NiTiHf-tabanlı yüksek sıcaklıklı şekil hafızalı alaşımlar
Şekil hafızalı alaşımlar metalik akıllı malzemeler olup biyomedikal, havacılık, elektronik, inşaat, petrol ve otomobil dahil olmak üzerebir çok endüstri alanında kullanılmakta ve gelecekte kullanım alanlarının artacağı tahmin edilmektedir. Biyomedikal ve elektronikgibi bazı alanlarda düşük sıcaklıkta gösterilen hafıza özelliği yeterli olmakla birlikte havacılık, petrol ve otomobil uygulamaları içinyüksek sıcaklıkta (>100 oC) şekil hafıza özelliği gösteren malzemelere ihtiyaç duyulmaktadır. Bundan dolayı en çok bilinen Nitinolalaşımları yüksek sıcaklık uygulamaları için uygun olmamaktadır. Bu derleme makalesinde yüksek sıcaklık uygulamaları içingeliştirilen NiTiHf-tabanlı (Nikel-Titanyum-Hafniyum tabanlı) şekil hafızalı alaşımlar üzerinde yapılan en son araştırmalar vekullanım alanlarından bahsedilmektedir. NiTiHf-tabanlı yüksek sıcaklıklı şekil hafızalı alaşımların günümüzde yaygın olarakkullanılmasının önündeki engellerden ve bu engellerin ortadan kaldırılması için yapılan çalışmalar hakkında bilgi verilecektir.
NiTiHf-based high temperature shape memory alloys
Shape memory alloys are metallic smart materials that have been currently used in many industries including biomedical, aerospace, electronics, construction, oil-gas and automobile and their application areas are predicted to be increased in future. Industries such as aerospace, oil-gas and automobile requires high transformation temperatures (>100 oC ) whereas low transformation temperatures are sufficient in biomedical and electronics. Thus, NiTi alloys are not good candidates for high temperature applications due to their low transformation temperatures. In this review, recent developments on research and application of NiTiHf-based high temperature shape memory alloys are discussed. On the other hand, limitations of NiTiHf-based high temperature shape memory alloys and studies to overcome those limitations are commented.
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- Wayman, C.M., Otsuka, K.1998. Shape Memory Materials,
Cambridge University Press.
- Noebe RD, Biles T and Padula SA. 2007. ‘NiTi-based hightemperature
shape-memory alloys: properties, prospects, and
potential applications’, in ‘Advanced structural materials:
properties, design optimization, and applications’, (ed. W. O.
Soboyejo and T. S.Srivatsan); New York, Taylor & Francis
Group.
- LeBlanc L. 2001. ‘Part I – ‘‘Smart metals’’ providing
actuation, sealing, and completion functions downhole’,
Offshore.61 (12), 58.
- LeBlanc L.2002. ‘Part II – ‘‘Smart metals’’ providing
actuation, sealing, and completion functions downhole’,
Offshore.62 (1), 54.
- Song G, Ma N and Li HN. 2006. ‘Applications of shape
memory alloys in civil structures’, Eng. Struct..28, (9), 1266–
1274.
- Van Humbeeck J. 1999. ‘Non-medical applications of shape
memory alloys’, Mater. Sci. Eng. A, A273, 134–148.
- Petrini L and Migliavacca F.2011. ‘Biomedical applications
of shape memory alloys’, J. Metall., 501483.
- El Feninat F, Laroche G, Fiset M and Mantovani D. 2002.
‘Shape memory materials for biomedical applications’, Adv.
Eng. Mater.4, (3), 91–104.
- Firstov GS, Van Humbeeck J and Koval YN.2006. ‘High
temperature shape memory alloys problems and prospects’, J.
Intell. Mater. Syst. Struct.17, (12), 1041–1047.
- Karaca HE, Kaya I, Tobe H, Basaran B, Nagasako M,
Kainuma R, Chumlyakov YI.2013. ‘Shape memory behavior of
high strength Ni54Ti46 alloys’, Mater. Sci. Eng. A. A580, 66–
70.
- Otsuka K and Ren X.2005 ‘Physical metallurgy of Ti-Nibased
shape memory alloys’, Prog. Mater. Sci. 50, (5), 511–678.
- Ma J, Karaman I and Noebe RD.2010. ‘High temperature
shape memory alloys’, Int. Mater. Rev. 55, (5), 257–315.
- Kockar B, Karaman I, Kim JI and Chumlyakov YI.2006.
‘A method to enhance cyclic reversibility of NiTiHf high
temperature shape memory alloys’, Scr. Mater. 54, (12), 2203–
2208.
- Meng XL, Cai W, Wang LM, Zheng YF, Zhao LC and
Zhou LM. 2001. ‘Microstructure of stress-induced martensite in
a Ti- Ni-Hf high temperature shape memory alloy’, Scr.
Mater..45, (10), 1177–1182.
- Meng XL, Cai W, Fu YD, Li QF, Zhang JX and Zhao
LC.2008. ‘Shape-memory behaviors in an aged Ni-rich TiNiHf
high temperature shape-memory alloy’, Intermetallics. 16, (5),
698–705.
- Meng XL, Cai W, Chen F and Zhao LC.2006. ‘Effect of
aging on martensitic transformation and microstructure in Nirich
TiNiHf shape memory alloy’, Scr. Mater. 54, 1599–1604.
- Karaca HE, Saghaian SM, Ded G, Tobe H, Basaran B,
Maier HJ, Noebe RD and Chumlyakov YI. 2013. ‘Effects of
nanoprecipitation on the shape memory and material
propertiesof an Ni-rich NiTiHf high temperature shape memory
alloy’, Acta Mater., 61, (19), 7422–7431.
- Santamarta R, Arro´ R, Pons J, Evirgen A, Karaman I,
Karaca HE and Noebe RD.2013. ‘TEM study of structural and
microstructural characteristics of a precipitate phase in Ni-rich
Ni– Ti–Hf and Ni–Ti–Zr shape memory alloys’, Acta Mater.
61,(16), 6191–6206.
- Karaca HE, Saghaian SM, Basaran B, Bigelow GS, Noebe
RD and Chumlyakov YI2011. ‘Compressive response of nickelrich
NiTiHf high-temperature shape memory single crystals
along the [1 1 1] orientation’, Scr. Mater. 65, (7), 577–580.
- Karaca,H.E.,Acar,E.,Tobe,H. and Saghaian,S.M.2014.
”NiTiHf-based shape memory alloys”, Mater. Sci. Technol.,
30;1530–1544.
- Acar E, Karaca HE, Basaran B, Yang F, Mills MJ, Noebe
RD and Chumlyakov YI.2013. ‘Role of aging time on the
microstructure and shape memory properties of NiTiHfPd single
crystals’, Mater. Sci. Eng. A. A573, 161–165.
- Acar E, Karaca HE, Tobe H, Noebe RD and Chumlyakov
YI.2013. ‘Characterization of the shape memory properties of a
Ni45?3Ti39?7Hf10Pd5 alloy’, J. Alloys Compd. 578, 297–302.
- Karaca HE, Acar E, Basaran B, Noebe RD, Bigelow GS,
Garg A, Yang F, Mills MJ and Chumlyakov YI.2012. ‘Effects
of aging on [111] oriented NiTiHfPd single crystals under
compression’, Scr. Mater.67, (7–8), 728–731.
- Acar E, Ozbulut OE and Karaca HE. 2015. Experimental
investigation and modeling of the loading rate and temperature
dependent superelastic response of a high performance shapememory
alloy, Smart Mater. Struct., (24/7), 75020.
- Acar E. 2015. Dynamic mechanical response of a Ni45.
7Ti29. 3Hf20Pd5 alloy, Materiaşs Science and Engineering A,
(633) 169-175.
- Karaca HE, Acar E, Ded GS, Basaran B, Tobe H, Noebe
RD, Bigelow G and Chumlyakov YI.2013. ‘Shape memory
behavior of high strength NiTiHfPd polycrystalline alloys’, Acta
Mater. 61, (13), 5036–5049.
- Karaca HE, Acar E, Basaran B, Noebe RD and
Chumlyakov YI.2012. ‘Superelastic response and damping
capacity of ultrahigh-strength [111]-oriented NiTiHfPd single
crystals’, Scr. Mater. 67, (5), 447–450.
- Kim HY, Jinguu T, Nam TH and Miyazaki S.2011. ‘Cold
workability and shape memory properties of novel Ti–Ni–Hf–Nb
high-temperature shape memory alloys’, Scr. Mater. 65, (9),
846–849.
- Liang XL, Chen Y, Shen HM, Zhang ZF, Li W and Wang
YN.2001. ‘Thermal cycling stability and two-way shape
memory effect of Ni-Cu-Ti-Hf alloys’, Solid State Commun.
119, (6), 381–385.
- Hsieh SF and Wu SK.2000. ‘Martensitic transformation of
quaternary Ti50?5-XNi49?5ZrX/2HfX/2 (X50–20 at.%) shape
memory alloys’, Mater. Charact. 45, (2), 143–152.
- Besseghini S, Villa E and Tuissi A.1999 ‘Ni-Ti-Hf shape
memory alloy: effect of aging and thermal cycling’, Mater. Sci.
Eng. A. A273–A275, 390–394.
- Angst DR, Thoma PE and Kao MY.1995. ‘The effect of
Hafnium content on the transformation temperatures of
Ni49Ti51-xHfx shape memory alloy’, J. Phys. IV, Colloq. C8,
747–752.
- Abu Judom D, Thoma PE, Kao MY and Angst DR.1992.
‘High transformation temperature shape memory alloy’, US
patent 5,114,504.
- Wang YQ, Zheng YF, Cai W and Zhao LC.1999. ‘The
tensile behavior of Ti36Ni49Hf15 high temperature shape
memory alloy’, Scr. Mater. 40, (12), 1327–1331.
- Zarinejad M and Liu Y.2010. ‘Dependence of
transformation temperatures of shape memory alloys on the
number and concentration of valence electrons’, in ‘Shape
memory alloys: manufacture, properties and applications’, (ed.
H. R. Chen), 339– 360; Hauppauge, NY Science Publishers.
- Meng XL, Cai W, Lau KT, Zhao LC, Zhou LM.2005.
‘Phase transformation and microstructure of quaternary
TiNiHfCu high temperature shape memory alloys’,
Intermetallics. 13, (2), 197–201
- Zarinejad M, Liu Y and Tong Y.2009. ‘Transformation
temperature changes due to second phase precipitation in NiTibased
shape memory alloys’, Intermetallics. 17, (11), 914–919.
- Zarinejad M and Liu Y.2008. ‘Dependence of
transformation temperatures of NiTi-based shape-memory alloys
on the number and concentration of valence electrons’, Adv.
Funct. Mater. 18, (18), 2789–2794.
- Potapov PL, Shelyakov AV, Gulyaev AA, Svistunov EL,
Matveeva NM and Hodgson D.1997 ‘Effect of Hf on the
structure of Ni-Ti martensitic alloys’, Mater. Lett. 32, (4), 247–
250.
- Karaca HE, Acar E, Ded GS, Saghaian SM, Basarab B, Tobe
H, Kok M, Maier HJ, Noebe RD, Chumlyakov YI. 2015.
Microstructure and transformation related behaviors of a
Ni45.3Ti29.7Hf20Cu5 high temperature shape memory alloy”,
Mater. Sci. Eng. A. ,627; 82–94
- Meng XL, Zheng YF, Wang Z and Zhao LC.2000. ‘Effect
of aging on the phase transformation and mechanical behavior of
Ti36Ni49Hf15 high temperature shape memory alloy’, Scr.
Mater. 42, (4), 341–348.
- Meng XL, Cai W, Zheng YF, Tong YX, Zhao LC and Zhou
LM.2002. ‘Stress-induced martensitic transformation behavior
of a Ti-Ni-Hf high temperature shape memory alloy’, Mater.
Lett. 55, (1–2), 111–115.
- Bigelow GS, Garg A, Padula II SA, Gaydosh DJ and
Noebe RD.2011. ‘Load-biased shape-memory and superelastic
properties of a precipitation strengthened high-temperature
Ni50?3Ti29?7Hf20 alloy’, Scr. Mater. 64, (8), 725–728.
- Hong SH, Kim JT, Park HJ, Kim YS, Suh JY, Na YS, Lim
KR, Shim CH, Park JM, Kim KB. 2017. ‘Influence of Zr content
on phase formation, transition and mechanical behavior of NiTi-Hf-Zr
high temperature shape memory alloys’. Journal of
Alloys and Compounds, 692; 77-85
- Yi X, Pang G, Sun B, Meng X, Cai W. 2018. ‘The
microstructure and martensitic transformation behaviors in TiNi-Hf
-X (Ag, Sn) high temperature shape memory alloys’.
Journal of Alloys and Compounds. 756;19-25.
- Yi X, Gao W, Meng X, Gao Z, Cai W, Zhao L. 2017.
‘Martensitic transformation behaviors and mechanical
properties of (Ti36Ni49Hf15)100-xYx high temperature
shape memory alloys’. Journal of Alloys and
Compounds.705;98-104.
- Huang,W.,1998. ‘Shape Memory Alloys and their
Application to Actuators for Deployable Structures’. PhD
Dissertation ,University of Cambridge.
- Acar, E.2014.’Precipitation, orientation and composition
effects on the shape memory properties of high strength
NiTiHfPd alloys’, PhD Dissertation, University of Kentucky