Assessment of acid mine drainage formation using geochemical and static tests in Mutki (Bitlis, SE Turkey) mineralization area

In this study, geochemical analyses, as well as short-term contact leaching and acid-base accounting tests, were carried out to determine the occurrence of acid mine drainage (AMD) by static tests in the ore stockpile areas at the Mutki Cu-Fe-Cr deposit (Bitlis, SE Turkey). According to the short-term contact leaching tests, the high enrichment in trace element concentrations in ore-bearing samples, especially in potentially toxic metals such as Cr, Cu, Mn, and Zn, were directly related to sulphide and oxide mineralizations. The pH (3.27-4.05) values of water samples, together with the classification of the intracontinental water resources, indicated that the water quality is the fourth class. Leaching tests, paste pH (3.42-4.46) and sulphide-sulphur (3.9-13.4 wt%) values also suggested that there was AMI) production potential in the mineralization area. The AMI) production potential was supported by the high mobility of several elements, such as Fe, Mg, Cr, As, Cu, S, and Zn. In ore samples, net neutralization potential (NNP) and net potential ratio (NPR) values were less than -20 kg CaCO3/t and 1, respectively. The basalts forming the basement rock of the stockpile area were characterized by permeable to slightly permeable properties that potentially increase the contamination risk of the groundwater due to seepage in the stockpile area. In order to prevent seepage in the stock area, geomembrane (synthetic waterproofing covers) should be laid at the base to ensure impermeability. The improvements planned in the stock area were modeled by the finite element method and seepage discharges at a depth of 5 m were determined as 1.34 x 10(-17)m(3)/s. Thanks to these planned applications, surface and groundwater pollution can be efficiently prevented.

___

  • Adedokun T.A., 2016, INT J RECENT INNOVAT, V4, P126, DOI [10.1007/s12303-019-0017-8., DOI 10.1007/S12303-019-0017-8]
  • Akaryali E, 2018, DOGAL AFETLER VE CER, V4, P192
  • Akcil A, 2006, J CLEAN PROD, V14, P1139, DOI 10.1016/j.jclepro.2004.09.006
  • Alemdag S, 2020, YERBILIMLERI, V41, P56 .
  • Alemdag S, 2015, ARAB J GEOSCI, V8, P1099, DOI 10.1007/s12517-013-1236-3
  • Baba A, 2004, INT J ENVIRON POLLUT, V22, P676, DOI 10.1504/IJEP.2004.006057
  • Balci N, 2018, MINE WATER ENVIRON, V37, P56, DOI 10.1007/s10230-017-0470-4
  • Betrie GD, 2015, ENVIRON TECHNOL INNO, V4, P240, DOI 10.1016/j.eti.2015.07.004
  • BLOWES DW, 1990, APPL GEOCHEM, V5, P327, DOI 10.1016/0883-2927(90)90008-S
  • Boon M, 1998, HYDROMETALLURGY, V48, P27, DOI 10.1016/S0304-386X(97)00072-8
  • Bouffard SC, 2006, HYDROMETALLURGY, V84, P225, DOI 10.1016/j.hydromet.2006.05.008
  • Bouzahzah H, 2014, MINE WATER ENVIRON, V33, P54, DOI 10.1007/s10230-013-0249-1
  • Bradham W.S., 1991, 2 INT C AB AC DRAIN, V1, P157
  • Brady K, 2000, PREDICTION WATER QUA, P8 .
  • Brodie MJ, 1991, P 2 ICARD, V3, P119 .
  • Brown E.T., 1981, ISRM SUGG METH ROCK .
  • Brunner B, 2008, EARTH PLANET SC LETT, V270, P63, DOI 10.1016/j.epsl.2008.03.019
  • Caraballo MA, 2011, ENVIRON POLLUT, V159, P3613, DOI 10.1016/j.envpol.2011.08.003
  • Caraballo MA, 2009, APPL GEOCHEM, V24, P2301, DOI 10.1016/j.apgeochem.2009.09.007
  • Cidu R, 2009, J GEOCHEM EXPLOR, V100, pV, DOI 10.1016/j.gexplo.2008.06.002
  • Cimen O, 2018, ENVIRON EARTH SCI, V77, DOI 10.1007/s12665-018-7391-9
  • De Capitani L, 2014, PERIOD MINERAL, V83, P223
  • Deere D.U., 1964, ROCK MECH ENG GEOLOG, V1, P16, DOI DOI 10.1016/S0886-7798(01)00038-4
  • Delibalta MS, 2016, J ENG SCI, V5, P73 .
  • Descostes M, 2004, GEOCHIM COSMOCHIM AC, V68, P4559, DOI 10.1016/j.gca.2004.04.012
  • Dold B, 2017, J GEOCHEM EXPLOR, V172, P120, DOI 10.1016/j.gexplo.2016.09.014
  • Dold B, 2014, MINERALS-BASEL, V4, P621, DOI 10.3390/min4030621
  • Dold B, 2009, J GEOCHEM EXPLOR, V100, P133, DOI 10.1016/j.gexplo.2008.05.002
  • EPA (US Environmental Protection Agency), 1994, 530R94012 EPA USEPA
  • EPA (US Environmental Protection Agency), 1994, 530R94036 EPA USEPA
  • Erguler GK, 2020, ARAB J GEOSCI, V13, DOI 10.1007/s12517-020-05372-0
  • Erguler GK, 2014, MINER ENG, V55, P18, DOI 10.1016/j.mineng.2013.09.008
  • Farid AT, 2017, INT J GEOTECHNICAL G, V11, P948
  • Ferguson K, 1991, P 2 INT C AB AC DRAI, P83
  • Ficklin WH, 1992, WATER ROCK INTERACTI, P381
  • Frostad SR, 2003, MINING ENV SUDBURY 2, P231
  • Gleisner M, 2006, CHEM GEOL, V225, P16, DOI 10.1016/j.chemgeo.2005.07.020
  • Gray NF, 1997, ENVIRON GEOL, V30, P62, DOI 10.1007/s002540050133
  • Gurocak Z, 2012, B ENG GEOL ENVIRON, V71, P221, DOI 10.1007/s10064-011-0400-9
  • HOEK E, 2002, P N AM ROCK MECH S 5, V5, P267
  • Holmes PR, 2000, GEOCHIM COSMOCHIM AC, V64, P263, DOI 10.1016/S0016-7037(99)00296-3
  • Hossner LR, 1997, P 14 ANN M ASSMR, P128
  • Imer A, 2016, ECON GEOL, V111, P1619 .
  • Imer A, 2013, MINER DEPOSITA, V48, P557, DOI 10.1007/s00126-012-0444-1
  • Jia Y, 2019, GREEN ENERGY ENVIRON, V4, P29, DOI 10.1016/j.gee.2018.04.001
  • Kanik M, 2019, ARAB J GEOSCI, V12, DOI 10.1007/s12517-019-4243-1
  • Karsli O, 2008, LITHOS, V106, P55, DOI 10.1016/j.lithos.2008.06.008
  • Kayabasi A, 2015, ENG GEOL, V185, P1, DOI 10.1016/j.enggeo.2014.12.007
  • Keskin M, 2006, GEOL SOC AM SPEC PAP, V409, P475, DOI 10.1130/2006.2409(23)
  • Khoeurn K, 2019, J GEOCHEM EXPLOR, V201, P1, DOI 10.1016/j.gexplo.2019.03.003
  • Koppen W, 1918, PETERMANNS MITT, V64, P193
  • Lapakko K. A., 2002, MINING MINERALS SUST, V67, P1
  • Lawrence RW, 1997, ENVIRON GEOL, V32, P100, DOI 10.1007/s002540050198
  • Lawrence RW, 1991, 1161B CANMET MEND .
  • Lawrence RW, 1996, 1163 MENDNEDEM CAN C .
  • Lawrence RW, 1989, ASSESSMENT PREDICTIV, P317
  • Liu C, 2017, SCI REP-UK, V7, DOI 10.1038/s41598-017-04420-2
  • Lottermoser BG, 2010, MINE WASTES: CHARACTERIZATION, TREATMENT AND ENVIRONMENTAL IMPACTS, P1, DOI 10.1007/978-3-642-12419-8
  • Ma Y., 2013, SCI REPORTS, V3, P1350, DOI DOI 10.1038/SREP01350
  • MEND (Mine Environment Neutral Drainage), 2009, 1201 MEND
  • Michaud ML, 2017, J GEOCHEM EXPLOR, V181, P58, DOI 10.1016/j.gexplo.2017.07.001
  • Morin K.A., 2001, ENV GEOCHEMISTRY MIN .
  • Nordstrom DK, 2009, J GEOCHEM EXPLOR, V100, P97, DOI 10.1016/j.gexplo.2008.08.002
  • Okay AI, 1999, GEOL SOC SPEC PUBL, V156, P475, DOI 10.1144/GSL.SP.1999.156.01.22
  • Parbhakar-Fox A, 2013, MINER ENG, V52, P111, DOI 10.1016/j.mineng.2013.04.022
  • Park I, 2019, CHEMOSPHERE, V219, P588, DOI 10.1016/j.chemosphere.2018.11.053
  • Parlak O, 2013, GEOL SOC SPEC PUBL, V372, P75, DOI 10.1144/SP372.7
  • Plumlee G.S., 1999, GEOLOGIC CONTROLS CO, V6, P373
  • Plumlee G. S., 1992, P 7 INT WAT ROCK INT, P419
  • Price W.A., 1997, P 4 INT C AC ROCK DR, V1, P1
  • Price WA, 2003, MINERAL AS, V31, P1 .
  • Rastegarnia A, 2019, Q J ENG GEOL HYDROGE, V52, P360, DOI 10.1144/qjegh2017-042
  • Robertson Steffen, 1989, DRAFT AC ROCK DRAIN, V1
  • Rocscience, 2019, RS2 10 012 2D GEOT F .
  • Sanliyuksel Y. D., 2013, ARCH ENV CONTAM TOXI, V64, P357, DOI DOI 10.1007/s00244-012-9843-7
  • Sapsford DJ, 2009, MINER ENG, V22, P25, DOI 10.1016/j.mineng.2008.03.008
  • Sengor AMC, 2003, GEOPHYS RES LETT, V30, DOI 10.1029/2003GL017858
  • Siddharth S., 2002, MINE WATER ENVIRON, V21, P106, DOI [10.1007/s102300200030, DOI 10.1007/S102300200030]
  • SINGER PC, 1970, SCIENCE, V167, P1121, DOI 10.1126/science.167.3921.1121
  • Skousen J, 2000, PREDICTION WATER QUA, P73
  • Skousen J.G., 2000, RECLAM DRASTICALLY D, DOI [10.2134/agronmonogr41.c6, DOI 10.2134/AGRONMONOGR41.C6]
  • Skousen JG, 1987, EWRC 871 .
  • Smith RM, 1976, EPA600276184 USEPA .
  • Sobek A.A., 1978, EPA600278054 .
  • Soregaroli BA, 1998, P MIN DES OP CLOS C
  • Tayfur G, 2010, ENVIRON MONIT ASSESS, V169, P509, DOI 10.1007/s10661-009-1193-1
  • Tosun YI, 2017, COAL FLY ASH BENEFIC, P141, DOI 10.5772/intechopen.69927.
  • Ulusay R, 2007, TEST MON .
  • US Bureau of Reclamation, 1974, FIELD PERM TESTS WEL
  • Verburg R, 2009, MINE WATER ENVIRON, V28, P305, DOI 10.1007/s10230-009-0078-4
  • [Ярошевский А.А. Yaroshevsky A.A.], 2006, [Геохимия, Geokhimiya], P54
  • Yolcubal I, 2017, ENVIRON EARTH SCI, V76, DOI 10.1007/s12665-017-6423-1
  • Yolcubal I, 2016, ENVIRON EARTH SCI, V75, DOI 10.1007/s12665-016-6224-y
  • Yucel DS, 2016, ENVIRON MONIT ASSESS, V188, DOI 10.1007/s10661-016-5462-5
  • Yucel DS, 2016, ARCH ENVIRON CON TOX, V70, P757, DOI 10.1007/s00244-016-0270-z