The Preparation and Characterization of LSCF and LCCF Perovskite Cathode Electrode for Solid Oxide Fuel Cell Applications

The Preparation and Characterization of LSCF and LCCF Perovskite Cathode Electrode for Solid Oxide Fuel Cell Applications

In this paper, LaSrCoFe and LaCaCoFe powders compositions were prepared with the solid state reaction. The crystal structure of powders perovskite possess hexagonal type crystal lattice according to the literature survey. Crystallographic and micro structural properties of the produced powder were characterized by XRD. Lattice parameter for LSCF a=5.471 Å,c=13.47 Å and for LCCF a=5.435 Å, c=13.23 Å. Cathode electrode which is small crystal particle was formed into a thin film. The conductivity of the thin film LSCF was measured by four probe conductive.

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  • 1. Jiang, S.P, Development of lanthanum strontium manganite perovskite cathode materials of solid oxide fuel cells: a review, Journal of Material Science, 2008, 43(21), 6799-6833,
  • 2. Hung, M.H, Madhava Rao, M.V, Tsai, D.S, Microstructures andelectrical properties of calcium substituted LaFeO3 as SOFC cathode, Materials Chemistry and Physics, 2007, 101, 297-302.
  • 3. Torun Özlü, H, Çakar, S, Ersoy, E, Türkoğlu, O, The bulk electrical contuctivity properties of d-Bi2O3 solid electrolyte system doped with Yb2O3, Journal of Thermal Analysis and Calorimetry, 2015, 122, 525- 536.
  • 4. Özlü, H, Ersoy, E, Çakar, S, Türkoğlu, O, The Preparation and Characterization of LaNi1-xFexO3 Perovskite Thin Film as a Cathode Electrode for Solid Oxide Fuel Cell Applications. 2nd International Conference on Nuclear and Renewable Energy Resources, 2010.
  • 5. Efimov, K, Klande, T, Juditzki, N, Feldhoff, A, Ca-containing CO2- tolerant perovskite materials for oxygen separation, Journal of Membrane Science, 2012, 389, 205-215.
  • 6. Manasa, K.R, Lee, K, Investigation of aliovalent transition metal doped La0.7Ca0.3Cr0.8X0.2O3? (x=Ti, Mn, Fe, Co, and Ni) as electrode materials for symmetric solid oxide fuel cells, Ceramics International, 2015, 41, 10878-10890.
  • 7. Gu, H, Chen, H, Gao, L, Zheng, Y, Zhu, X, Guo, L, Effect of Co doping on the properties of Sr0.8Ce0.2MnO3-? cathode for inter-mediatetemperature solid-oxide fuel cells, International Journal of Hydrogen Energy, 2008, 33(17), 4681-4688.