Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier

Öz In this study, the transport and mechanism of Fe(III) ions in acidic solution were investigated by using TOPO as carrier dissolved in kerosene with multi-drop membrane system. The parameters which are important in the transport of Fe(III) ions and their effects on the extraction process have been studied. These parameters are the effects of concentration of HCl solutions of donor phase, concentration of NaCl solutions of acceptor phase, concentration of TOPO solution of organic phase, transfer rate of organic phase, and temperature of the system. The optimum conditions for extraction of Fe(III) ions was conducted as 2.00 M of HCl and 100 mgL-1 Fe(III) ions for donor phase, 1.5x10-2 M of TOPO, 2.00 M NaCl of acceptor phase, 50 mLmin-1 of flux rate at 298.15 K. Over time, the reduction curves of the Fe(III) ions in the donor phase showed good agreement with the experimental data on the organic and acceptor phases. The activation energy was determined as 25.79 kJmol-1 and the extraction of Fe(III) ions was carried out by an intermediated-controlled process.
Anahtar Kelimeler:

MDLM system, Extraction, Iron, TOPO

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Bibtex @araştırma makalesi { jist481079, journal = {Journal of the Institute of Science and Technology}, issn = {2146-0574}, eissn = {2536-4618}, address = {}, publisher = {Iğdır Üniversitesi}, year = {2019}, volume = {9}, pages = {944 - 955}, doi = {10.21597/jist.481079}, title = {Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier}, key = {cite}, author = {Donat, Ramazan and Durmaz, Ömür} }
APA Donat, R , Durmaz, Ö . (2019). Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier . Journal of the Institute of Science and Technology , 9 (2) , 944-955 . DOI: 10.21597/jist.481079
MLA Donat, R , Durmaz, Ö . "Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier" . Journal of the Institute of Science and Technology 9 (2019 ): 944-955 <
Chicago Donat, R , Durmaz, Ö . "Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier". Journal of the Institute of Science and Technology 9 (2019 ): 944-955
RIS TY - JOUR T1 - Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier AU - Ramazan Donat , Ömür Durmaz Y1 - 2019 PY - 2019 N1 - doi: 10.21597/jist.481079 DO - 10.21597/jist.481079 T2 - Journal of the Institute of Science and Technology JF - Journal JO - JOR SP - 944 EP - 955 VL - 9 IS - 2 SN - 2146-0574-2536-4618 M3 - doi: 10.21597/jist.481079 UR - Y2 - 2019 ER -
EndNote %0 Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier %A Ramazan Donat , Ömür Durmaz %T Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier %D 2019 %J Journal of the Institute of Science and Technology %P 2146-0574-2536-4618 %V 9 %N 2 %R doi: 10.21597/jist.481079 %U 10.21597/jist.481079
ISNAD Donat, Ramazan , Durmaz, Ömür . "Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier". Journal of the Institute of Science and Technology 9 / 2 (Haziran 2019): 944-955 .
AMA Donat R , Durmaz Ö . Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier. Iğdır Üniv. Fen Bil Enst. Der.. 2019; 9(2): 944-955.
Vancouver Donat R , Durmaz Ö . Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier. Journal of the Institute of Science and Technology. 2019; 9(2): 944-955.
IEEE R. Donat ve Ö. Durmaz , "Extraction of Fe(III) Ions through MDLM System Containing TOPO as Carrier", Journal of the Institute of Science and Technology, c. 9, sayı. 2, ss. 944-955, Haz. 2019, doi:10.21597/jist.481079