Synthesis and Spectral Investigations of Some Platinum Metals Ions Coordination Compounds of 4[N-(Furan-2'-carboxalidene)Amino]Antipyrine Thiosemicarbazone and 4[N-(3',4',5'-Trimethoxybenzalidene)Amino]Antipyrine Thiosemicarbazone

The present work describes the synthesis and spectral properties of some platinum metals chlorides coordination compounds of 4[N-(-(furan-2'-carboxalidene)amino]antipyrine thiosemicarbazone (FFAAPTS) and 4[N-(3',4',5'-trimethoxybenzalidene)amino]antipyrine thiosemicarbazone (TMBAAPTS). All the compounds have the general composition MCl2(L) (M = Pd2+ or Pt2+ ; L = FFAAPTS or TMBAAPTS) or MCl3(L) (M = Ru3+ , Rh3+ or Ir3+ ; L = FFAAPTS or TMBAAPTS). All the complexes were characterized by elemental analyses, molar conductance, molecular weight, magnetic measurements, and infrared and electronic spectra. The infrared spectra suggest that both the thiosemicarbazones behave as neutral tridentate (N,N,S) ligands. The magnetic and electronic spectra suggest that Pd2+ and Pt2+ complexes are square planar, while Ru3+ , Rh3+ and Ir3+ complexes have octahedral geometry.

Anahtar Kelimeler:

Platinum metals, Thiosemicarbazones, Coordination compounds.

Synthesis and Spectral Investigations of Some Platinum Metals Ions Coordination Compounds of 4[N-(Furan-2'-carboxalidene)Amino]Antipyrine Thiosemicarbazone and 4[N-(3',4',5'-Trimethoxybenzalidene)Amino]Antipyrine Thiosemicarbazone

Keywords:

Platinum metals, Thiosemicarbazones, Coordination compounds.,

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B. Rosenberg, L. Van Camp, J.E. Trosko and V.H. Mansour, Nature (London), 222, 385 (1969).
R. Drasga, L. Einhern and S. Williams, Cancer J. Clin. 32, 65 (1982).
P. Leehrer and L. Einhern, Ann. Int. Med., 100, 704 (1984).
T.A.K. Al-Allaf and R.I. Al-Bayati, Asian J. Chem., 7, 465 (1995).
T.A.K. Al-Allaf, R.I. Al-Bayati and A.S. Al-Botany, Asian J. Chem., 8, 839 (1996).
T.A.K. Al-Allaf, L.J. Rashan, R.F. Khuzaie and W.F. Halaseh, Asian J. Chem., 9, 239 (1997).
T.A.K. Al-Allaf, R.I. Al-Bayati and A.S. Al-Botany, Asian J. Chem., 10, 287 (1998).
T.A.K. Al-Allaf and L.J. Rashan, Eur. J. Med. Chem., 33, 817 (1998).
T.A.K. Al-Allaf and L.J. Rashan, Asian J. Chem., 10, 342 (1998).
T.A.K. Al-Allaf and L.J. Rashan, Asian J. Chem., 11, 950 (1999).
R.K. Agarwal, Bhushan and G.B. Singh, Pol. J. Chem., 68, 871 (1994).
R.K. Agarwal, G. Singh and B. Bhushan, J. Inst. Chemists, 65, 131 (1993).
F.J. Welcher, “The Analytical Uses of EDTA, D. Van Nostrand Co. Inc., N.Y. 1965.
A. I. Vogel, “A Text Book of Quantitative Inorganic Analysis,” 4thEdit., ELBS Longman, London 1986.
R.K. Agarwal and G. Singh, Asian J. Chem., 1, 409 (1989).
R.K. Agarwal, Pol. J. Chem., 65, 1211 (1991).
T.S. Lane, A Yamagauchi and A. Rayon James, J. Am. Chem. Soc., 80, 527 (1958).
K. Swaminathan and H.M.N.H. Irving, J. Inorg. Nucl. Chem., 26, 1291 (1964).
V.B. Rana, J. Inorg. Nucl. Chem., 37, 1826 (1975).
B.D. Sarma and J.C. Bailer (Jr), J. Am. Chem. Soc., 77, 5476 (1955).
P.W. Sadler, J. Chem. Soc., 957 (1961).
S. Chandra and K.K. Sharma, Synth. React. Inorg. Met-Org. Chem., 12, 415 (1982).
S. Chandra and K.B. Pandeya, Transition Met. Chem., 6, 110 (1981).
S. Yamada and K. Yamanouchi, Bull. Chem. Soc. (Japan), 42, 2543 (1969).
P.L. Goggin, R.J. Goodfellow and F.J.S. Reed, J. Chem. Soc. Dalton, 1298 (1972).
R.M. Alcock, P.R. Hartley and D.E. Rogers, J. Chem. Soc. Dalton, 1070 (1973).
W.R. Marson and H.B. Gray, J. Am. Chem. Soc., 90, 5721 (1968).
A.R. Latham, V. Hamscale and H.B. Gray, Inorg. Chem., 4, 788 (1965).
S. Chandra, K.B. Pandeya and R.P. Singh, Indian J. Chem., 18A, 476 (1979).
S. Chandra and R. Singh, Indian J. Chem., 27A, 417 (1988).
Usha and S. Chandra, Synth. React. Inorg. Met. Org. Chem., 22, 929, 1565 (1992).
A. Kumar, Usha and S. Chandra, Synth. React. Inorg. Met. Org. Chem., 23, 671 (1993).
Usha, A. Kumar and S. Chandra, Transition Met. Chem., 18, 342 (1993).
C.K. Jorgensen, Prog. Inorg. Chem., 4, 73 (1962).
C.K. Jogensen, “Absorption Spectra and Chemical Bonding in Complexes”, Pergamon Press, London (1964).