Synthesis and photovoltaic characterization of triarylamine-substituted quinoxaline push-pull dyes to improve the performance of dye-sensitized solar cells

Novel unsymmetrical organic sensitizers having donor, $\pi $-spacer, and anchoring groups were designed and synthesized for dye-sensitized solar cell (DSSC) application. The dyes 3-{4-[7-(4-{bis[4-(hexyl)phenyl]amino} phenyl)-11,12-dibutoxy-1,4,5,8-tetrahydrodibenzo [a, c] phenazine-2-yl]phenyl} -2-cyano acrylic acid (KD-148) and 3-{5-[7-(4-{bis[4-(hexyloxy)phenyl]amino} phenyl)-11,12-dibutoxy-1,4,5,8-tetrahydrodibenzo [a, c] phenazine-2-yl]-2-thienyl} -2-cyano acrylic acid (KD-150) were anchored onto TiO$_{2}$ and tested with ionic liquid electrolyte. The monochromatic incident photon-to-current conversion efficiencies (IPCE) of the dyes were 50% and 60% at 420 nm, respectively. The KD-150-sensitized solar cell gave a short-circuit current (I$_{SC})$ of 7.37 mA/cm$^{2}$, an open-circuit voltage (V$_{oc})$ of 560 mV, a fill factor (FF) of 0.56, and overall conversion efficiency ($\eta )$ of 2.32% whereas the standard dye Z-907 dye exhibited 14.51 mA/cm$^{2}$ of I$_{SC}$, 630 mV of V$_{oc}$, 0.45 of FF, and 4.08% of $\eta $ under AM 1.5 illumination with power of 100 mW/cm$^{2}$.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Development of a sample preparation strategy for the determination of tungsten in soil samples by inductively coupled plasma mass spectrometry using a response surface methodology

Ümran SEVEN ERDEMİR

KADİR DEMİRAK, MUSTAFA CAN, CİHAN ÖZSOY, MESUDE ZELİHA YİĞİT, BURAK GÜLTEKİN, ŞERAFETTİN DEMİÇ, CEYLAN ZAFER

The structure and cytotoxic activity of a new saponin: cephoside A from Cephalaria elazigensis var. purpurea

Murat PEKMEZ, Süheyla KIRMIZIGÜL, Peyker KAYCE, Nazlı BÖKE SARIKAHYA, Nazlı ARDA

Fabrication of multilayer graphene oxide-reinforced high density polyethylene nanocomposites with enhanced thermal and mechanical properties via thermokinetic mixing

Burcu SANER OKAN

Fatma TELLİ, Stephen Thomas ASTLEY, AZİZE YEŞİM SALMAN

A biochar-modified carbon paste electrode

Gökçen AKGÜL, Derya BAL ALTUNTAŞ, Jale YANIK, Ülkü ANIK

Efficient photodegradation of neutral red chloride dye in aqueous medium using graphene/cobalt-manganese oxides nanocomposite

Idrees KHAN, Khalid SAEED

Seyed Ershad MORADI, Shayessteh DADFARNIA, Ali Mohammad Haji SHABANI, Saeed EMAMI

Synthesis of novel derivatives of chromenone bearing an NN-carbamothioyl moiety as soybean 15-LOX inhibitors

Mina SAEEDI, Mohammad MAHDAVI, Robabeh KAVIANI, Hamid NADRI, Alireza MORADI, Tahmineh AKBARZADEH, Abbas SHAFIEE

A rapid, eco-friendly, and reliable microplate method for determination of Cr(VI)

Alejandro CORENO-ALONSO, Gustavo CRUZ-JIM ENEZ, Leticia LOPEZ-MARTİNEZ, Georgina E. REYNA-LOPEZ, Francisco Javier ACEVEDO-AGUILAR