenediamine). While each hydet-en ligand coordinates to copper metal as bidentate, the tpht2-anion is freely available in the unit cell. Copper center has a square plane geometry. In the square geometry, the equatorial plane of the complex is composed of primary and secondary amine groups of hydet-en ligands. Monomers are bonded with O-H∙∙∙O and N-H∙∙∙O hydrogen bonds to form a supramolecular structure. FT-IR investigation of the complex was performed in the middle IR region. The vibrations of the complex were focused mainly considering the characteristic vibrations of terephthalic acid and N-(2- hydroxyethyl)ethylenediamine ligands. Thermal behaviour of the complex was followed using TG, DTA and DTG techniques.

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Bibtex @araştırma makalesi { jist649334, journal = {Journal of the Institute of Science and Technology}, issn = {2146-0574}, eissn = {2536-4618}, address = {}, publisher = {Iğdır Üniversitesi}, year = {2020}, volume = {10}, pages = {985 - 997}, doi = {10.21597/jist.649334}, title = {Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu}, key = {cite}, author = {Aycan, Tuğba and Paşaoğlu, Hümeyra} }
APA Aycan, T , Paşaoğlu, H . (2020). Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu . Journal of the Institute of Science and Technology , 10 (2) , 985-997 . DOI: 10.21597/jist.649334
MLA Aycan, T , Paşaoğlu, H . "Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu" . Journal of the Institute of Science and Technology 10 (2020 ): 985-997 <
Chicago Aycan, T , Paşaoğlu, H . "Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu". Journal of the Institute of Science and Technology 10 (2020 ): 985-997
RIS TY - JOUR T1 - Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu AU - Tuğba Aycan , Hümeyra Paşaoğlu Y1 - 2020 PY - 2020 N1 - doi: 10.21597/jist.649334 DO - 10.21597/jist.649334 T2 - Journal of the Institute of Science and Technology JF - Journal JO - JOR SP - 985 EP - 997 VL - 10 IS - 2 SN - 2146-0574-2536-4618 M3 - doi: 10.21597/jist.649334 UR - Y2 - 2020 ER -
EndNote %0 Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu %A Tuğba Aycan , Hümeyra Paşaoğlu %T Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu %D 2020 %J Journal of the Institute of Science and Technology %P 2146-0574-2536-4618 %V 10 %N 2 %R doi: 10.21597/jist.649334 %U 10.21597/jist.649334
ISNAD Aycan, Tuğba , Paşaoğlu, Hümeyra . "Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu". Journal of the Institute of Science and Technology 10 / 2 (Haziran 2020): 985-997 .
AMA Aycan T , Paşaoğlu H . Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu. Iğdır Üniv. Fen Bil Enst. Der.. 2020; 10(2): 985-997.
Vancouver Aycan T , Paşaoğlu H . Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu. Journal of the Institute of Science and Technology. 2020; 10(2): 985-997.
IEEE T. Aycan ve H. Paşaoğlu , "Tereftalat ile [N-(2-Hidroksietil)-Etilendiamin] İçeren Karışık ligantlı Bakır(II) Kompleksinin Sentezi, Spektral, Termal ve Yapısal Karakterizasyonu", Journal of the Institute of Science and Technology, c. 10, sayı. 2, ss. 985-997, Haz. 2020, doi:10.21597/jist.649334