SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES

SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES

The 2,4-dioxopentanoic acid derivatives (3d-f) were obtained from the reaction of 4- acetyl-5-(1-naphthyl)furan-2,3-dione (1) with various nitrogenous nucleophiles (2d-f). The structures of these newly synthesized compounds (3d-f) were determined from the FT-IR, 1H and 13C NMR spectroscopic data and elemental analyses. Theoretical Study of derivatives of (3Z)-3-{2-naphthyl[2- (4-nitrophenyl)hydrazino]methylene}-2,4-dioxopentanoic acid (3d-f) were carried out by using DFT/B3LYP method with basis set of the 6-311G(d,p) in order to find molecular properties by Gaussian 03 program [1](see Schemes 1and 2). According to EHOMO and softness values; electronic give trends for investigated molecules can be written as: 3f>3d>3e.The EHOMO and EHOMO energy gap of a measure of stability. Additionally, according to EHOMO and EHOMO energy gap; stability give trends for investigated molecules can be written as: 3e>3d>3f.

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Bibtex @araştırma makalesi { else313721, journal = {Electronic Letters on Science and Engineering}, issn = {1305-8614}, address = {Bozok University, Electrical and Electronics Engineering, Erdoğan Akdag Kampus, 66200, Yozgat, TURKEY.}, publisher = {Fevzullah TEMURTAŞ}, year = {2016}, volume = {12}, number = {2}, pages = {24 - 25}, title = {SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES}, key = {cite}, author = {Saracoglu, Murat and Kandemirli, Fatma and Özalp, Ayhan and Kökbudak, Zülbiye} }
APA Saracoglu, M. , Kandemirli, F. , Özalp, A. & Kökbudak, Z. (2016). SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES . Electronic Letters on Science and Engineering , 12 (2) , 24-25 .
MLA Saracoglu, M. , Kandemirli, F. , Özalp, A. , Kökbudak, Z. "SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES" . Electronic Letters on Science and Engineering 12 (2016 ): 24-25 <
Chicago Saracoglu, M. , Kandemirli, F. , Özalp, A. , Kökbudak, Z. "SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES". Electronic Letters on Science and Engineering 12 (2016 ): 24-25
RIS TY - JOUR T1 - SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES AU - Murat Saracoglu , Fatma Kandemirli , Ayhan Özalp , Zülbiye Kökbudak Y1 - 2016 PY - 2016 N1 - DO - T2 - Electronic Letters on Science and Engineering JF - Journal JO - JOR SP - 24 EP - 25 VL - 12 IS - 2 SN - 1305-8614- M3 - UR - Y2 - 2022 ER -
EndNote %0 Electronic Letters on Science and Engineering SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES %A Murat Saracoglu , Fatma Kandemirli , Ayhan Özalp , Zülbiye Kökbudak %T SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES %D 2016 %J Electronic Letters on Science and Engineering %P 1305-8614- %V 12 %N 2 %R %U
ISNAD Saracoglu, Murat , Kandemirli, Fatma , Özalp, Ayhan , Kökbudak, Zülbiye . "SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES". Electronic Letters on Science and Engineering 12 / 2 (Ağustos 2016): 24-25 .
AMA Saracoglu M. , Kandemirli F. , Özalp A. , Kökbudak Z. SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES. Electronic Letters on Science and Engineering. 2016; 12(2): 24-25.
Vancouver Saracoglu M. , Kandemirli F. , Özalp A. , Kökbudak Z. SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES. Electronic Letters on Science and Engineering. 2016; 12(2): 24-25.
IEEE M. Saracoglu , F. Kandemirli , A. Özalp ve Z. Kökbudak , "SYNTHESIS AND THEORETICAL STUDY OF 4-ACETYL-5-(2-NAPHTYL)-2,3-DIHYDRO-2,3-FURANDIONE WITH SOME NITROGENOUS NUCLEOPHILES", Electronic Letters on Science and Engineering, c. 12, sayı. 2, ss. 24-25, Ağu. 2016