12062

A COMPARATIVE THERMAL ANALYSIS OF FIRE-OFF TREATED COTTON, POLYESTER AND CO/PET FABRICS

The present paper analyzes the potential for commercially available flame-retardant chemical called Fire-off for enhancing the flame-retardant properties of polyester (PET) and cotton (Co) fabrics and their corresponding blends (Co/PET). Fire-off was applied to the fabric through impregnation method and the resulting properties of these fabrics were assessed in terms of combustion behavior by use of a micro cone calorimeter (MCC) and Thermogravimetric Analysis (TGA). TGA results revealed that Fire-off could greatly enhance char residues of cotton, polyester and Co/PET fabrics at high temperature region. MCC results showed that Fire-off treatment could significantly decrease the heat release capacity (HRC), heat release rate (HRR), total heat release rate (THR) and peak heat release rate (pHRR) of cotton, polyester and Co/PET fabrics. According to comparison results, a near-perfect agreement between MCC and TGA data were found in terms of degradation temperatures and mass loss rates of fabric samples.

Keywords:

Micro-scale combustion calorimeter, thermogravimetric analysis, thermal characterization tests cotton, polyester,

PDF

___

A. R. Horrocks, “Flame retardant challenges for textiles and fibres: New chemistry versus innovatory solutions,” Polym. Degrad. Stab., vol. 96, no. 3, pp. 377–392, 2011.
Q. hua Zhang, J. Gu, G. qiang Chen, and T. ling Xing, “Durable flame retardant finish for silk fabric using boron hybrid silica sol,” Appl. Surf. Sci., vol. 387, pp. 446–453, 2016.
M. Przybylak, H. Maciejewski, A. Dutkiewicz, D. Wesołek, and M. Władyka-Przybylak, “Multifunctional, strongly hydrophobic and flame-retarded cotton fabrics modified with flame retardant agents and silicon compounds,” Polym. Degrad. Stab., vol. 128, pp. 55–64, 2016.
I. Šimkovic, “TG/DTG/DTA evaluation of flame retarded cotton fabrics and comparison to cone calorimeter data,” Carbohydr. Polym., vol. 90, no. 2, pp. 976–981, 2012.
Lyon, Richard E ; Walters, Richard, “A microscale combustion calorimeter” Final Report, Federal Aviation Administration Washington DC Office of Aviation Research, Feb.2002.
B. Schartel, K. H. Pawlowski, and R. E. Lyon, “Pyrolysis combustion flow calorimeter: A tool to assess flame retarded PC/ABS materials?,” Thermochim. Acta, vol. 462, no. 1–2, pp. 1–14, 2007.
J. Alongi, J. Tata, F. Carosio, G. Rosace, A. Frache, and G. Camino, “A comparative analysis of nanoparticle adsorption as fire-protection approach for fabrics,” Polymers (Basel)., vol. 7, no. 1, pp. 47–68, 2015.
F. Fang et al., “Boron-containing intumescent multilayer nanocoating for extinguishing flame on cotton fabric,” Cellulose, vol. 23, no. 3, pp. 2161–2172, 2016.
X. W. Cheng, J. P. Guan, R. C. Tang, and K. Q. Liu, “Phytic acid as a bio-based phosphorus flame retardant for poly(lactic acid) nonwoven fabric,” J. Clean. Prod., vol. 124, pp. 114–119, 2016.
F. Fang et al., “Environmentally friendly assembly multilayer coating for flame retardant and antimicrobial cotton fabric,” Prog. Org. Coatings, vol. 90, pp. 258–266, 2016.
Q. Zhang et al., “Flame retardance and thermal stability of wool fabric treated by boron containing silica sols,” Mater. Des., vol. 85, pp. 796–799, 2015.
Q. hua Zhang, G. qiang Chen, and T. ling Xing, “Silk flame retardant finish by ternary silica sol containing boron and nitrogen,” Appl. Surf. Sci., vol. 421, pp. 52–60, 2017.
J. Alongi, J. Milnes, G. Malucelli, S. Bourbigot, and B. Kandola, “Thermal degradation of DNA-treated cotton fabrics under different heating conditions,” J. Anal. Appl. Pyrolysis, vol. 108, pp. 212–221, 2014.
Q. Chen, C. Q. Yang, and T. Zhao, “Heat release properties and flammability of the nylon/cotton blend fabric treated with a crosslinkable organophosphorus flame retardant system,” J. Anal. Appl. Pyrolysis, vol. 110, no. 1, pp. 205–212, 2014.
C. Q. Yang, Q. He, R. E. Lyon, and Y. Hu, “Investigation of the flammability of different textile fabrics using micro-scale combustion calorimetry,” Polym. Degrad. Stab., vol. 95, no. 2, pp. 108–115, 2010.
K. Apaydin, A. Laachachi, V. Ball, M. Jimenez, S. Bourbigot, and D. Ruch, “Layer-by-layer deposition of a TiO2-filled intumescent coating and its effect on the flame retardancy of polyamide and polyester fabrics,” Colloids Surfaces A Physicochem. Eng. Asp., vol. 469, pp. 1–10, 2015.
L. Chen et al., “A new intumescent flame retardant containing phosphorus and nitrogen: Preparation, thermal properties and application to UV curable coating,” Prog. Org. Coatings, vol. 70, no. 1, pp. 59–66, 2011.
M. Zarrelli, A. Pullara, M. Codda, E. Amendola, A. Borriello, and P. Fermi, “Fireproof silicone sealants for shipbuilding,” no. June, pp. 24–28, 2012.
H. Lu, C. A. Wilkie, M. Ding, and L. Song, “Flammability performance of poly(vinyl alcohol) nanocomposites with zirconium phosphate and layered silicates,” Polym. Degrad. Stab., vol. 96, no. 7, pp. 1219–1224, 2011.
H. Behniafar and S. Haghighat, “Thermally stable and organosoluble one-pot preparation and characterization,” no. January, pp. 1040–1047, 2008.
H. Lu and C. A. Wilkie, “Study on intumescent flame retarded polystyrene composites with improved flame retardancy,” Polym. Degrad. Stab., vol. 95, no. 12, pp. 2388–2395, 2010.
H. Lu and C. A. Wilkie, “Synergistic effect of carbon nanotubes and decabromodiphenyl oxide/Sb2O3 in improving the flame retardancy of polystyrene,” Polym. Degrad. Stab., vol. 95, no. 4, pp. 564–571, 2010.
C. Q. Yang and Q. He, “Applications of micro-scale combustion calorimetry to the studies of cotton and nylon fabrics treated with organophosphorus flame retardants,” J. Anal. Appl. Pyrolysis, vol. 91, no. 1, pp. 125–133, 2011.
C. Q. Yang and Q. He, “Applications of micro-scale combustion calorimetry to the studies of cotton and nylon fabrics treated with organophosphorus flame retardants,” J. Anal. Appl. Pyrolysis, vol. 91, no. 1, pp. 125–133, 2011.
X. W. Cheng, J. P. Guan, R. C. Tang, and K. Q. Liu, “Improvement of flame retardancy of poly(lactic acid) nonwoven fabric with a phosphorus- containing flame retardant,” J. Ind. Text., vol. 46, no. 3, pp. 914–928, 2016.
Z. Yang, H. Ai-Huayi, J. Y. Liu, and X. Zhao, “Study of Fire Hazard of Flooring Materials on Data of Cone Calorimeter,” Procedia Eng., vol. 135, pp. 584–587, 2016.
R. Atakan, A. Bical, E. Celebi, G. Ozcan, N. Soydan, and A. S. Sarac, “Development of a flame retardant chemical for finishing of cotton, polyester, and CO/PET blends,” J. Ind. Text., 2018.
G. O. Raziye Atakan, “Mechanical Assessments of Fire-off on CO/PET Fabrics,” IOP Conf. Ser.: Mater. Sci. Eng. 460 012052, 2018.
A. R. Horrocks and D. Price, Fire retardant materials. woodhead Publishing, 2001.

ISSN: 1300-3356
Yayın Aralığı: Yılda 4 Sayı
Yayıncı: Ege Üniversitesi Tekstil ve Konfeksiyon Araştırma & Uygulama Merkezi

Arşiv