Synthesis, spectroscopic characterization, mass spectrometry, and crystal structure of N-{[(4-bromophenyl)amino]carbonothioyl}benzamide
N-{[(4-bromophenyl)amino]carbonothioyl}benzamide was synthesized and characterized by IR, 1H- and 13C-NMR, mass spectrometry, and elemental analysis. The crystal structure was determined from single crystal X-ray diffraction data. It crystallizes in monoclinic space group P21/n with unit cell dimensions a = 13.822(3) Å, b = 5.927(2) Å, c = 16.642(3) Å, and b = 103.963(3)°. There is a strong intramolecular hydrogen bond of the type N_H L O, with an HL O distance of 2.6129 (11) Å. The mass fragmentation pattern is also discussed.
Anahtar Kelimeler:
Thiourea derivative, X-ray structure determination, mass fragmentation
Synthesis, spectroscopic characterization, mass spectrometry, and crystal structure of N-{[(4-bromophenyl)amino]carbonothioyl}benzamide
N-{[(4-bromophenyl)amino]carbonothioyl}benzamide was synthesized and characterized by IR, 1H- and 13C-NMR, mass spectrometry, and elemental analysis. The crystal structure was determined from single crystal X-ray diffraction data. It crystallizes in monoclinic space group P21/n with unit cell dimensions a = 13.822(3) Å, b = 5.927(2) Å, c = 16.642(3) Å, and b = 103.963(3)°. There is a strong intramolecular hydrogen bond of the type N_H L O, with an HL O distance of 2.6129 (11) Å. The mass fragmentation pattern is also discussed.
- ISSN: 1300-0527
- Yayın Aralığı: Yılda 6 Sayı
- Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler
Chemistry of 2-aminoanthraquinones
Moustafa Ahmed GOUDA, Moged Ahmed BERGHOT, Alaa SHOEIB, Khaled M. ELATTAR, Abd El-Galil Mohamed KHALIL
Mahdi HOSSEIN, Nasser DALALI, Ali KARIMI, Kourosh DASTANRA
Kemal SANCAK, Yasemin ÜNVER, Canan KAZAK, Esra DÜĞDÜ, Burcu ARSLAN
Batool AKHLAGHINIA, Alireza POURALI
Amtul NASEER, Athar Yaseen KHAN
Kadriye AYDIN, Stephen T. ASTLEY, Gamze KOZ, Leman KARADENİZ
Hai-Xian REN, Ming-Gen ZHAO, Ying-Jin WANG