The Direct Electrochemical Synthesis of Ti(II), Fe(II), Cd(II), Sn(II), and Pb(II) Complexes with N, N´-Bis(Salicylidene)-o-Phenylenediamine

The electrochemical oxidation of anodic Ti, Fe, Cd, Sn, and Pb (=M) into acetonitrile solutions of N,N'-bis(salicylidene)-o-phenylenediamine [SalophH2] gives the corresponding M(Saloph) complexes in high yield. The mechanism of the electrochemical reactions is discussed. SalophH2 forms complexes (1:1 molar ratio) with titanium, iron, cadmium, tin, and lead ions. The complexes have been characterized by elemental analyses, molar conductivity measurements, and infrared and electronic spectral data. The SalophH2 complexes of iron(II) and cadmium(II) have been further identified by 1H-NMR and mass spectra.

The Direct Electrochemical Synthesis of Ti(II), Fe(II), Cd(II), Sn(II), and Pb(II) Complexes with N, N -Bis(Salicylidene)-o-Phenylenediamine

The electrochemical oxidation of anodic Ti, Fe, Cd, Sn, and Pb (=M) into acetonitrile solutions of N,N'-bis(salicylidene)-o-phenylenediamine [SalophH2] gives the corresponding M(Saloph) complexes in high yield. The mechanism of the electrochemical reactions is discussed. SalophH2 forms complexes (1:1 molar ratio) with titanium, iron, cadmium, tin, and lead ions. The complexes have been characterized by elemental analyses, molar conductivity measurements, and infrared and electronic spectral data. The SalophH2 complexes of iron(II) and cadmium(II) have been further identified by 1H-NMR and mass spectra.

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  • R. Ramesh, P. K. Suganthy and K. Natarajan, Synth. Inorg. Met. -Org. Chem. 26, 47-60 (1996).
  • Y. Ohashi, Bull. Chem. Soc. Jpn. 70, 1319-1324 (1997).
  • R.A. Siddiqui, P. Raj and A.K. Saxena, Synth. Inorg. Met. -Org. Chem. 26, 1189-1203 (1996).
  • Z. Xinde, W. Chenggang, L. Zhiping, L. Zhifeng and W. Zhshen, Synth. Inorg. Met. -Org. Chem. 26, 966 (1996).
  • R. Yuan, Y. Chai, D. Liu, D. Gao , J. Li and R. Yu, Anal. Chem. 65, 2572-2575 (1993).
  • L.J. Boucher and C.G. Coe, Inorg. Chem. 15, 1334-1340 (1976).
  • B.S. Tovrog, D.J. Kitko and R.S. Drago, J. Am. Chem. Soc. 98, 5144-5253 (1976).
  • P. S. Dixit and K. Srinivason, Inorg. Chem. 27, 4507-4509 (1988).
  • N. T. Tojo and T. Matsura, J. Chem. Soc. Chem. Commun. 896-897 (1974).
  • S.L. Kessel, R.M. Emberson, P.G. Debunner and D.N. Hendrickson, Inorg. Chem. 19, 1170-1178 (1980).
  • N.A. Bailey, B.M. Higson and E.D. Mckenzie, J. Chem. Soc. Dalton Trans. 503-508 (1972).
  • D. Cummins, E.D. Mckenzie and H. Milburb, J. Chem. Soc. Dalton Trans. 130-135 (1976).
  • F.F. Said and D.G. Tuck, Inorganica Chimica Acta. 59, 1-4 (1982)
  • E. Labisbal, A. Sousa-Pedrares, A. Castineiras, J.K. Swearingen and D.X. West, Polyhedron. 21, 1553-1559 (2002).
  • J. Sanchez-Piso, J.A. Garcia-Vazquez, J. Romero, M.L. Duran, A. Sousa-Pedrares, E. Labisbal and O.R. Nascimento, Inorganica Chimica Acta. 328, 111-122 (2002).
  • M. Vazquez, M.R. Bermejo, M. Fondo, A. Garcia-Deibe, A.M. Gonzalez and R. Pedrido, Eur. J. Inorg. Chem. 465-472 (2002).
  • M. Vazquez, M.R. Bermejo, M. Fondo, A.M. Garcia-Deibe, A.M. Gonzalez, R. Pedrido and J. Sanmartin, Z. Anorg. Aiig. Chem. 628, 1068-1074 (2002).
  • J. Castro, S. Cabaleiro, P. Perez-Lourido, J. Romero, J.A. Garcia-Vazquez and A. Sousa, Z. Anorg. Aiig. Chem. 628, 1210-1217 (2002).
  • L. Jianning, Y, Xingqi, D. Yanjie and S. Qizhen, Chinese Journal of Inorganic Chemistry 15, 680-684 (1999).
  • T.A. Annan, D.G. Tuck, M.A. Khan and C. Peppe, Organometallics. 10, 2159-2166 (1991).
  • M.A. Khan, R. Kumar and D.G. Tuck, Polyhedron. 7, 49-55 (1988).
  • F. Kratz, B. Nuber, J. Weib and B.K. Keppler, Synth. Inorg. Met. -Org. Chem. 21, 1601-1615 (1991).
  • N.S. Biradar and V.H. Kulkami, J. Inorg. Nucl. Chem. 33, 3781-3786 (1971).
  • J.N.R. Ruddick and J.R. Sams, J. Organomet. Chem. 60, 233-246 (1973).
  • P. Toyssie and J.J. Charette, Spectrochim. Acta. 19, 1407-1422 (1963).
  • S. Sarawat, G.S. Srivastava and R.C. Mehrotra, J. Organomet. Chem. 129, 155-161 (1977).
  • G. Wang and J.C. Chang, Synth. Inorg. Met. -Org. Chem. 24, 1091-1097 (1994).
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
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