Modelling study of the atmospheric composition over Cyprus

In this study the online meteorological and chemical transport model “Weather Research and Forecasting coupled with Chemistry” (WRF/Chem) is implemented over Cyprus and evaluated against ground-based air quality and meteorological observations. Hourly O3 concentrations are strongly overestimated and a reduction in the lateral boundaries of ozone by 30% improved model agreement with observations. Utilization of grid spacing closer to the resolution of the emission data leads to an improvement in the simulation of air pollutants, while further reduction of the grid spacing mostly impacts the model performance related to meteorological parameters. The method of speciation of volatile organic compounds can also affect model results. Reduction of NOx emissions can reduce fine particulate (PM2.5) levels relatively effectively due to the important role of nitrate over Cyprus. The present case study indicates that the performance of the WRF/Chem model is reasonable for air quality and meteorological variables over Cyprus when boundary conditions are cautiously adjusted or improved, while there is a need to pursue a high-resolution local emission inventory.

Kaynakça

Abdallah, C., Sartelet, K., Afif, C., 2016. Influence of boundary conditions and anthropogenic emission inventories on simulated O3 and PM2.5 concentrations over Lebanon. November 2016. Atmos. Pollut. Res. 7 (6), 971–979.

Ackermann, I.J., Hass, H., Memmesheimer, M., Ebel, A., Binkowski, F.S., Shankar, U., 1998. Modal aerosol dynamics model for Europe: development and first applications. Atmos. Environ. 32, 2981–2999.

Amanatidis, D.G., Myriokefalitakis, S., Daskalakis, N., Kanakidou, M., 2017. Evaluation of a coupled mesoscale meteorology and chemistry model over the mediterranean. In: Karacostas, T., Bais, A., Nastos, P. (Eds.), Perspectives on Atmospheric Sciences. Springer Atmospheric Sciences. Springer, Cham.

Astitha, M., Kallos, G., 2008. Gas-phase and Aerosol Chemistry Interactions in South Europe and the Mediterranean Region Environmental Fluid Mechanics. http://dx.doi. org/10.1007/s10652-008-9110-7.

Baklanov, A., Mahura, A., Sokhi, R., 2011a. Integrated Systems of Meso-meteorological and Chemical Transport Models, Springer. pp. 242. http://dx.doi.org/10.1007/978- 3-642-13980-2.

Baklanov, A.A., Korsholm, U.S., Mahura, A.G., Nuterman, R.B., Sass, B.H., Zakey, A.S., 2011b. Physical and chemical weather forecasting as a joint problem: two-way interacting integrated modelling. In: American Meteorological Society 91st Annual Meeting, 23–27 January 2011, Seattle, WA, USA, Paper 7.1, AMS2011 paper 7-1 fv.pdf.

Bangert, M., Nenes, A., Vogel, B., Vogel, H., Barahona, D., Karydis, V.A., Kumar, P., Kottmeier, C., Blahak, U., 2012. Saharan dust event impacts on cloud formation and radiation over Western Europe. Atmos. Chem. Phys. 12, 4045–4063. http://dx.doi. org/10.5194/acp-12-4045-2012.

Bossioli, E., Tombrou, M., Kalogiros, J., Allan, J., Bacak, A., Bezantakos, S., Biskos, G., Coe, H., Jones, B., Kouvarakis, G., Mihalopoulos, N., Percival, C., 2016. Atmospheric composition in the Eastern Mediterranean: Influence of biomass burning during summertime using the WRF-Chem model. Atmos. Environ. 317. http://dx.doi.org/10. 1016/j.atmosenv.2016.03.011.

Derstroff, B., Hüser, I., Sander, R., Bourtsoukidis, E., Crowley, J.N., Fischer, H., Gromov, S., Harder, H., Kesselmeier, J., Lelieveld, J., Mallik, C., Martinez, M., Novelli, A., Parchatka, U., Phillips, G.J., Sauvage, C., Schuladen, J., Stönner, C., Tomsche, L., Williams, J., 2017. Volatile organic compounds (VOCs) in photochemically aged air from the Eastern and Western Mediterranean. Atmos. Chem. Phys. 17, 9547–9566. http://dx.doi.org/10.5194/acp-17-9547-2017.

Eder, B., Kang, D., Mathur, R., Yu, S., Schere, K., 2006. An operational evaluation of the Eta-CMAQ air quality forecasting model. Atmos. Environ. 40, 4894–4905.

Emmons, L.K., Walters, S., Hess, P.G., Lamarque, J.-F., Pfister, G.G., Fillmore, D., Granier, C., Guenther, A., Kinnison, D., Laepple, T., Orlando, J., Tie, X., Tyndall, G., Wiedinmyer, C., Baughcum, S.L., Kloster, S., 2010. Description and evaluation of the model for ozone and related chemical Tracers, version 4 (MOZART-4). Geosci. Model Dev. 3, 43–67. http://dx.doi.org/10.5194/gmd-3-43-2010.

Fast, J.D., Gustafson Jr., W.I., Easter, R.C., Zaveri, R.A., Barnard, J.C., Chapman, E.G., Grell, G.A., 2006. Evolution of ozone, particulates, and aerosol direct forcing in an urban area using a new fully-coupled meteorology, chemistry, and aerosol model. J. Geophys. Res. Atmos. 111, D21305. http://dx.doi.org/10.1029/2005JD006721.

Gerasopoulos, E., Zanis, P., Papastefanou, C., Zerefos, C.S., Ioannidou, A., Wernli, H., 2006a. A complex case study of down to the surface intrusions of persistent stratospheric air over the Eastern Mediterranean. Atmos. Environ. 40, 4113–4125.

Gerasopoulos, E., Kouvarakis, G., Babasakalis, P., Vrekoussis, M., Putaud, J.P., Mihalopoulos, N., 2006b. Origin and variability of particulate matter (PM10) mass concentrations over the Eastern Mediterranean. Atmos. Environ. 40, 4679–4690.

Gerasopoulos, E., Kouvarakis, G., Vrekoussis, M., Donoussis, C., Mihalopoulos, N., Kanakidou, M., 2006c. Photochemical ozone production in the eastern mediterranean. Atmos. Environ. 40, 3057–3069.

Grell, G.A., Devenyi, D., 2002. A generalized approach to parameterizing convection combining ensemble and data assimilation techniques. Geophys. Res. Lett. 29, 10–13. http://dx.doi.org/10.1029/2002GL015311. 1693.

Grell, G.A., Baklanov, A., 2011. Integrated modelling for forecasting weather and air quality: a call for fully coupled approaches. Atmos. Environ. 45, 6845–6851.

Grell, G.A., Peckham, S.E., McKeen, S., Schmitz, R., Frost, G., Skamarock, W.C., Eder, B., 2005. Fully coupled “online” chemistry within the WRF model. Atmos. Environ. 39, 6957–6975. http://dx.doi.org/10.1016/j.atmosenv.2005.04.027.

Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P.I., Geron, C., 2006. Estimates of global terrestrial isoprene emissions using MEGAN (model of emissions of gases and aerosols from nature). Atmos. Chem. Phys. 6, 3181–3210. http://dx.doi.org/10. 5194/acp-6-3181-2006.

Hong, Song–You, Noh, Yign, Dudhia, Jimy, 2006. A new vertical diffusion package with an explicit treatment of entrainment processes. Mon. Wea. Rev. 134, 2318–2341.

Iacono, M.J., Delamere, J.S., Mlawer, E.J., Shephard, M.W., Clough, S.A., Collins, W.D., 2008. Radiative forcing by long-lived greenhouse gases: calculations with the AER radiative transfer models. J. Geophys. Res. Atmos. 113, D13103.

Im, U., Kanakidou, M., 2012. Impacts of East Mediterranean megacity emissions on air quality. Atmos. Chem. Phys. 12, 6335–6355.

Janssens-Maenhout, G., Dentener, F., van Aardenne, J., Monni, S., Pagliari, V., Orlandini, L., Klimont, Z., Kurokawa, J., Akimoto, H., Ohara, T., Wankmüller, R., Battye, B., Grano, D., Zuber, A., Keating, T., 2012. EDGAR-htap: a Harmonized Gridded Air Pollution Emission Dataset Based on National Inventories. European Commission, Joint Research Centre, Institute for Environment and Sustainability, Luxemburg.

Kallos, G., Astitha, M., Katsafados, P., Spyrou, C., 2007. Long-range transport of anthropogenically and naturally produced particulate matter in the Mediterranean and North Atlantic: current state of knowledge. J. Appl. Meteorol. Clim. 46. http://dx.doi. org/10.1175/JAM2530.1.

Kanakidou, M., Mihalopoulos, N., Kindap, T., Im, U., Vrekoussis, M., Gerasopoulos, E., Dermitzaki, E., Unal, A., Koçak, M., Markakis, K., Melas, D., Kouvarakis, G., Youssef, A.F., Richter, A., Hatzianastassiou, N., Hilboll, A., Ebojie, F., Wittrock, F., von Savigny, C., Burrows, J.P., Ladstaetter-Weissenmayer, A., Moubasher, H., 2010. Megacities as hot spots of air pollution in the East Mediterranean. Atmos. Environ. http://dx.doi.org/10.1016/j.atmosenv.2010.11.048.

Kleanthous, S., Vrekoussis, M., Mihalopoulos, N., Kalabokas, P., Lelieveld, J., 2014. On the temporal and spatial variation of ozone in Cyprus. Sci. Tot. Environ. 476–477, 677–687.

Kouvarakis, G., Vrekoussis, M., Mihalopoulos, N., Kourtidis, K., Rappenglueck, B., Gerasopoulos, E., Zerefos, C., 2002. Spatial and temporal variability of tropospheric ozone (O3) in the boundary layer above the Aegean Sea (Eastern Mediterranean). J. Geophys. Res. Atmos. 107 PAU 4-1-PAU 4–14.

Kukkonen, J., Olsson, T., Schultz, D.M., Baklanov, A., Klein, T., Miranda, A.I., Monteiro, A., Hirtl, M., Tarvainen, V., Boy, M., Peuch, V.-H., Poupkou, A., Kioutsioukis, I., Finardi, S., Sofiev, M., Sokhi, R., Lehtinen, K.E.J., Karatzas, K., San José, R., Astitha, M., Kallos, G., Schaap, M., Reimer, E., Jakobs, H., Eben, K., 2012. A review of operational, regional-scale, chemical weather forecasting models in Europe. Atmos. Chem. Phys. 12, 1–87. http://dx.doi.org/10.5194/acp-12-1-2012.

Kushta, J., Kallos, G., Astitha, M., Solomos, S., Spyrou, C., Mitsakou, C., Lelieveld, J., 2014. Impact of natural aerosols on atmospheric radiation and consequent feedbacks with the meteorological and photochemical state of the atmosphere. JGR. http://dx. doi.org/10.1002/2013JD020714.

Lelieveld, J., Berresheim, H., Borrmann, S., Crutzen, P.J., Dentener, F.J., Fischer, H., Feichter, J., Flatau, P.J., Heland, J., Holzinger, R., Korrmann, R., Lawrence, M.G., Levin, Z., Markowicz, K.M., Mihalopoulos, N., Minikin, A., Ramanathan, V., de Reus, M., Roelofs, G.J., Scheeren, H.A., Sciare, J., Schlager, H., Schultz, M., Siegmund, P., Steil, B., Stephanou, E.G., Stier, P., Traub, M., Warneke, C., Williams, J., Ziereis, H., 2002. Global air pollution crossroads over the Mediterranean. Science 298, 794–799.

Lelieveld, J., Beirle, S., Hörmann, C., Stenchikov, G., Wagner, T., 2015. Abrupt recent trend changes in atmospheric nitrogen dioxide over the Middle East. Sci. Adv. http:// dx.doi.org/10.1126/sciadv.1500498.

Meusel, H., Kuhn, U., Reiffs, A., Mallik, C., Harder, H., Martinez, M., Schuladen, J., Bohn, B., Parchatka, U., Crowley, J.N., Fischer, H., Tomsche, L., Novelli, A., Hoffmann, T., Janssen, R.H.H., Hartogensis, O., Pikridas, M., Vrekoussis, M., Bourtsoukidis, E., Weber, B., Lelieveld, J., Williams, J., Pöschl, U., Cheng, Y., Su, H., 2016. Daytime formation of nitrous acid at a coastal remote site in Cyprus indicating a common ground source of atmospheric HONO and NO. Atmos. Chem. Phys. 16, 14475–14493. http://dx.doi.org/10.5194/acp-16-14475-2016.

Middleton, P., Stockwell, W.R., Carter, W.P.L., 1990. Aggregation and analysis of volatile organic compound emissions for regional modeling. Atmos. Environ. 24A, 1107–1133.

Mihalopoulos, N., Kerminen, V.-M., Kanakidou, M., Berresheim, H., Sciare, J., 2007. Formation of particulate sulfur species (sulfate and methanesulfonate) during, summer over the Eastern Mediterranean: a modelling approach. Atmos. Environ. 41, 6860–6871.

Monks, P.S., Granier, C., Fuzzi, S., Stohl, A., Williams, M.L., Akimoto, H., 2009. Atmospheric composition change - global and regional air quality. Atm. Env. 43 (33), 5268–5350. http://dx.doi.org/10.1016/j.atmosenv.2009.08.021. UC Irvine: 921467.

Morrison, H., Curry, J.A., Khvorostyanov, V.I., 2005. A new double-moment microphysics parameterization for application in cloud and climate models. Part I: description. J. Atmos. Sci. 62, 1665–1677. http://dx.doi.org/10.1175/JAS3446.1. 6120.

Otte, T.L., Pouliot, G., Pleim, J.E., Young, J.O., Schere, K.L., Wong, D.C., Lee, P.C.S., Tsidulko, M., McQueen, J.T., Davidson, P., Mathur, R., Chuang, H.Y., DiMego, G., Seaman, N.L., 2005. Linking the Eta model with the community multiscale air quality (CMAQ) modeling system to build a national air quality forecasting system. Weather Forecast. 20, 367e384.

Querol, X., Alastuey, A., Pey, J., Cusack, M., Pérez, N., Mihalopoulos, N., Theodosi, C., Gerasopoulos, E., Kubilay, N., Koçak, M., 2009. Variability in regional background aerosols within the Mediterranean. Atmos. Chem. Phys. 9, 4575–4591.

Safieddine, S., Boynard, A., Coheur, P.-F., Hurtmans, D., Pfister, G., Quennehen, B., Thomas, J.L., Raut, J.-C., Law, K.S., Klimont, Z., Hadji-Lazaro, J., George, M., Clerbaux, C., 2014. Summertime tropospheric ozone assessment over the Mediterranean region using the thermal infrared IASI/MetOp sounder and the WRFChem model. Atmos. Chem. Phys. 14, 10119–10131. http://dx.doi.org/10.5194/acp14-10119-2014.

Schell, B., Ackermann, I.J., Hass, H., Binkowski, F.S., Ebel, A., 2001. Modeling the formation of secondary organic aerosol within a comprehensive air quality model system. J. Geophys. Res. 106, 28275–28293.

Solomos, S., Kallos, G., Kushta, J., Astitha, M., Tremback, C., Nenes, A., Levin, Z., 2011. An integrated modeling study on the effects of mineral dust and sea salt particles on clouds and precipitation. Atmos. Chem. Phys. 11, 873–892. http://dx.doi.org/10. 5194/acp-11-873-2011.

Stockwell, W.R., Middleton, P., Chang, J.S., Tang, X., 1990. The second generation regional acid deposition model chemical mechanism for regional air quality modelling. J. Geophys. Res. 95, 16343–16367.

Tewari, M., Chen, F., Wang, W., Dudhia, J., LeMone, M.A., Mitchell, K., Ek, M., Gayno, G., Wegiel, J., Cuenca, R.H., 2004. Implementation and verification of the unified NOAH land surface model in the WRF model. In: 20th Conference on Weather Analysis and Forecasting/16th Conference on Numerical Weather Prediction, pp. 11–15.

Tyrlis, E., Škerlak, B., Sprenger, M., Wernli, H., Zittis, G., Lelieveld, J., 2014. On the linkage between the Asian summer monsoon and tropopause fold activity over the Eastern Mediterranean and the Middle East. J. Geophys. Res. Atmos. 119, 3202–3221.

Tyrlis, E., Lelieveld, J., 2012. Aspects of a climatology and dynamics of the summer Etesians. EGU General Assem. Conf. Abstr. 14, 2144.

Vrekoussis, M., Liakakou, E., Mihalopoulos, N., Kanakidou, M., Crutzen, P.J., Lelieveld, J., 2006. Formation of HNO3 and NO3 - in the anthropogenically-influenced eastern Mediterranean marine boundary layer. Geophys. Res. Lett. 33, L05811. http://dx.doi. org/10.1029/2005GL025069.

Vrekoussis, M., Richter, A., Hilboll, A., Burrows, J.P., Gerasopoulos, E., Lelieveld, J., Barrie, L., Zerefos, C., Mihalopoulos, N., 2013. Economic crisis detected from space: air quality observations over Athens/Greece. Geophys. Res. Lett. 40, 458–463.

Waked, A., Seigneur, C., Couvidat, F., Kim, Y., Sartelet, K., Afif, C., Borbon, A., Formenti, P., Sauvage, S., 2013. Modeling air pollution in Lebanon: evaluation at a suburban site in Beirut during summer. Atmos. Chem. Phys. 13, 5873–5886. http://dx.doi.org/ 10.5194/acp-13-5873-2013.

Wild, O., Zhu, X., Prather, M., Fast, J., 2000. Accurate simulation of in- and below-cloud photolysis in tropospheric chemical models. J. Atmos. Chem. 37, 245–282. http://dx. doi.org/10.1023/A:1006415919030.

Zanis, P., Hadjinicolaou, P., Pozzer, A., Tyrlis, E., Dafka, S., Mihalopoulos, N., Lelieveld, J., 2014. Summertime free-tropospheric ozone pool over the Eastern Mediterranean/ Middle East. Atmos. Chem. Phys. 14, 115–132.

Zhang, Y., Seigneur, C., Bocquet, M., Mallet, V., Baklanov, A., 2012. Real-time air quality forecasting, Part II: state of the science, current research needs, and future prospects. Atmos. Environ. 60, 656–676.

Zhang, D., Anthes, R.A., 1982. High-resolution model of the planetary boundary layer – sensitivity tests and comparisons with SESAME-79 data. J. Appl. Meteorol. 21, 1594–1609 6120.

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