Hegzaklorosiklohegzan izomerlerinin metal oksit varlığında gezegen hareketli bilyeli değirmen kullanılarak mekanokimyasal deklorinasyonu

Zararlı etkilerinden dolayı günümüzde hegzaklorosiklohegzan (HCH, C6H6Cl6) kullanımı yasaklanmış olsada geçmişten kalan üretim stokları hala mevcuttur. Son araştırmalar mekanokimyasal deklorinasyonprosesinin HCH’ın gideriminde umut vaat eden bir yöntem olduğunu göstermiştir. Ancak mekanokimyasaldeklorinasyon prosesinin geçerli bir yöntem olabilmesi için daha fazla araştırmaya ihtiyaç duyulmaktadır.Bu amaçla mevcut çalışmada; içeriğinde çeşitli metal oksitler bulunduran uçucu kömür külü (UK) verefrakter tuğla atığı (RT) kullanılarak hegzaklorosiklohegzan (HCH) izomerlerinin mekanokimyasaldeklorinasyonu ilk defa araştırılmıştır. Mekanokimyasal deklorinasyon prosesi oda sıcaklığında gezegenhareketli bilyeli değirmende gerçekleştirilmiş ve giderim veriminin belirlenmesi amacıyla elektron yakalamadedektörlü gaz kromatografi (GC-ECD) cihazı kullanılmıştır. Sonuçlar 1:20 (m/m) oranında HCH: UKkullanılarak 600 dk. sonunda HCH izomerlerinin tamamıyla giderildiğini göstermiştir. Organik klorun sudaçözünür klora dönüşüm oranı ise %52’dir. Proses sonunda bilye sıcaklıkları 105oC’ye kadar yükselmiş vereaktif+HCH karışım sıcaklıkları da proses süresi ile birlikte sürekli olarak artmıştır. Tetraklorobenzenler(TeKBz) ve triklorobenzenler (TKBz) ise deklorinasyon sırasında tespit edilen izomerlerdir. Çalışmasonuçlarına göre HCH izomerlerinin mekanokimyasal deklorinasyonu, termal arıtma ve biotik parçalamauygulamalarına alternatif çevre dostu bir teknolojidir.

Mechanochemical declorination of hexachlorocyclohexane isomers by planetary ball mill in the presence of metal oxides

Although the use of hexachlorocyclohexane (HCH, C6H6Cl6) is currently prohibited, the remaining production stocks of HCH are still present. Recent investigations have shown that mechanochemical dechlorination is a promising method to degrade HCH. However, the mechanochemical dechlorination method still needs further investigations. For this reason, in this study, mechanochemical dechlorination of HCH isomers were investigated for the first time by using coal fly ash (FA) and refractory brick waste (RB) which contain various metal oxides. The mechanochemical dechlorination process was carried out at room temperature using a planetary ball mill and the gas chromatograph with electron capture detector (GC-ECD) was used to determine the degradation efficiency. The results show that HCH isomers can be completely destroyed after 600 min grinding time in a mixture with a HCH/FA ratio of 1:20 (m/m). The conversion rate of chlorine to water soluble chlorine is 52%. At the end of the process, the ball temperatures increased up to 105oC and the mixture temperatures of reagent + HCH were continuously increased with the process time. Tetrachlorobenzenes (TeCBz) and trichlorobenzenes (TCBz) are the isomers detected during the dechlorination. Based on this study, mechanochemical dechlorination of HCH isomers is a eco-friendly technology alternative to thermal treatment and biotic degradation applications.

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