AB Tipi Nikel(II) Ftalosiyanin Türevinin Sentezi, Agregasyon Özelliği ve Floresan Kuantum Verimi

Bu çalışmada amino grupları içeren asimetrik ABAB tipi nikel ftalosiyanin sentezlenmiştir. Bu yeni nikelftalosiyaninin bileşiğinin yapısı element analizi, IR, 1H-NMR, UV-Vis ve kütle spektral verilerine göre karakterize edilmiştir. Yeni sentezlenen nikel ftalosiyanin bileşiği DMF, piridin, kloroform, diklorometangibi organik çözücülerde mükemmel çözünürlük göstermiştir. Nikel ftalosiyanin türevleri mükemmel elektrokatalitik özellik göstermektedirler. Bu tür çalışmalara temel oluşturmak amacıyla yeniftalosiyanininagregasyon özelliği ve floresan kuantum verimi incelenmiştir. Sentezlenen yeni ftalosiyanin bileşiği agregasyon göstermemiştir.

Anahtar Kelimeler:

Nikel phthalocyanine, Agregasyon, Floresan Kuantum Verimi

Synthesis, Aggregation and Fluorescent Quantum Yield of AB Type Nickel(II) Phthalocyanine Derivative

In this study, asymmetric ABAB type nickel phthalocyanine containing amino groups was synthesized. The structure of this new nickel phthalocyanine compound was characterized by elemental analysis, IR, 1H-NMR, UV-Vis and mass spectral data. The newly synthesized nickel phthalocyanine compound showed excellent solubility in organic solvents such as DMF, pyridine, chloroform, and dichloromethane. Nickel phthalocyanine derivatives show excellent electrocatalytic properties. In order to form a basis for such studies, theaggregation property and fluorescence quantum yield of the new phthalocyanine were investigated. The newly synthesized phthalocyanine compound did not show aggregation.

Keywords:

Nickel phthalocyanine, Aggregation, Fluorescent Quantum Yield,

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